论文信息 - (2,2-Dichlorovinyl)ferrocene

(2,2-Dichlorovinyl)ferrocene

The title compound, [Fe(C5H5)(C7H5Cl2)], represents a versatile building block for the preparation of π-conjugated redox-active compounds or polymetallic organometallic systems due to the presence of the electrochemically active ferrocenyl unit. It is therefore a potential starting material for the preperation of the corresponding alkyne. In the crystal, the alkenyl unit and the cyclopentadienide ring are almost parallel, with an angle between the best planes of only 10.6 (4)°.

[1] Yong‐Min Liang,et al. An Improving Method For the Preparation of Ethynylferrocene , 2000 .

[2] S. Clément,et al. (2,2‐Dibromovinyl)ferrocene as a Building Block for the Assembly of Heterodinuclear Complexes – Preparation of an σ‐Alkenylpalladium Complex and Dimetallic Dithioether Complexes , 2007 .

[3] S. Clément,et al. Ethynyl[2.2]paracyclophanes and 4-isocyano[2.2]paracyclophane as ligands in organometallic chemistry , 2007 .

[4] 良二上田. J. Appl. Cryst.の発刊に際して , 1970 .

[5] G. Sheldrick. A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[6] Sujit Roy,et al. Novel Catalytic Hunsdiecker−Heck (CHH) Strategy toward All-E Stereocontrolled Ferrocene-Capped Conjugated Push−Pull Polyenes , 2000 .

[7] B. Robinson,et al. Deamination of 1-aminoethylferrocene and the crystal structure of ethenylferrocene , 2008 .

[8] Louis J. Farrugia,et al. ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) , 1997 .

[9] J. Schwartz,et al. Organometallics , 1987, Science.