Early transition metal hydride complexes: synthesis and reactivity
暂无分享,去创建一个
[1] P. Berno,et al. Reaction of a Vanadium(III) Amide with H2: Isolation and Characterization of a Polynuclear Mixed‐Valence Polyhydrido–Nitrido Complex , 1995 .
[2] C. Housecroft,et al. Reactions of (.eta.-C5Me5)Ta(PMe3)(H)2(.eta.2-CHPMe2) and nature of the .eta.2-CHPMe2 ligand , 1991 .
[3] S. Shore,et al. The Effect of Solvent in the Reaction of Cp2ZrH{(μ-H)2BC4H8} with B(C6F5)3: Formation of [HB(C6F5)3]- Salts of the Unsupported Hydrogen-Bridged Cation [(μ-H){Cp2Zr(μ-H)2BC4H8}2]+ and the Cation [Cp2Zr(OEt2)(OEt)]+ , 2000 .
[4] D. Stephan,et al. Catalytic synthesis of the P16 macrocycle (C6H4P2)8 , 1997 .
[5] S. Shore,et al. Cyclic Hydroborate Complexes of Metallocenes II: Reactivity of (&mgr;-H)(2)(BC(5)H(10))(2) and Its Cyclic Derivative, [H(2)BC(5)H(10)](-); Synthesis of (eta(5)-C(5)H(5))(2)MCl(&mgr;-H)(2)BC(5)H(10) (M = Zr, Hf). , 1998, Inorganic chemistry.
[6] J. M. Lluch,et al. Synthesis and Spectroscopic Properties of Dihydrogen Isocyanide Niobocene [Nb(η5-C5H4SiMe3)2(η2-H2)(CNR)]+ Complexes. Experimental and Theoretical Study of the Blocked Rotation of a Coordinated Dihydrogen , 1997 .
[7] S. García-Yuste,et al. STUDIES ON THE INSERTION REACTIONS OF ACTIVATED ALKYNES INTO NB-H BONDS INHYDRIDE-NIOBOCENE COMPLEXES. X-RAY CRYSTAL STRUCTURES OF NB(ETA 5-C5H4SIME3 )2(H)ETA 2-RO2C(H)=C(H)CO2R (R=ME OR TBU) , 1996 .
[8] T. Koetzle,et al. Theoretical Predictions and Single-Crystal Neutron Diffraction and Inelastic Neutron Scattering Studies on the Reaction of Dihydrogen with the Dinuclear Dinitrogen Complex of Zirconium [P2N2]Zr(μ-η2-N2)Zr[P2N2], P2N2 = PhP(CH2SiMe2NSiMe2CH2)2PPh , 1999 .
[9] M. D. Fryzuk,et al. Synthesis and Bonding in the Diamagnetic Dinuclear Tantalum(IV) Hydride Species ([P2N2]Ta)2(μ-H)4 and the Paramagnetic Cationic Dinuclear Hydride Species {([P2N2]Ta)2(μ-H)4}+I- ([P2N2] = PhP(CH2SiMe2NSiMe2CH2)2PPh): The Reducing Ability of a Metal−Metal Bond , 2000 .
[10] I. Hierro,et al. Chemistry of η2-CS2 Niobocene Complexes: Synthesis and Characterization of New 1,3-Dithiol-2-ylidene Complexes via Reactions with Activated Alkynes , 1996 .
[11] Samuel A. Johnson,et al. New mode of coordination for the dinitrogen ligand: formation, bonding, and reactivity of a tantalum complex with a bridging N(2) unit that is both side-on and end-on. , 2001, Journal of the American Chemical Society.
[12] J. Bercaw,et al. Preparation and Structural Characterization of an Enantiomerically Pure, C2-Symmetric, Single-Component Ziegler−Natta α-Olefin Polymerization Catalyst , 1996 .
[13] C. T. Wee,et al. Insertion and C−H Bond Activation of Unsaturated Substrates by Bis(benzamidinato)yttrium Alkyl, [PhC(NSiMe3)2]2YR (R = CH2Ph·THF, CH(SiMe3)2), and Hydrido, {[PhC(NSiMe3)2]2Y(μ-H)}2, Compounds , 1996 .
[14] G. Bazan,et al. Hydrogenation Mechanisms in (Boratacycle)tantalum Analogues of Dimethylzirconocene , 1999 .
