A Miniaturised, Fully Integrated NDIR CO2 Sensor On-Chip

In this paper, we present a fully integrated Non-dispersive Infrared (NDIR) CO2 sensor implemented on a silicon chip. The sensor is based on an integrating cylinder with access waveguides. A mid-IR LED is used as the optical source, and two mid-IR photodiodes are used as detectors. The fully integrated sensor is formed by wafer bonding of two silicon substrates. The fabricated sensor was evaluated by performing a CO2 concentration measurement, showing a limit of detection of ∼750 ppm. The cross-sensitivity of the sensor to water vapor was studied both experimentally and numerically. No notable water interference was observed in the experimental characterizations. Numerical simulations showed that the transmission change induced by water vapor absorption is much smaller than the detection limit of the sensor. A qualitative analysis on the long term stability of the sensor revealed that the long term stability of the sensor is subject to the temperature fluctuations in the laboratory. The use of relatively cheap LED and photodiodes bare chips, together with the wafer-level fabrication process of the sensor provides the potential for a low cost, highly miniaturized NDIR CO2 sensor.

[1]  Jürgen Wöllenstein,et al.  A Wireless Gas Sensor Network to Monitor Indoor Environmental Quality in Schools , 2018, Sensors.

[2]  J. Jimenez,et al.  Exhaled CO2 as a COVID-19 Infection Risk Proxy for Different Indoor Environments and Activities , 2021, Environmental science & technology letters.

[3]  Peter Enoksson,et al.  A miniaturized optical gas-composition sensor with integrated sample chamber , 2016 .

[4]  R. Tatam,et al.  Optical gas sensing: a review , 2012 .

[5]  L. Morawska,et al.  It Is Time to Address Airborne Transmission of Coronavirus Disease 2019 (COVID-19) , 2020, Clinical Infectious Diseases.

[6]  Gunther Roelkens,et al.  On-Chip Non-Dispersive Infrared CO2 Sensor Based on an Integrating Cylinder † , 2019, Sensors.

[7]  Frank K Tittel,et al.  Mid-infrared absorption-spectroscopy-based carbon dioxide sensor network in greenhouse agriculture: development and deployment. , 2016, Applied optics.

[8]  J. L. Jimenez,et al.  Exhaled CO2 as COVID-19 infection risk proxy for different indoor environments and activities , 2020, medRxiv.

[9]  D. Milton,et al.  Risk of indoor airborne infection transmission estimated from carbon dioxide concentration. , 2003, Indoor air.

[10]  E. R. Polovtseva,et al.  The HITRAN2012 molecular spectroscopic database , 2013 .

[11]  Daqiang Zhang,et al.  A Survey on Gas Sensing Technology , 2012, Sensors.

[12]  Walter Lang,et al.  Merging ethylene NDIR gas sensors with preconcentrator-devices for sensitivity enhancement , 2012 .

[13]  Tyler A. Jacobson,et al.  Direct human health risks of increased atmospheric carbon dioxide , 2019, Nature Sustainability.

[14]  P. Xie,et al.  Water Vapor Interference Correction in a Non Dispersive Infrared Multi-Gas Analyzer , 2011 .

[15]  Ralph P. Tatam,et al.  Non-dispersive infra-red (NDIR) measurement of carbon dioxide at 4.2μm in a compact and optically efficient sensor , 2013 .

[16]  Ke Chen,et al.  Highly sensitive photoacoustic gas sensor based on multiple reflections on the cell wall , 2019, Sensors and Actuators A: Physical.

[17]  Chenyang Xue,et al.  Development of an Optical Gas Leak Sensor for Detecting Ethylene, Dimethyl Ether and Methane , 2013, Sensors.

[18]  C. Noakes Role of Ventilation in Controlling SARS-CoV-2 Transmission SAGE-EMG , 2020 .

[19]  J. DeSimone,et al.  CO2 Technology Platform: An Important Tool for Environmental Problem Solving. , 2001, Angewandte Chemie.

[20]  I. Eisele,et al.  Smart capacitive CO2 sensor , 2016, 2016 IEEE SENSORS.

[21]  R. Schooley,et al.  Reducing transmission of SARS-CoV-2 , 2020, Science.

[22]  Markus Niederberger,et al.  When Nanoparticles Meet Poly(Ionic Liquid)s: Chemoresistive CO2 Sensing at Room Temperature , 2015 .