Capillary trapping in sandstones and carbonates: Dependence on pore structure

[1] Residual non-wetting phase saturation and wetting-phase permeability were measured in three limestones and four sandstones ranging in porosity from 0.13 to 0.28 and in absolute permeability from 2 × 10−15 to 3 × 10−12 m2. This paper focuses on the residual state established by waterflooding at low capillary number from minimum water saturation achieved using the porous plate technique, which yields the maximum residual under strongly water-wet conditions. The pore coordination number and pore body-throat aspect ratio of each rock were estimated using pore networks extracted from X-ray microtomography images of the rocks. Residual saturation decreases with increasing porosity, with no apparent difference in magnitude between the limestones and sandstones at a given porosity. Thus intraparticle/intra-aggregate microporosity does not significantly alter the efficiency of capillary trapping in the rocks considered presently. Residual saturation broadly decreases as conditions become less favorable for snap-off, i.e., with decreasing pore aspect ratio and increasing coordination number. The measured residual saturations imply that capillary trapping may be an effective mechanism for storing carbon dioxide in both sandstones and carbonates provided that the systems are strongly water-wet.

[1]  W. B. Lindquist,et al.  Pore and throat size distributions measured from synchrotron X-ray tomographic images of Fontaineble , 2000 .

[2]  M. H. Holtz Reservoir Characterization Applying Residual Gas Saturation Modeling, Example From the Starfak t1 Reservoir, Middle Miocene Gulf of Mexico , 2005 .

[3]  Chris Morriss,et al.  Core Analysis By Low-field Nmr , 1997 .

[4]  D. J. Bergman,et al.  Nuclear Magnetic Resonance: Petrophysical and Logging Applications , 2011 .

[5]  F. Dullien,et al.  Hydraulic continuity of residual wetting phase in porous media , 1986 .

[6]  J. Billiotte,et al.  Experimental Relationships Between Residual Gas Saturation And Initial Gas Saturation In Heterogeneous Sandstone Reservoirs , 2003 .

[7]  Stig Bakke,et al.  Reconstruction of Berea sandstone and pore-scale modelling of wettability effects , 2003 .

[8]  J. Kamath,et al.  Understanding Waterflood Residual Oil Saturation of Four Carbonate Rock Types , 2001 .

[9]  Norman C. Wardlaw,et al.  Pore-throat size correlation from capillary pressure curves , 1987 .

[10]  Carlon S. Land,et al.  Calculation of Imbibition Relative Permeability for Two- and Three-Phase Flow From Rock Properties , 1968 .

[11]  M. Blunt,et al.  Capillary-Trapping Capacity of Sandstones and Sandpacks , 2011 .

[12]  Billiotte Joël SCA2003-14: RESIDUAL GAS SATURATION OF SAMPLE ORIGINALLY AT RESIDUAL WATER SATURATION IN HETEROGENEOUS SANDSTONE RESERVOIRS , 2003 .

[13]  S. Redner,et al.  Introduction To Percolation Theory , 2018 .

[14]  Ruben Juanes,et al.  Impact of relative permeability hysteresis on geological CO2 storage , 2006 .

[15]  P. L. Churcher,et al.  Rock Properties of Berea Sandstone, Baker Dolomite, and Indiana Limestone , 1991 .

[16]  N. Morrow,et al.  INITIAL WATER SATURATION AND OIL RECOVERY FROM CHALK AND SANDSTONE BY SPONTANEOUS IMBIBITION , 1999 .

[17]  Ruben Juanes,et al.  A New Model of Trapping and Relative Permeability Hysteresis for All Wettability Characteristics , 2008 .

[18]  G. L. Stegemeier MECHANISMS OF ENTRAPMENT AND MOBILIZATION OF OIL IN POROUS MEDIA , 1977 .

[19]  A. T. Watson,et al.  Characterization of fluid distributions in porous media by NMR techniques , 1996 .

[20]  Martin J. Blunt,et al.  Predictive pore‐scale modeling of two‐phase flow in mixed wet media , 2004 .

[21]  Scott Kirkpatrick,et al.  An introduction to percolation theory , 1971 .

[22]  D. E. Elrick,et al.  Percolation processes and porous media: I. Geometrical and topological model of porous media using a three-dimensional joint pore size distribution , 1986 .

[23]  J. O. Amaefule,et al.  The Effect of Interfacial Tensions on Relative Oil/Water Permeabilities of Consolidated Porous Media , 1982 .