[15] J. Fernández-Baeza,et al. Synthesis and Characterization of the First Niobocene Germyl Complexes and Reactivity of Triphenylsilyl-, Triphenylgermyl-, and Triphenylstannylniobocene Derivatives. X-ray Molecular Structures of d0 Nb(η5-C5H4SiMe3)2(H)2(EPh3) (E = Ge, Sn) , 1998 .
[16] V. Bakhmutov,et al. Tantalum-Gold and Tantalum-Copper Trihydride Complexes [Cp'(2)TaH(3)MPPh(3)][PF(6)] (Cp' = C(5)H(4)C(CH(3))(3)). Structure Determination from (1)H T(1) Relaxation Studies. , 1999, Inorganic chemistry.
[17] J. Bercaw,et al. Pentamethylcyclopentadienyl—aminoborole derivatives of zirconium and hafnium with alkyl and allyl ligands , 1997 .
[18] K. Schenk,et al. BIFUNCTIONAL CARRIERS OF ORGANOMETALLIC FUNCTIONALITIES : ALKALI-METAL-ZIRCONIUM-HYDRIDO, -ALKYL, AND -ALLYL DERIVATIVES OF MESO-OCTAETHYLPORPHYRINOGE N AND THEIR REACTION WITH ISOCYANIDES , 1995 .
[19] R. Duchateau,et al. C-H Activation of Arenes and Substituted Arenes by the Yttrium Hydride (Cp*2YH)2: Competition between Cp* Ligand Metalation, Arene Metalation, and H/D Exchange. Molecular Structures of Cp*2Y(μ-H)(μ-η1,η5-CH2C5Me4)YCp* and Cp*2Y(o-C6H4PPh2CH2) , 1993 .
[20] Malcolm L. H. Green,et al. Group 5 ansa-Metallocenes: Structural and Dynamic Properties of Tetrahydroborate Complexes , 2000 .
[21] W. Jones,et al. CARBON-FLUORINE BOND CLEAVAGE BY ZIRCONIUM METAL HYDRIDE COMPLEXES , 1999 .
[22] P. Carroll,et al. Synthesis of mono- and bis(silyl) complexes of tantalum , 1991 .
[23] R. Bergman,et al. Dihydrogen Activation by Titanium Sulfide Complexes. , 1999, Organometallics.
[24] W. Lukens,et al. Synthesis and Structure of Cp*2TiH, Cp*2TiH2Li(tmed), and [Cp*2TiOLi(THF)]2 , 1998 .
[25] M. Thornton-Pett,et al. Cationic Zirconocene Hydrides: A New Type of Highly Effective Initiators for Carbocationic Polymerizations , 1999 .
[26] D. Roddick,et al. Reactions of alkyl and hydride derivatives of permethylzirconocene and permethylhafnocene with carbon monoxide. Synthesis and reactivity studies of aldehyde complexes of zirconium and hafnium , 1989 .
[27] G. Mcgrady. Molecules with hydride or alkyl ligands and including d0 transition metal centers: problem cases for the simple VSEPR model , 2000 .
[28] T. Tilley,et al. Structure and Reactivity of Chelating Imido−Amido Complexes of Tantalum. Mechanistic Studies on the Addition of Silanes to Ta−N Multiple Bonds , 1997 .
[29] A. Otero,et al. SYNTHESIS AND CHARACTERIZATION OF NEW ALKYL-CARBON DIOXIDE COMPOUNDS AND THE FIRST NEUTRAL ACYL-CARBONYL NIOBOCENE COMPLEXES , 1997 .
[30] P. Fanwick,et al. Reactivity of Tantalum Hydride Aryloxide Complexes toward Organic Isocyanide Reagents , 1996 .
[31] D. Stephan,et al. Niobium and Tantalum Diphosphanato Complexes: Synthesis, Structure, and NMR Studies of Cp2MH[(PR)2] (R = Ph, Cy, H) , 1997 .
[32] J. Okuda,et al. Chiral complexes of titanium containing a linked amido-cyclopentadienyl ligand: synthesis, structure, and asymmetric imine hydrogenation catalysis , 2000 .
