Surface compositions across Pluto and Charon

New Horizons unveils the Pluto system In July 2015, the New Horizons spacecraft flew through the Pluto system at high speed, humanity's first close look at this enigmatic system on the outskirts of our solar system. In a series of papers, the New Horizons team present their analysis of the encounter data downloaded so far: Moore et al. present the complex surface features and geology of Pluto and its large moon Charon, including evidence of tectonics, glacial flow, and possible cryovolcanoes. Grundy et al. analyzed the colors and chemical compositions of their surfaces, with ices of H2O, CH4, CO, N2, and NH3 and a reddish material which may be tholins. Gladstone et al. investigated the atmosphere of Pluto, which is colder and more compact than expected and hosts numerous extensive layers of haze. Weaver et al. examined the small moons Styx, Nix, Kerberos, and Hydra, which are irregularly shaped, fast-rotating, and have bright surfaces. Bagenal et al. report how Pluto modifies its space environment, including interactions with the solar wind and a lack of dust in the system. Together, these findings massively increase our understanding of the bodies in the outer solar system. They will underpin the analysis of New Horizons data, which will continue for years to come. Science, this issue pp. 1284, 10.1126/science.aad9189, 10.1126/science.aad8866, 10.1126/science.aae0030, & 10.1126/science.aad9045 Pluto and Charon have surfaces dominated by volatile ices, with large variations in color and albedo. INTRODUCTION The Kuiper Belt hosts a swarm of distant, icy objects ranging in size from small, primordial planetesimals to much larger, highly evolved objects, representing a whole new class of previously unexplored cryogenic worlds. Pluto, the largest among them, along with its system of five satellites, has been revealed by NASA’s New Horizons spacecraft flight through the system in July 2015, nearly a decade after its launch. RATIONALE Landforms expressed on the surface of a world are the product of the available materials and of the action of the suite of processes that are enabled by the local physical and chemical conditions. They provide observable clues about what processes have been at work over the course of time, the understanding of which is a prerequisite to reconstructing the world’s history. Materials known to exist at Pluto’s surface from ground-based spectroscopic observations include highly volatile cryogenic ices of N2 and CO, along with somewhat less volatile CH4 ice, as well as H2O and C2H6 ices and more complex tholins that are inert at Pluto surface temperatures. Ices of H2O and NH3 are inert components known to exist on Pluto’s large satellite Charon. New Horizons’ Ralph instrument was designed to map colors and compositions in the Pluto system. It consists of a charge-coupled device camera with four color filters spanning wavelengths from 400 to 970 nm plus a near-infrared imaging spectrometer covering wavelengths from 1.25 to 2.5 μm, where the various cryogenic ices are distinguishable via their characteristic vibrational absorption features. RESULTS New Horizons made its closest approach to the system on 14 July 2015. Observations of Pluto and Charon obtained that day reveal regionally diverse colors and compositions. On Pluto, the color images show nonvolatile tholins coating an ancient, heavily cratered equatorial belt. A smooth, thousand-kilometer plain must be able to refresh its surface rapidly enough to erase all impact craters. Infrared observations of this region show volatile ices including N2 and CO. H2O ice is not detected there, but it does appear in neighboring regions. CH4 ice appears on crater rims and mountain ridges at low latitudes and is abundant at Pluto’s high northern latitudes. Pluto’s regional albedo contrasts are among the most extreme for solar system objects. Pluto’s large moon Charon offers its own surprises. Its H2O ice–rich surface is unlike other outer solar system icy satellites in exhibiting distinctly reddish tholin coloration around its northern pole as well as a few highly localized patches rich in NH3 ice. CONCLUSION Pluto exhibits evidence for a variety of processes that act to modify its surface over time scales ranging from seasonal to geological. Much of this activity is enabled by the existence of volatile ices such as N2 and CO that are easily mobilized even at the extremely low temperatures prevalent on Pluto’s surface, around 40 K. These ices sublimate and condense on seasonal time scales and flow glacially. As they move about Pluto’s surface environment, they interact with materials such as H2O ice that are sufficiently rigid to support rugged topography. Although Pluto’s durable H2O ice is probably not active on its own, it appears to be sculpted in a variety of ways through the action of volatile ices of N2 and CO. CH4 ice plays a distinct role of its own, enabled by its intermediate volatility. CH4 ice condenses at high altitudes and on the winter hemisphere, contributing to the construction of some of Pluto’s more unusual and distinctive landforms. The latitudinal distribution of Charon’s polar reddening suggests a thermally controlled production process, and the existence of highly localized patches rich in NH3 ice on its surface implies relatively recent emplacement. Enhanced color view of Pluto’s surface diversity This mosaic was created by merging Multispectral Visible Imaging Camera color imagery (650 m per pixel) with Long Range Reconnaissance Imager panchromatic imagery (230 m per pixel). At lower right, ancient, heavily cratered terrain is coated with dark, reddish tholins. At upper right, volatile ices filling the informally named Sputnik Planum have modified the surface, creating a chaos-like array of blocky mountains. Volatile ice occupies a few nearby deep craters, and in some areas the volatile ice is pocked with arrays of small sublimation pits. At left, and across the bottom of the scene, gray-white CH4 ice deposits modify tectonic ridges, the rims of craters, and north-facing slopes. The New Horizons spacecraft mapped colors and infrared spectra across the encounter hemispheres of Pluto and Charon. The volatile methane, carbon monoxide, and nitrogen ices that dominate Pluto’s surface have complicated spatial distributions resulting from sublimation, condensation, and glacial flow acting over seasonal and geological time scales. Pluto’s water ice “bedrock” was also mapped, with isolated outcrops occurring in a variety of settings. Pluto’s surface exhibits complex regional color diversity associated with its distinct provinces. Charon’s color pattern is simpler, dominated by neutral low latitudes and a reddish northern polar region. Charon’s near-infrared spectra reveal highly localized areas with strong ammonia absorption tied to small craters with relatively fresh-appearing impact ejecta.

