Boron nitride nanotubes: functionalization and composites

Boron nitride nanotubes (BNNTs) are novel because of their wide band gap, superb mechanical properties, high thermal conductivity and robustness to oxidation. These features make BNNTs promising nanofillers that lead to the significant mechanical reinforcement and improvement of thermal conductivity of a composite. However, only in recent years, benefiting from the development of effective syntheses of BNNTs, have the follow-up chemical functionalization and composite studies of BNNTs been initiated. To achieve better solubility and processability of BNNTs, various methods have been developed to functionalize BNNTs via different interactions. Moreover, BNNT polymeric and ceramic composites have been fabricated and property improvements have indeed been documented. In this feature article, we summarize the recent progress in the chemistry and composite research of BNNTs.

[1]  J. Fraser Stoddart,et al.  Preparation and Properties of Polymer-Wrapped Single-Walled Carbon Nanotubes , 2001 .

[2]  Atula S. D. Sandanayaka,et al.  Photoinduced charge injection and bandgap-engineering of high-specific-surface-area BN nanotubes using a zinc phthalocyanine monolayer. , 2007, Small.

[3]  Xiao-hua Li,et al.  Assay for uric acid level in rat striatum by a reagentless biosensor based on functionalized multi-wall carbon nanotubes with tin oxide , 2005, Analytical and bioanalytical chemistry.

[4]  S. Iijima.  Helical microtubules of graphitic carbon , 1991, Nature.

[5]  A. Zettl,et al.  Functionalized boron nitride nanotubes with a stannic oxide coating: a novel chemical route to full coverage. , 2003, Journal of the American Chemical Society.

[6]  Takuzo Aida,et al.  Molecular Ordering of Organic Molten Salts Triggered by Single-Walled Carbon Nanotubes , 2003, Science.

[7]  C. Zhi,et al.  Purification of boron nitride nanotubes through polymer wrapping. , 2006, The journal of physical chemistry. B.

[8]  C. Zhi,et al.  Boron nitride nanotubes: nanoparticles functionalization and junction fabrication. , 2007, Journal of nanoscience and nanotechnology.

[9]  P. Bernier,et al.  Elastic Properties of C and B x C y N z Composite Nanotubes , 1998 .

[10]  Y. Xiao,et al.  Specific heat and quantized thermal conductance of single-walled boron nitride nanotubes , 2004 .

[11]  Angel Rubio,et al.  Phase separation of carbon nanotubes and turbostratic graphite using a functional organic polymer , 2000 .

[12]  P. McEuen,et al.  Thermal transport measurements of individual multiwalled nanotubes. , 2001, Physical Review Letters.

[13]  Sung R. Choi,et al.  Boron Nitride Nanotubes-Reinforced Glass Composites , 2006 .

[14]  C. Zhi,et al.  Engineering of electronic structure of boron-nitride nanotubes by covalent functionalization , 2006 .

[15]  Lian Gao,et al.  Enhancing superplasticity of engineering ceramics by introducing BN nanotubes , 2007 .

[16]  C. Zhi,et al.  Covalent functionalization: towards soluble multiwalled boron nitride nanotubes. , 2005, Angewandte Chemie.

[17]  R. Andrews,et al.  Carbon nanotube polymer composites , 2004 .

[18]  Louie,et al.  Electron correlation in semiconductors and insulators: Band gaps and quasiparticle energies. , 1986, Physical review. B, Condensed matter.

[19]  M. Conway,et al.  Nanotube growth during annealing of mechanically milled Boron , 2003 .

[20]  D. A. Dougherty,et al.  The Cationminus signpi Interaction. , 1997, Chemical reviews.

[21]  Abhijit P. Suryavanshi,et al.  Elastic modulus and resonance behavior of boron nitride nanotubes , 2004 .

[22]  Milo S. P. Shaffer,et al.  Development of a dispersion process for carbon nanotubes in an epoxy matrix and the resulting electrical properties , 1999 .

[23]  A. Govindaraj,et al.  B–C–N, C–N and B–N nanotubes produced by the pyrolysis of precursor molecules over Co catalysts , 1998 .

[24]  Eklund,et al.  Solution properties of single-walled carbon nanotubes , 1998, Science.

[25]  Dmitri Golberg,et al.  Direct Force Measurements and Kinking under Elastic Deformation of Individual Multiwalled Boron Nitride Nanotubes , 2007 .

[26]  J. Gerald,et al.  Synthesis of boron nitride nanotubes at low temperatures using reactive ball milling , 1999 .

[27]  C. Zhi,et al.  Perfectly dissolved boron nitride nanotubes due to polymer wrapping. , 2005, Journal of the American Chemical Society.

[28]  C. Zhi,et al.  SnO2 nanoparticle-functionalized boron nitride nanotubes. , 2006, The journal of physical chemistry. B.

[29]  C. Zhi,et al.  Phonon characteristics and cathodolumininescence of boron nitride nanotubes , 2005 .

[30]  John D. Fitz Gerald,et al.  A solid-state process for formation of boron nitride nanotubes , 1999 .

[31]  A. Zettl,et al.  Self-Assembly of Gold Nanoparticles at the Surface of Amine- and Thiol-Functionalized Boron Nitride Nanotubes , 2007 .