[33] H. Brunner,et al. Heterobimetallic Complexes Bridged by a Single 4e Sulfur Ligand: Addition of M'(CO)5 (M' = Cr, Mo, W) to the Ta:S Bond of (t-BuC5H4)2Ta(S)H , 1995 .
[34] D. Stephan,et al. Reactivity of Decamethylzirconocene Trihydride Anion with Protic Reagents , 2000 .
[35] H. Brunner,et al. Metallocene sulfide chemistry of niobium and tantalum: new insights into the formation of niobium-polysulfido complexes and synthesis, structure, and reactivity of Cp2'Ta(.eta.2-S2)H (Cp' = tert-BuC5H4) , 1992 .
[36] J. Bercaw,et al. Synthesis and reactivity of permethyltantalocene derivatives processing .eta.3-allyl, .eta.2-butadiene, .eta.2-methylallene, and .eta.1-alkenylidene ligands. Model studies for the role of surface vinylidenes in the Fischer-Tropsch hydrocarbon-chain-lengthening process , 1991 .
[37] J. H. Teuben,et al. SYNTHESIS AND STRUCTURE OF BIS(PHENYLTETRAMETHYLCYCLOPENTADIENYL)TITANIUM(III) HYDRIDE - THE FIRST MONOMERIC BIS(CYCLOPENTADIENYL)TITANIUM(III) HYDRIDE: The First Monomeric Bis(cyclopentadienyl)titanium(III) Hydride , 1995 .
[38] F. Cotton,et al. The [Zr6X18H5]3− Ions with X = Cl, Br, and Related Species , 1995 .
[39] W. Schaefer,et al. Model Ziegler-Natta .alpha.-Olefin Polymerization Catalysts Derived from[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}(PMe3)Sc(.mu.2-H)]2 and[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}Sc(.mu.2-CH2CH2CH3)]2. Synthesis, Structures, and Kinetic and Equilibrium Investigations of the Catalytically Active Species in Solut , 1994 .
[40] W. Schaefer,et al. Oxo-hydrido and imido-hydrido derivatives of permethyltantalocene. Structures of (.eta.5-C5Me5)2Ta(:O)H and (.eta.5-C5Me5)2Ta(:NC6H5)H: doubly or triply bonded tantalum oxo and imido ligands? , 1992 .
[41] P. Fanwick,et al. Zirconium-catalyzed, highly regioselective hydrosilation reaction of alkenes and X-ray structures of silyl(hydrido)zirconocene derivatives , 1991 .
[42] W. Schaefer,et al. Synthesis and characterization of (η5-C5Me5)2TaCl(THF), a useful synthetic precursor for the preparation of oxo, imido and methylidene derivatives of permethyltantalocene , 1993 .
[43] M. D. Fryzuk,et al. Synthesis, characterization, and reactivity of scandium chloro, alkyl, aryl, and borohydride complexes, Sc(η5-C5H5)R[N(SiMe2CH2PiPr2)2] (R = Cl, Me, Ph, and BH4) , 2000 .
[44] T. Marks,et al. Organometallic thermochemistry. Metal hydrocarbyl, hydride, halide, carbonyl, amide, and alkoxide bond enthalpy relationships and their implications in pentamethylcyclopentadienyl and cyclopentadienyl complexes of zirconium and hafnium , 1988 .
[45] W. Lukens,et al. SYNTHESIS, STRUCTURE, AND REACTIONS OF (ETA 5-C5H5)3ZR , 1995 .
[46] J. Arnold,et al. Tethered Bis-Amidinates as Supporting Ligands: A Concerted Elimination/σ-π Rearrangement Reaction Forming an Unusual Titanium Arene Complex. , 1998, Angewandte Chemie.
[47] W. Schaefer,et al. Pentamethylcyclopentadienyl-dicarbollide derivatives of scandium , 1993 .
[48] D. Stephan,et al. Catalytic Oligomerization of Primary Phosphines by the Anionic Zirconocene Trihydride: [Cp*2ZrH3]- , 1995 .
[49] J. Bercaw,et al. ON THE MECHANISM OF DIHYDROGEN ADDITION TO TANTALOCENE COMPLEXES , 1998 .
[50] U. Rothlisberger,et al. Ditantalum Hydride Complexes with Bridging (2,6-iPr2C6H3)NSiHPh Silanimine Ligands Resulting from PhSiH3-Imido Ligand Coupling. A Combined Spectroscopic and Theoretical Investigation , 2000 .