[1]  B. Schmitt,et al.  Near-Infrared Spectroscopy of Simple Hydrocarbons and Carbon Oxides Diluted in Solid N2and as Pure Ices: Implications for Triton and Pluto , 1997 .

[2]  Robert E. Johnson,et al.  Gas transfer in the Pluto–Charon system: A Charon atmosphere , 2014 .

[3]  Nicolas Fray,et al.  Sublimation of ices of astrophysical interest: A bibliographic review , 2009 .

[4]  C. M. Lisse,et al.  The Pluto system: Initial results from its exploration by New Horizons , 2015, Science.

[5]  Marc William Buie,et al.  The Distribution and Physical State of H2O on Charon , 2000 .

[6]  D. Paige,et al.  Pluto's climate modeled with new observational constraints , 2015 .

[7]  W. Grundy,et al.  Near-infrared spectral monitoring of Triton with IRTF/SpeX II: Spatial distribution and evolution of ices , 2009, 0908.2623.

[8]  R. Binzel,et al.  Hemispherical Color Differences on Pluto and Charon , 1988, Science.

[9]  Dale P. Cruikshank,et al.  Evidence for Methane Segregation at the Surface of Pluto , 2013 .

[10]  Dale P. Cruikshank,et al.  Thermal properties of Pluto’s and Charon’s surfaces from Spitzer observations , 2011 .

[11]  D. Reuter,et al.  Anticipated Scientific Investigations at the Pluto System , 2008 .

[12]  Dennis C. Reuter,et al.  Logarithmically variable infrared etalon filters , 1994, Optics & Photonics.

[13]  Stuart McMuldroch,et al.  Ralph: A Visible/Infrared Imager for the New Horizons Pluto/Kuiper Belt Mission , 2005, SPIE Optics + Photonics.

[14]  D. Strobel,et al.  The atmosphere of Pluto as observed by New Horizons , 2016, Science.

[15]  D. Strobel,et al.  Pluto’s interaction with its space environment: Solar wind, energetic particles, and dust , 2016, Science.

[16]  D. E. Jennings,et al.  The small satellites of Pluto as observed by New Horizons , 2016, Science.

[17]  W. Grundy,et al.  Evidence for longitudinal variability of ethane ice on the surface of Pluto , 2014, 1406.1748.

[18]  L. Trafton On the state of methane and nitrogen ice on Pluto and Triton: Implications of the binary phase diagram , 2015 .

[19]  R. Kaiser,et al.  ELECTRON IRRADIATION OF KUIPER BELT SURFACE ICES: TERNARY N2–CH4–CO MIXTURES AS A CASE STUDY , 2012 .

[20]  M. W. Buie,et al.  Near-infrared spectral monitoring of Pluto’s ices: Spatial distribution and secular evolution , 2013, 1301.6284.

[21]  S. Sandford,et al.  ICE CHEMISTRY ON OUTER SOLAR SYSTEM BODIES: ELECTRON RADIOLYSIS OF N2-, CH4-, AND CO-CONTAINING ICES , 2015, The Astrophysical journal.

[22]  T. Lauer,et al.  The geology of Pluto and Charon through the eyes of New Horizons , 2016, Science.

[23]  B. Cobb,et al.  An Experimental Approach , 1957 .

[24]  L A Young,et al.  Surface Ices and the Atmospheric Composition of Pluto , 1993, Science.

[25]  W. Calvin,et al.  Evidence for crystalline water and ammonia ices on Pluto's satellite charon. , 2000, Science.

[26]  B. Cheng,et al.  SPECTRA AND PHOTOLYSIS OF PURE NITROGEN AND METHANE DISPERSED IN SOLID NITROGEN WITH VACUUM–ULTRAVIOLET LIGHT , 2012 .