[24]  Robert Sok,et al.  ANALYSIS OF ROCK MICROSTRUCTURE USING HIGH- RESOLUTION X-RAY TOMOGRAPHY , 2006 .

[25]  Yuan Herbert Hi-Hwa The Influence of Pore Coordination on Petrophysical Parameters , 1981 .

[26]  W. B. Lindquist,et al.  3D image-based characterization of fluid displacement in a Berea core , 2007 .

[27]  M. J. Oak,et al.  Three-phase relative permeability of Berea sandstone , 1990 .

[28]  Morrel H. Cohen,et al.  Quantitative methods for microgeometric modeling , 1982 .

[29]  H. Ezzat Khalifa,et al.  Tables of the Dynamic and Kinematic Viscosity of Aqueous KCl Solutions in the Temperature Range 25-150 C and the Pressure Range 0.1-35 MPa, , 1981 .

[30]  Gianni Schena,et al.  X-ray tomography measurements of power-law cluster size distributions for the nonwetting phase in sandstones. , 2010, Physical review. E, Statistical, nonlinear, and soft matter physics.

[31]  T. Wong,et al.  Micromechanics of cataclastic pore collapse in limestone , 2010 .

[32]  N. Morrow,et al.  Correlation of capillary number relationships for sandstone , 1984 .

[33]  M. Blunt,et al.  Residual Saturation of Water-Wet Sandstones: Experiments, Correlations and Pore-Scale Modeling , 2010 .

[34]  A. Sheppard,et al.  Trapping thresholds in invasion percolation. , 2002, Physical review. E, Statistical, nonlinear, and soft matter physics.

[35]  Martin J Blunt,et al.  Pore-network extraction from micro-computerized-tomography images. , 2009, Physical review. E, Statistical, nonlinear, and soft matter physics.

[36]  J. W. Essam,et al.  Critical Percolation Probabilities by Series Methods , 1964 .

[37]  G. R. Jerauld,et al.  The effect of pore-structure on hysteresis in relative permeability and capillary pressure: Pore-level modeling , 1990 .

[38]  Susana Zeppieri,et al.  Interfacial Tension of Alkane + Water Systems† , 2001 .

[39]  P. Doyen,et al.  Permeability, conductivity, and pore geometry of sandstone , 1988 .

[40]  Ioannis Chatzis,et al.  Magnitude and Detailed Structure of Residual Oil Saturation , 1983 .

[41]  S. Marsden,et al.  Effect of Temperature Level upon Capillary Pressure Curves , 1971 .

[42]  N. Morrow,et al.  Effect of Wettability on Waterflood Recovery for Crude-Oil/Brine/Rock Systems , 1995 .

[43]  Suzanne Karine DISTRIBUTION OF TRAPPED GAS SATURATION IN HETEROGENEOUS SANDSTONE RESERVOIRS , 2001 .

[44]  N. Wardlaw,et al.  Estimation of Recovery Efficiency by Visual Observation of Pore Systems in Reservoir Rocks , 1979 .

[45]  A. Revil,et al.  In situ mineralogy and permeability logs from downhole measurements: Application to a case study in chlorite‐coated sandstones , 2003 .

[46]  C. Clauser,et al.  Study of the variation of thermal conductivity with water saturation using nuclear magnetic resonance , 2011 .

[47]  H. Westphal,et al.  NMR Measurements in Carbonate Rocks: Problems and an Approach to a Solution , 2005 .

[48]  N. Wardlaw Chapter 10 Factors affecting oil recovery from carbonate reservoirs and prediction of recovery , 1996 .

[49]  E. R. Cohen An Introduction to Error Analysis: The Study of Uncertainties in Physical Measurements , 1998 .

[50]  G. R. Jerauld,et al.  Prudhoe Bay Gas/Oil Relative Permeability , 1997 .

[51]  Edo S. Boek,et al.  Particulate invasion from drilling fluids , 2000 .

[52]  N. Gland,et al.  Hydromechanical behavior of heterogeneous carbonate rock under proportional triaxial loadings , 2011 .

[53]  J. Ziman The localization of electrons in ordered and disordered systems I. Percolation of classical particles , 1968 .

[54]  W. M. Haynes CRC Handbook of Chemistry and Physics , 1990 .

[55]  A. Cerepi,et al.  Pore microgeometry analysis in low-resistivity sandstone reservoirs , 2002 .

[56]  Ioannis Chatzis,et al.  Comprehensive Pore Structure Characterization Using 3D Computer Reconstruction and Stochastic Modeling , 1997 .

[57]  M. Blunt,et al.  Pore-scale imaging and modelling , 2013 .