[51] D. Stephan,et al. STERICALLY INDUCED P-C BOND CLEAVAGE : ROUTES TO SUBSTITUENT-FREE PHOSPHORUS COMPLEXES OF ZIRCONIUM , 1995 .
[52] K. Mach,et al. Synthesis and structure of a novel .mu.-dimethyldimethylenecyclopentenyl bis(.mu.-hydrido) mixed-valence titanium(III)/titanium(II) compound , 1993 .
[53] Y. Mu,et al. Use of Alkane Elimination in the One-Step Synthesis of Organoscandium Complexes Containing a New Multidentate Cyclopentadienyl Ligand , 1996 .
[54] T. Tilley,et al. Synthesis, characterization, and reactivity of triphenylsilyl, triphenylgermyl, and triphenylstannyl derivatives of zirconium and hafnium , 1992 .
[55] Dietmar Seyferth,et al. Comprehensive Organometallic Chemistry , 1984 .
[56] Z. Wu,et al. Reactions of tetrakis(dimethylamide)-titanium, -zirconium and -hafnium with silanes: synthesis of unusual amide hydride complexes and mechanistic studies of titanium-silicon-nitride (Ti-Si-N) formation. , 2001, Journal of the American Chemical Society.
[57] J. Fernández-Baeza,et al. Exchange Coupling in Niobocene Trihydrides, Nb(C5H3RR')2H3, and Their Adducts with Copper Triad Cations, ({Nb(C5H3RR')2H3}2M) + (R ) R' ) H; R ) H, R') SiMe3; R ) R' ) SiMe3 ;M )Cu, Ag, Au) , 1996 .
[58] S. Buchwald,et al. Syntheses of [ethylene-1,2-bis(.eta.5-4,5,6,7-tetrahydro-1-indenyl)]zirconium and -hafnium hydride complexes. Improved syntheses of the corresponding dichlorides , 1991 .
[59] J. Bercaw,et al. Synthesis of Singly and Doubly Bridgedansa-Zirconocene Hydrides. Formation of an Unusual Mixed Valence Trimeric Hydride by Reaction of H_2 with {(Me_2Si)_2(η^5-C_5H_3)_2}Zr(CH_3)_2and Generation of a Dinitrogen Complex by Reaction of N_2 with a Zirconocene Dihydride , 2001 .
[60] H. Woo,et al. Synthesis and Crystal Structure of Some Novel Titanocene Phosphido Compounds by P−H Activation in the Presence of Hydrosilanes , 1997 .
[61] P. Carroll,et al. Agostic .beta.-silicon-hydrogen interactions in silylamido complexes of zirconocene , 1994 .
[62] J. Mayer,et al. Synthesis and reactivity of new polyhydride compounds of tantalum(V) , 1982 .
[63] G. Nikonov,et al. Insertion of ClPPh2 into a Ta-H bond: Synthesis and Structure of the First Phosphido Derivative of Tantalocene , 1995 .
[64] G. Nikonov,et al. THE FIRST ARSENIDO-SUBSTITUTED NIOBOCENE DERIVATIVE , 1995 .
[65] P. Fanwick,et al. Reactions of Alkynes and Olefins with Tantalum Hydrides Containing Aryloxide Ancillary Ligation: Relevance to Catalytic Hydrogenation† , 1999 .
[66] G. Parkin,et al. Telluroformaldehyde, tellurido, and ditellurido derivatives of permethyltantalocene , 1994 .
[67] J. H. Teuben,et al. THE DECEPTIVELY SIMPLE THERMOLYSIS OF TRIVALENT PERMETHYLTITANOCENE DERIVATIVES (ETA-5-C5ME5)2TIR - FORMATION OF A TETRAMETHYLFULVENE TITANIUM COMPOUND (ETA-6-C5ME4CH2)(ETA-5-C5ME5)TI AND RH, CATALYZED BY PERMETHYLTITANOCENE HYDRIDE, (ETA-5-C5ME5)2TIH , 1992 .
[68] E. Coughlin. Iso-specific Ziegler-Natta polymerization of α-olefins with a single-component organoyttrium catalyst , 1992 .