[32]  C. Zhi,et al.  DNA-mediated assembly of boron nitride nanotubes. , 2007, Chemistry - An Asian Journal.

[33]  F. Willaime,et al.  Boron nitride nanotubes with reduced numbers of layers synthesized by arc discharge. , 1996, Physical review letters.

[34]  John Ballato,et al.  Carbon Nanotube Doped Polyaniline , 2002 .

[35]  Electric polarization of heteropolar nanotubes as a geometric phase. , 2001, Physical review letters.

[36]  David L. Carroll,et al.  A Composite from Poly(m‐phenylenevinylene‐co‐2,5‐dioctoxy‐p‐phenylenevinylene) and Carbon Nanotubes: A Novel Material for Molecular Optoelectronics , 1998 .

[37]  A. Zettl,et al.  Amine-functionalized boron nitride nanotubes , 2007 .

[38]  Kenji Takeuchi,et al.  The production and structure of pyrolytic carbon nanotubes (PCNTs) , 1993 .

[39]  Steven G. Louie,et al.  Stability and Band Gap Constancy of Boron Nitride Nanotubes , 1994 .

[40]  A. Majumdar,et al.  Isotope effect on the thermal conductivity of boron nitride nanotubes. , 2006, Physical review letters.

[41]  C. Zhi,et al.  Molecule Ordering Triggered by Boron Nitride Nanotubes and “Green” Chemical Functionalization of Boron Nitride Nanotubes , 2007 .

[42]  C. Kirmaier,et al.  Optical properties of metalloporphyrin excited states , 1989 .

[43]  Kyeongjae Cho,et al.  Nanomechanics of carbon nanotubes and composites , 2003 .

[44]  Atula S. D. Sandanayaka,et al.  Donor–Acceptor Nanoensembles Based on Boron Nitride Nanotubes , 2007 .

[45]  Norman C. Billingham,et al.  Carbon nanotubes as polymer antioxidants , 2003 .

[46]  R. Car,et al.  Frustration effects and microscopic growth mechanisms for BN nanotubes , 1998 .

[47]  Dmitri Golberg,et al.  Boron Nitride Nanotubes , 2007 .

[48]  C. Zhi,et al.  Boron nitride nanotubes/polystyrene composites , 2006 .

[49]  T. Chou,et al.  Aligned multi-walled carbon nanotube-reinforced composites: processing and mechanical characterization , 2002 .

[50]  M. Zheng,et al.  DNA-assisted dispersion and separation of carbon nanotubes , 2003, Nature materials.

[51]  Y. Bando,et al.  A novel precursor for synthesis of pure boron nitride nanotubes. , 2002, Chemical communications.

[52]  C. Rao,et al.  Functionalization and solubilization of BN nanotubes by interaction with Lewis bases , 2007 .

[53]  I. Chen,et al.  Superplastic Alumina at Temperatures below 1300°C Using Charge-Compensating Dopants , 1996 .

[54]  Ying Chen,et al.  Large-quantity production of high-yield boron nitride nanotubes , 2002 .

[55]  Gilbert C Walker,et al.  Noncovalent engineering of carbon nanotube surfaces by rigid, functional conjugated polymers. , 2002, Journal of the American Chemical Society.

[56]  Rusli,et al.  Semiconducting boron carbonitride nanostructures: Nanotubes and nanofibers , 2000 .

[57]  S. Louie,et al.  Electronic structure of radially deformed BN and BC 3 nanotubes , 2001 .

[58]  Elizabeth C. Dickey,et al.  Load transfer and deformation mechanisms in carbon nanotube-polystyrene composites , 2000 .

[59]  C. Zhi,et al.  Effective precursor for high yield synthesis of pure BN nanotubes , 2005 .

[60]  C. Zhi,et al.  Characteristics of boron nitride nanotube-polyaniline composites. , 2005, Angewandte Chemie.

[61]  B. Akdim,et al.  Comparative theoretical study of single-wall carbon and boron-nitride nanotubes , 2003 .

[62]  Y. Bando,et al.  Synthesis of boron nitride nanotubes from carbon nanotubes by a substitution reaction , 1998 .

[63]  Ya‐Ping Sun,et al.  Solubilization of boron nitride nanotubes. , 2005, Chemical communications.

[64]  K. Méténier,et al.  Elastic Modulus of Ordered and Disordered Multiwalled Carbon Nanotubes , 1999 .

[65]  Steven G. Louie,et al.  Boron Nitride Nanotubes , 1995, Science.

[66]  Peter J. F. Harris,et al.  Carbon nanotube composites , 2004 .

[67]  C. Zhi,et al.  Immobilization of proteins on boron nitride nanotubes. , 2005, Journal of the American Chemical Society.

[68]  H. Pan,et al.  Ab initio study of OH-functionalized single-wall carbon nanotubes , 2004 .

[69]  C. Zhi,et al.  Grafting Boron Nitride Nanotubes: From Polymers to Amorphous and Graphitic Carbon , 2007 .

[70]  J. Tour,et al.  Glass transition of polymer/single-walled carbon nanotube composite films , 2003 .

[71]  C. Zhi,et al.  Chemical peeling and branching of boron nitride nanotubes in dimethyl sulfoxide. , 2006, Angewandte Chemie.