Synthesis, properties and applications of inorganic–organic copolymers (ORMOCER®s)

Hybrid inorganic-organic polymers based on organically modified heteropolysiloxanes have found widespread attention and application as materials with adjustable properties using tailor-made precursors. The chemical structures of monomers and their modified sol-gel processing method are described. An overview is given for the control of various properties (mechanical, electrical, optical) of the materials on a molecular scale. Successful material developments and industrial applications are described.

[1]  M. Schaub,et al.  ORMOCERs/sup TM/-new photo-patternable dielectric and optical materials for MCM-packaging , 1998, 1998 Proceedings. 48th Electronic Components and Technology Conference (Cat. No.98CH36206).

[2]  H. Wolter,et al.  A new silane precursor with reduced polymerization shrinkage , 1994 .

[3]  H. Wolter,et al.  Synthesis and characterization of the organic surface modifications of monodisperse colloidal silica , 1997 .

[4]  Bruce M. Novak,et al.  Hybrid nanocomposite materials―between inorganic glasses and organic polymers , 1993 .

[5]  Wolfgang Kiefer,et al.  Investigations on the organic crosslinking in ORMOCERs by means of Raman spectroscopy , 1998 .

[6]  J. Phalippou,et al.  Mechanical characterization of Ormosil films on plastics: Young's modulus determination by three points bending , 1994 .

[7]  H. Böttner,et al.  Preparation of membranes based on heteropolysiloxanes , 1985 .

[8]  Peter Dannberg,et al.  New Inorganic-Organic Hybrid Polymers for Integrated Optics , 1998 .

[9]  H. Wolter,et al.  Novel Carboxy Functionalized Sol-Gel Precursors , 1996 .

[10]  G. Schottner,et al.  Functional coatings on glass using ORMOCER®-systems , 1994 .

[11]  J. Schulz,et al.  A new inorganic-organic polymer for the passivation of thin film capacitors , 1994 .

[12]  G. Schottner,et al.  Industrial Application of Hybrid Sol-Gel Coatings for the Decoration of Crystal Glassware , 1998 .

[13]  W. Glaubitt,et al.  Multifunctional Acrylate Alkoxysilanes for Polymeric Materials. , 1992 .

[14]  K. G. Sharp.  Inorganic/Organic Hybrid Materials , 1998 .

[15]  H. Schmidt,et al.  Chemistry And Applications Of Inorganic-Organic Polymers (Organically Modified Silicates) , 1986 .

[16]  C. Sanchez,et al.  DESIGN OF HYBRID ORGANIC-INORGANIC MATERIALS SYNTHESIZED VIA SOL-GEL CHEMISTRY , 1994 .

[17]  M. Popall,et al.  Perfluoroaryl Substituted Inorganic-Organic Hybrid Materials , 1996 .

[18]  S. Amberg-schwab,et al.  Inorganic-Organic Polymers with Barrier Properties for Water Vapor, Oxygen and Flavors , 1998 .

[19]  Ulrich S. Schubert,et al.  Hybrid Inorganic-Organic Materials by Sol-Gel Processing of Organofunctional Metal Alkoxides , 1995 .

[20]  U. Wiesner,et al.  Multinuclear solid‐state‐NMR studies of hybrid organic‐inorganic materials , 1997 .

[21]  Milos Hayer,et al.  Organopolysiloxanes as Chemically Sensitive Coatings for Optical Fibers , 1998 .

[22]  Xin Du,et al.  Inorganic-organic copolymers as solid state ionic conductors with grafted anions , 1995 .

[23]  W. Glaubitt,et al.  Multifunctional (Meth)Acrylate Alkoxysilanes a New Type of Reactive Compounds , 1992 .

[24]  Michael Popall,et al.  ORMOCERs as inorganic-organic electrolytes for new solid state lithium batteries and supercapacitors , 1998 .

[25]  H. Wolter,et al.  New Inorganic/Organic Copolymers (Ormocer ® s) for Dental Applications , 1994 .

[26]  S. Amberg-schwab,et al.  Functionalized coating materials based on inorganic-organic polymers , 1999 .

[27]  G. Schottner,et al.  Functionalized coatings based on inorganic–organic polymers (ORMOCER®s) and their combination with vapor deposited inorganic thin films , 1999 .

[28]  J. Mackenzie,et al.  Mechanical properties of ormosils , 1996 .

[29]  T. Saegusa.  Organic-inorganic polymers hybrids , 1995 .

[30]  Albrecht Brandenburg,et al.  Integrated optical gas sensors using organically modified silicates as sensitive films , 1993 .

[31]  Keisuke Iwata,et al.  Physical properties and structure of organic-inorganic hybrid materials produced by sol-gel process , 1998 .