[69] M. Hursthouse,et al. Synthesis and structure of zirconium complex [Me2C(C5H4)(Flu)Zr(.mu.-H)Cl]2, an .eta.3:.eta.5-bonded ansa-metallocene , 1993 .
[70] Samuel A. Johnson,et al. NEW MODE OF COORDINATION FOR THE DINITROGEN LIGAND : A DINUCLEAR TANTALUM COMPLEX WITH A BRIDGING N2 UNIT THAT IS BOTH SIDE-ON AND END-ON , 1998 .
[71] J. Schwartz,et al. Synthesis and reactivity of (dialkylacetylene)niobium(III) complexes and derivatives. Contrast between protonation and methylation pathways , 1975 .
[72] J. H. Teuben,et al. A remarkable Lewis acid-base adduct: Preparation and structure of [TaH5(dmpe)(2)][LiHBEt3] (dmpe=1,2-bis(dimethylphosphino)ethane) , 1997 .
[73] J. H. Teuben,et al. Pentamethylcyclopentadienyl Zirconium and Hafnium Polyhydride Complexes : Synthesis, Structure, and Reactivity , 2001 .
[74] J. Bercaw,et al. Synthesis and characterization of thioaldehyde hydride derivatives of permethyltantalocene. Investigations of their equilibration with thiolates and the stereochemistry of alkyl migrations from sulfur to tantalum , 1992 .
[75] B. Chaudret,et al. Synthesis, X-ray crystal structure, NMR characterization and theoretical calculations on [Cp2Ta(η2-H2)(CO)]+, the first thermally stable group 5 dihydrogen complex , 2001 .
[76] Merz,et al. van't Hoff-Le Bel Stranger: Formation of a Phosphonium Cation with a Planar Tetracoordinate Phosphorus Atom. , 1999, Angewandte Chemie.
[77] P. Power,et al. Reaction of cyclopentadienyl zirconium derivatives with sterically encumbered arylaluminum hydrides: X-ray crystal structure of (η5-C5H5)2(H)Zr(μ2-H)2Al(H)C6H2-2,4,6-But3 , 1999 .
[78] M. Hall,et al. Transition Metal Polyhydride Complexes. 9. The Effect of Ligand σ- and π-Bonding on the H−Ta−H Bond Angle in Six-Coordinate Tantalum(V) Dihydride Complexes , 1998 .
[79] I. Beletskaya,et al. Reactivity of lanthanide and yttrium hydrides and hydrocarbyls toward organosilicon hydrides and related compounds , 1997 .
[80] J. H. Teuben,et al. Regioselective homo- and codimerization of alpha-olefins catalyzed by bis(2,4,7-trimethylindenyl)yttrium hydride , 1998 .
[81] P. T. Wolczanski,et al. Insertion of H2C=CHX (X = F, Cl, Br, O(i)Pr) into (tBu3SiO)3TaH2 and beta-X-Elimination from (tBu3SiO)3HTaCH2CH2X (X = OR): relevance to Ziegler-Natta copolymerizations. , 2001, Journal of the American Chemical Society.
[82] Y. Kai,et al. Facile synthesis and stereochemistry of alkyne complexes of Cp2MH and Cp2MCH2CH2R (M = niobium, tantalum) , 1991 .
[83] C. Raston,et al. HYDRIDE-BRIDGED HETEROBIMETALLIC COMPLEXES OF ZIRCONIUM AND ALUMINUM , 1997 .
[84] M. Horáček,et al. ACTIVATION OF THE (TRIMETHYLSILYL)TETRAMETHYLCYCLOPENTADIENYL LIGAND IN THE C5ME4(SIME3)2TICL2/MG SYSTEM, YIELDING INTRAMOLECULAR SI-CH2-MG AND SI-CH2 -TI BONDS. MOLECULAR STRUCTURES OF ETA 5-C5ME4SIME2(MU -CH2MG,MG)ETA 5-C5ME 4(SIME3)TIIII (MU -H)2MG(THF)2 AND ETA 5:ETA 1-C5ME4SIME2CH2(ETA 5-C5ME4( , 1997 .
[85] D. L. Ward,et al. Group 5 Metallocene Complexes as Models for Metal-Mediated Hydroboration: Synthesis of a Reactive Borane Adduct, endo-Cp*2Nb(H2BO2C6H4), via Hydroboration of Coordinated Olefins , 1997 .