[27]  Marla H. Moore,et al.  Infrared study of ion-irradiated N2-dominated ices relevant to Triton and Pluto: formation of HCN and HNC , 2003 .

[28]  M. W. Buie,et al.  Orbits and Photometry of Pluto’s Satellites: Charon, S/2005 P1, and S/2005 P2 , 2005, astro-ph/0512491.

[29]  A. Coradini,et al.  Structure and Evolution of Kuiper Belt Objects and Dwarf Planets , 2008 .

[30]  L. A. Young,et al.  Overview of the New Horizons Science Payload , 2007, Space Science Reviews.

[31]  S. Sandford,et al.  ICE CHEMISTRY ON OUTER SOLAR SYSTEM BODIES: CARBOXYLIC ACIDS, NITRILES, AND UREA DETECTED IN REFRACTORY RESIDUES PRODUCED FROM THE UV PHOTOLYSIS OF N2:CH4:CO-CONTAINING ICES , 2014 .

[32]  Uwe Fink,et al.  The Separate Spectra of Pluto and its Satellite Charon , 1987 .

[33]  R. Binzel,et al.  Pluto’s insolation history: Latitudinal variations and effects on atmospheric pressure , 2015 .

[34]  M. Astrofisica,et al.  On the atmospheres of objects in the Kuiper Belt , 2014 .

[35]  T. Owen,et al.  Water Ice on Triton , 2000 .

[36]  William M. Grundy,et al.  The Temperature-Dependent Spectrum of Methane Ice I between 0.7 and 5 μm and Opportunities for Near-Infrared Remote Thermometry , 2002 .

[37]  B. Carry,et al.  Spectral variability of Charon’s 2.21-μm feature , 2015 .

[38]  Robert E. Johnson Effect of irradiation on the surface of Pluto , 1989 .

[39]  S. Stern,et al.  On the roles of escape erosion and the viscous relaxation of craters on Pluto , 2014, 1412.1405.

[40]  Eliot F. Young,et al.  PLUTO AND CHARON WITH THE HUBBLE SPACE TELESCOPE. II. RESOLVING CHANGES ON PLUTO’S SURFACE AND A MAP FOR CHARON , 2010 .

[41]  Ivan R. Linscott,et al.  New Horizons: Anticipated Scientific Investigations at the Pluto System , 2008 .

[42]  NASA Ames Research Center,et al.  The Mauna Kea Observatories Near-Infrared Filter Set. III. Isophotal Wavelengths and Absolute Calibration , 2005 .

[43]  G. Strazzulla,et al.  Evolution of icy surfaces : an experimental approach , 1998 .

[44]  B. Buratti Voyager disk resolved photometry of the Saturnian satellites , 1984 .

[45]  J. Masiero,et al.  PHOTOMETRY OF PLUTO 2008–2014: EVIDENCE OF ONGOING SEASONAL VOLATILE TRANSPORT AND ACTIVITY , 2015 .

[46]  M. Moorea,et al.  Infrared study of ion-irradiated N 2-dominated ices relevant to Triton and Pluto : formation of HCN and HNC , 2003 .

[47]  G Mazzarella,et al.  [Bibliographic review]. , 1978, Archivio stomatologico.

[48]  Manabu Kato,et al.  Experimental study on the rheological properties of polycrystalline solid nitrogen and methane: Implications for tectonic processes on Triton , 2010 .

[49]  Tzu-Ping Huang,et al.  ULTRAVIOLET AND INFRARED SPECTRA OF ELECTRON-BOMBARDED SOLID NITROGEN AND METHANE DILUTED IN SOLID NITROGEN , 2013 .

[50]  Ted L. Roush,et al.  Near-Infrared Spectroscopy of Charon: Possible Evidence for Cryovolcanism on Kuiper Belt Objects , 2006 .

[51]  T. Owen,et al.  Ices on the Surface of Triton , 1993, Science.

[52]  J. Richardson,et al.  Proton Irradiation of Centaur, Kuiper Belt, and Oort Cloud Objects at Plasma to Cosmic Ray Energy , 2003 .

[53]  Marc William Buie,et al.  Spatial and Compositional Constraints on Non-ice Components and H2O on Pluto's Surface , 2002 .

[54]  Glenn Schneider,et al.  Hubble Space Telescope NICMOS Spectroscopy of Charon’s Leading and Trailing Hemispheres , 2001 .

[55]  A. Domaracka,et al.  Radiolysis of ammonia-containing ices by energetic, heavy, and highly charged ions inside dense astrophysical environments , 2009, 0910.3595.

[56]  J. M. Ward,et al.  Photometry of Triton 1992–2004: Surface volatile transport and discovery of a remarkable opposition surge , 2011 .

[57]  E. H. Darlington,et al.  Long-Range Reconnaissance Imager on New Horizons , 2007, 0709.4278.

[58]  Larry A. Lebofsky,et al.  Water frost on Charon , 1987, Nature.