R-phase transition and related mechanical properties controlled by low-temperature aging treatment in a Ti–50.8 at.% Ni thin wire

A cold-drawn Ti–50.8 at.% Ni wire was annealed at 600 °C for 30 min, followed by aging at 250 °C for different times. A microstructure with small grains and nanoscaled precipitates was obtained. The thermally induced martensite transformation is suppressed in the samples aged for 4 h or longer, leaving a one-stage R-phase transition between −150 and +150 °C. The transformation behavior, work output and recovery stress associated with the R-phase transition are presented.

[1]  Shuichi Miyazaki,et al.  Shape-memory effect and pseudoelasticity associated with the R-phase transition in Ti-50·5 at.% Ni single crystals , 1988 .

[2]  Shuichi Miyazaki,et al.  Effect of thermal cycling on the transformation temperatures of TiNi alloys , 1986 .

[3]  H. Matsumoto Transformation behaviour with thermal cycling in NiTi alloys , 2003 .

[4]  Hisaaki Tobushi,et al.  Thermomechanical properties due to martensitic and R-phase transformations of TiNi shape memory alloy subjected to cyclic loadings , 1996 .

[5]  Shuichi Miyazaki,et al.  Deformation and transition behavior associated with theR-phase in Ti-Ni alloys , 1986 .

[6]  X. Ren,et al.  Physical metallurgy of Ti–Ni-based shape memory alloys , 2005 .

[7]  Yong Liu,et al.  Effect of annealing on the transformation behavior and superelasticity of NiTi shape memory alloy , 2001 .

[8]  G. G. Stokes "J." , 1890, The New Yale Book of Quotations.

[9]  D. Schryvers,et al.  Electron-diffraction structure refinement of Ni4Ti3 precipitates in Ni52Ti48. , 2006, Acta crystallographica. Section B, Structural science.

[10]  P. McCormick,et al.  Three stage transformation behaviour in aged NiTi , 1993 .

[11]  K. K. Mahesh,et al.  Effect of thermal cycling on R-phase stability in a NiTi shape memory alloy , 2002 .

[12]  Shuichi Miyazaki,et al.  Mechanical behaviour associated with the premartensitic rhombohedral-phase transition in a Ti50Ni47Fe3alloy , 1985 .

[13]  D. Schryvers,et al.  Quantitative determination of strain fields around Ni4Ti3 precipitates in NiTi , 2005 .

[14]  Hyeon-Cheol Kim,et al.  Effect of R-phase heat treatment on torsional resistance and cyclic fatigue fracture. , 2013, Journal of endodontics.

[15]  Yufeng Zheng,et al.  Effect of ageing treatment on the transformation behaviour of Ti–50.9 at.% Ni alloy , 2008 .

[16]  H. Matsumoto Appearance of an intermediate phase with thermal cycling on the transformation of NiTi , 1991 .

[17]  Jun Sun,et al.  Origin of 2-stage R-phase transformation in low-temperature aged Ni-rich Ti–Ni alloys , 2005 .

[18]  V. Novák,et al.  R-phase transformation phenomena in thermomechanically loaded NiTi polycrystals , 2006 .

[19]  C. M. Wayman,et al.  Electron microscopy studies of the “Premartensitic” transformations in an aged Ti-51 at%Ni shape memory alloy , 1988 .

[20]  Yinong Liu,et al.  Ageing-induced two-stage R-phase transformation in Ti – 50.9at.%Ni , 2004 .

[21]  Yong Du,et al.  Simulation of the electron diffraction patterns from needle/rod-like precipitates in Al-Mg-Si alloys , 2011 .

[22]  D. Schryvers,et al.  Linking a completely three-dimensional nanostrain to a structural transformation eigenstrain. , 2009, Nature materials.

[23]  B. Verlinden,et al.  Effect of grain size on aging microstructure as reflected in the transformation behavior of a low-temperature aged Ti–50.8 at.% Ni alloy , 2013 .