[86] R. Grubbs,et al. α-Agostic Interactions and Olefin Insertion in Metallocene Polymerization Catalysts , 1996 .
[87] B. Gautheron,et al. Composés métallocèniques chalcogènés. Action des dihydrures de zirconocène et de hafnocène sur le soufre, le sélénium et le tellure , 1989 .
[88] D. Stephan,et al. The Main Group Macrocycle , 2001, Angewandte Chemie.
[89] Hyosun Lee,et al. Synthesis and Structural Characterization of {[Me2Si(C5Me4)2]Zr(η2-C2H4)H}2Mg: An ansa-Zirconocene Ethylene−Hydride Complex , 1998 .
[90] W. Schaefer,et al. HIGHLY ELECTRON DEFICIENT GROUP 3 ORGANOMETALLIC COMPLEXES BASED ON THE 1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE LIGAND SYSTEM , 1997 .
[91] J. Britten,et al. Reactions of bis(indenyl)dimethyltitanium with phenylsilane: synthesis of a novel (.mu.-indenyl-.mu.-dihydrido) mixed-valence Ti(III)/Ti(II) compound , 1992 .
[92] R. Lazzaroni,et al. Synthesis and structure of the niobium(III) phosphido complex (C5H5)2Nb(CO)(P-iso-PrPh): efficient Gauche effect and low inversion barrier in bent-metallocene chemistry , 1992 .
[93] P. Hitchcock,et al. A Non-Metallocene Hydride of Titanium(III) , 1999 .
[94] Yundong Wu,et al. Synthesis and structure of an unusual zirconium hydride amide complex. Mechanistic studies of the reactions of transition-metal amides with silanes , 1999 .
[95] B. Gautheron,et al. Synthese et reactivite de nouveaux dihydrurozirconocenes et -hafnocenes substitues achiraux et chiraux , 1980 .
[96] W. M. Davis,et al. Synthesis, characterization, and reactivity of zirconocene and hafnocene silyl hydride complexes , 1991 .
[97] Y. Mu,et al. Reactions of silanes with bis(cyclopentadienyl)dialkylzirconium complexes , 1991 .
[98] J. Majoral,et al. Zirconium Species as Tools in Phosphorus Chemistry, 1 [Cp2ZrHCI]n, a Versatile Reagent , 1996 .
[99] J. Atwood,et al. Photoinduced reactions of (.eta.5-C5H5)2MH3 and (.eta.5-C5H5)2M(CO)H (M = Nb, Ta) and the molecular structure of (.eta.5-C5H5)2Ta(CO)H , 1982 .
[100] P. Fanwick,et al. Isolation of a new series of seven-coordinate hydride compounds of tantalum(V) and their involvement in the catalytic hydrogenation of arene rings , 1991 .
[101] R. F. Jordan,et al. THF ring-opening and hydrogen/deuterium exchange reactions of (C5H4Me)2Zr(H)(THF)+. Evidence for hydrogenolysis of zirconium-cyclopentadiene bonds , 1992 .
[102] G. Parkin,et al. Selenium complexes of permethyltantalocene. Interesting contrasts with their tellurium analogues , 1995 .
[103] C. Schaverien. Alkoxides as ancillary ligands in organolanthanide chemistry: synthesis of, reactivity of, and olefin polymerization by the .mu.-hydride-.mu.-alkyl compounds [Y(C5Me5)(OC6H3tBu2)]2(.mu.-H)(.mu.-alkyl) , 1994 .
[104] Ronghua Shu,et al. Titanocene(III) catalyzed homogeneous hydrosilation-hydrogenation of pyridines , 2001 .
[105] P. Meunier,et al. Synthesis, x-ray structure and electrochemical study of [{.eta.5-C5H4C(CH3)3}2ZrH(.mu.-H)]2. Identification of the [{.eta.5-C5H4C(CH3)3}]2ZrH2 anion radical by EPR spectroscopy , 1991 .
[106] G. Duyne,et al. Syntheses, carbonylations, and dihydrogen exchange studies of monomeric and dimeric silox ([sup 1]Bu[sub 3]SiO[sup [minus]]) hydrides of tantalum. Structure of [(silox)[sub 2]TaH[sub 2]][sub 2] , 1993 .
