Lost by Design.

In some common uses metals are lost by intent-copper in brake pads, zinc in tires, and germanium in retained catalyst applications being examples. In other common uses, metals are incorporated into products in ways for which no viable recycling approaches exist, examples include selenium in colored glass and vanadium in pigments. To determine quantitatively the scope of these "losses by design", we have assessed the major uses of 56 metals and metalloids, assigning each use to one of three categories: in-use dissipation, currently unrecyclable when discarded, or potentially recyclable when discarded. In-use dissipation affects fewer than a dozen elements (including mercury and arsenic), but the spectrum of elements dissipated increases rapidly if applications from which they are currently unrecyclable are considered. In many cases the resulting dissipation rates are higher than 50%. Among others, specialty metals (e.g., gallium, indium, and thallium) and some heavy rare earth elements are representative of modern technology, and their loss provides a measure of the degree of unsustainability in the contemporary use of materials and products. Even where uses are currently compatible with recycling technologies and approaches, end of life recycling rates are in most cases well below those that are potentially achievable. The outcomes of this research provide guidance in identifying product design approaches for reducing material losses so as to increase element recovery at end-of-life.

[1]  Fabrizio Passarini,et al.  Historical evolution of greenhouse gas emissions from aluminum production at a country level , 2014 .

[2]  G. Gunn Critical Metals Handbook: Gunn/Critical Metals Handbook , 2014 .

[3]  T E Graedel,et al.  On the materials basis of modern society , 2013, Proceedings of the National Academy of Sciences.

[4]  Till Zimmermann,et al.  Critical materials and dissipative losses: a screening study. , 2013, The Science of the total environment.

[5]  N. T. Nassar CHAPTER 7:Anthropospheric Losses of Platinum Group Elements , 2013 .

[6]  Thomas E. Graedel,et al.  The omnivorous diet of modern technology , 2013 .

[7]  G. Steinhauser,et al.  Illicit utilization of arsenic compounds in pyrotechnics? An analysis of the suspended particle emission during Vienna’s New Year fireworks , 2013, Journal of Radioanalytical and Nuclear Chemistry.

[8]  Laura Talens Peiró,et al.  Material flow analysis of scarce metals: sources, functions, end-uses and aspects for future supply. , 2013, Environmental science & technology.

[9]  L. Schebek,et al.  Dissipative application of lithium – lost for the future? , 2012 .

[10]  Siegfried Bauer,et al.  Sustainable materials: With both eyes open , 2012 .

[11]  T. Graedel,et al.  Challenges in Metal Recycling , 2012, Science.

[12]  M. Çelik,et al.  Effect of quantity and size distribution of calcite filler on the quality of water borne paints , 2012 .

[13]  T. Graedel,et al.  Exploring the Global Journey of Nickel with Markov Chain Models , 2012 .

[14]  E M Harper,et al.  Metal lost and found: dissipative uses and releases of copper in the United States 1975-2000. , 2012, The Science of the total environment.

[15]  P. Westerhoff,et al.  Titanium dioxide nanoparticles in food and personal care products. , 2012, Environmental science & technology.

[16]  T. Klapötke,et al.  Alkaline Earth Metal Salts of 5,5′‐Bistetrazole – from Academical Interest to Practical Application , 2011 .

[17]  J. Allwood,et al.  What Do We Know About Metal Recycling Rates? , 2011 .

[18]  Y. Ni,et al.  Carbohydrate-based fillers and pigments for papermaking: A review , 2011 .

[19]  N. M. Ahmed,et al.  Innovative titanium dioxide‐kaolin mixed pigments performance in anticorrosive paints , 2011 .

[20]  Daniel Müller,et al.  Tracking the devil's metal: Historical global and contemporary US tin cycles , 2010 .

[21]  T. Klapötke,et al.  Using the Chemistry of Fireworks To Engage Students in Learning Basic Chemical Principles: A Lesson in Eco-Friendly Pyrotechnics , 2010 .

[22]  Veerle Timmermans,et al.  Long-term consequences of non-intentional flows of substances: modelling non-intentional flows of lead in the Dutch economic system and evaluating their environmental consequences. , 2009, Waste management.

[23]  Paul T Anastas,et al.  Spatial assessment of net mercury emissions from the use of fluorescent bulbs. , 2008, Environmental science & technology.

[24]  Luca Rossi,et al.  Diffuse release of environmental hazards by railways , 2008 .

[25]  S. Eijsbouts Life cycle of hydroprocessing catalysts and total catalyst management , 2008 .

[26]  C Scott Clark,et al.  Lead content of dried films of domestic paints currently sold in Nigeria. , 2007, The Science of the total environment.

[27]  Timothy G Gutowski,et al.  What gets recycled: an information theory based model for product recycling. , 2007, Environmental science & technology.

[28]  Dominic Wittmer,et al.  Exploration of urban deposits: long-term prospects for resource and waste management , 2007, Waste management & research : the journal of the International Solid Wastes and Public Cleansing Association, ISWA.

[29]  M. Minguillón,et al.  Recreational atmospheric pollution episodes: Inhalable metalliferous particles from firework displays , 2007 .

[30]  Sabina C. Grund,et al.  Antimony and Antimony Compounds , 2006 .

[31]  T. Graedel,et al.  Metal stocks and sustainability , 2006, Proceedings of the National Academy of Sciences of the United States of America.

[32]  Robert J. Klee,et al.  ELEMENTAL CYCLES: A Status Report on Human or Natural Dominance , 2004 .

[33]  K. Adachi,et al.  Characterization of heavy metal particles embedded in tire dust. , 2004, Environment international.

[34]  E. Landa,et al.  Tire-wear particles as a source of zinc to the environment. , 2004, Environmental science & technology.

[35]  Paolo Fornasiero,et al.  Automotive catalytic converters: current status and some perspectives , 2003 .

[36]  Colin R. Janssen,et al.  Runoff rates and ecotoxicity of zinc induced by atmospheric corrosion. , 2001, The Science of the total environment.

[37]  Adisa Azapagic,et al.  Indicators of Sustainable Development for Industry: A General Framework , 2000 .

[38]  B. Langner Selenium and selenium compounds. , 2000, IARC monographs on the evaluation of the carcinogenic risk of chemicals to man.

[39]  E. Helmers Elements accompanying platinum emitted from automobile catalyst's , 1996 .

[40]  Giancarla Alberti,et al.  Environmental vanadium distribution from an industrial settlement , 1996 .

[41]  R. Ayres,et al.  Toxic heavy metals: materials cycle optimization. , 1992, Proceedings of the National Academy of Sciences of the United States of America.

[42]  H. H. Sisler Nitric acid: Manufacture and uses (Miles, Frank Douglas) , 1962 .

[43]  Julian M. Allwood,et al.  Squaring the Circular Economy: The Role of Recycling within a Hierarchy of Material Management Strategies , 2014 .

[44]  Adisa Azapagic,et al.  Options for broadening and deepening the LCA approaches , 2010 .

[45]  Robert U. Ayres,et al.  Industrial Metabolism: Theory and Policy , 2005 .

[46]  P. Enghag Encyclopedia of the Elements: Technical Data - History - Processing - Applications , 2004 .

[47]  J. Loebenstein Materials Flow of Arsenic in the United States , 1994 .

[48]  H. Holzmann Platinum Recovery in Ammonia Oxidation Plants A NEW PROCESS USING GOLD-PALLADIUM CATCHMENT GAUZES , 1969 .