[107] F. Cotton,et al. Pentanuclear Zirconium Clusters with Chloride, Hydride, and Phosphine Ligands , 1994 .
[108] M. Eisen,et al. Catalytic Isomerization and Disproportionation of Olefins Promoted by Group 4/d0 Benzamidinate Complexes , 1999 .
[109] J. Bercaw,et al. Preparation and characterization of monomeric and dimeric group IV metallocene dihydrides having alkyl-substituted cyclopentadienyl ligands , 1999 .
[110] D. Stephan,et al. The Anionic Zirconocene Trihydride: [Cp*2ZrH3]- , 1997 .
[111] A. Otero,et al. Synthesis and Characterization of New Silyl Niobocene Complexes. X-ray Molecular Structure of d.degree. Nb(.eta.5-C5H4SiMe3)2(H)2(SiPh2H) , 1995 .
[112] J. Bercaw,et al. Alkanediyl and related derivatives of permethylhafnocene , 1992 .
[113] I. Guzei,et al. The Ansa-Effect in Zirconocene Chemistry: The Syntheses and Interconversions of the Hydride Complexes {[Me2Si(C5Me4)2]Zr(H)(μ-H)}2, [Me2Si(C5Me4)2]ZrH2(PMe3), and [Me2Si(C5Me4)2]Zr(Ph)H , 1998 .
[114] T. Tilley,et al. Carbonylation Chemistry of the Tantalum Silyl Hydride Cp*(2,6-iPr2C6H3N)Ta[Si(SiMe3)3]H: The Unexpected Formation of a Ta(V) Carbonyl Complex and the Complete Reduction of CO , 1999 .
[115] G. Nikonov,et al. CP2NBH2SBPH2 : SYNTHESIS AND STRUCTURE OF THE FIRST ANTIMONY-SUBSTITUTED NIOBOCENE , 1997 .
[116] J. Jaud,et al. Synthesis, characterization, and chemical reactivity of zirconium dihydride [(C5H4R)2Zr(.mu.-H)H]2 (R = SiMe3, CMe3). H/D exchange reactions of anionic species [(C5H4R)2ZrH2]-. X-ray crystal structure of [(C5H4SiMe3)2Zr(.mu.-H)H]2 , 1993 .
[117] J. Harrod,et al. Identification of some intermediates in the titanocene-catalyzed dehydrogenative coupling of primary organosilanes , 1986 .
[118] G. Bazan,et al. Pentamethylcyclopentadienyl Borollide Complexes of Tantalum: New Group 4 Metallocene Mimics , 1995 .
[119] O. Blacque,et al. SYNTHESIS OF CP2'TA(SH)H2 FROM CP2'TA(=S)H (CP'=ETA 5-T-BUC5H4) AND ITS APPLICATION IN THE PREPARATION OF NEW HYDROSULFIDO-BRIDGED HETEROBIMETALLIC CO MPLEXES , 1997 .
[120] D. L. Ward,et al. Synthesis of endo-Cp2TaH2(BO2C6H4) and exo-Cp2TaH2(BO2C6H4): Regioisomers of the First Tantalum Boryl Complexes , 1994 .
[121] J. Arnold,et al. PREPARATION OF SCANDIUM COMPLEXES WITH BENZAMIDINATE LIGANDS : SYNTHESIS AND REACTIVITY OF ALKYL AND HYDRIDO DERIVATIVES , 1996 .
[122] G. Nikonov,et al. Facile insertion of ClPPh2 into Nb-H bonds as a synthetic route to new phosphino and phosphido derivatives of niobocene , 1994 .
[123] T. Tuinstra,et al. Alternatives for Cyclopentadienyl Ligands in Organoyttrium Chemistry: Bis(N,O-bis(tert-butyl)(alkoxydimethylsilyl)amido)yttrium Compounds , 1997 .
[124] J. Bercaw. BIS(PENTAMETHYLCYCLOPENTADIENYL)TITANIUM(II) AND ITS COMPLEXES WITH MOLECULAR NITROGEN , 1974 .
[125] J. Hartwig,et al. A Continuum Resulting from Equilibrium between Two Structural Extremes in Tungstenocene and Niobocene Boryl and Hydridoborate Complexes. .pi.-Bonding in a d2 Boryl System and the First d0 Boryl Complex , 1994 .