Origins, current status, and future challenges of green chemistry.

Over the course of the past decade, green chemistry has demonstrated how fundamental scientific methodologies can protect human health and the environment in an economically beneficial manner. Significant progress is being made in several key research areas, such as catalysis, the design of safer chemicals and environmentally benign solvents, and the development of renewable feedstocks. Current and future chemists are being trained to design products and processes with an increased awareness for environmental impact. Outreach activities within the green chemistry community highlight the potential for chemistry to solve many of the global environmental challenges we now face. The origins and basis of green chemistry chart a course for achieving environmental and economic prosperity inherent in a sustainable world.

[1]  P. White,et al.  Rhodium(I)-catalyzed homologation of aromatic aldehydes with trimethylsilyldiazomethane. , 2001, Journal of the American Chemical Society.

[2]  Joan F. Brennecke,et al.  High-Pressure Phase Behavior of Ionic Liquid/CO2 Systems , 2001 .

[3]  K. R. Seddon,et al.  Stereoselective hydrogenation reactions in chloroaluminate(III) ionic liquids: a new method for the reduction of aromatic compounds , 1999 .

[4]  Krzysztof Matyjaszewski,et al.  Controlled/“Living” Radical Polymerization. Kinetics of the Homogeneous Atom Transfer Radical Polymerization of Styrene , 1997 .

[5]  Leo E. Manzer.  Chemistry and Catalysis: Keys to Environmentally Safer Processes , 1994 .

[6]  Robin D. Rogers,et al.  Room temperature ionic liquids as novel media for ‘clean’ liquid–liquid extraction , 1998 .

[7]  A. Russell,et al.  Biocatalytic Synthesis of Fluorinated Polyesters , 2000, Biotechnology progress.

[8]  M. Sedlák,et al.  Genetically EngineeredSaccharomycesYeasts for Conversion of Cellulosic Biomass to Environmentally Friendly Transportation Fuel Ethanol , 2000 .

[9]  Michael J. Bartos,et al.  The Design of Green Oxidants , 1999 .

[10]  Stephen K. Ritter.  ACCEPTING THE GREEN CHALLENGE: Presidential awards recognize innovative technologies that promote pollution prevention , 2001 .

[11]  Paul T. Anastas,et al.  Green chemistry : frontiers in benign chemical syntheses and processes , 1998 .

[12]  R. Breslow,et al.  Biomimetic selectivity. , 2001, Chemical record.

[13]  Mary M. Kirchhoff,et al.  Catalysis as a foundational pillar of green chemistry , 2001 .

[14]  David E. Bergbreiter.  Polymer-Facilitated Biphasic Catalysis , 2000 .

[15]  G. Thompson,et al.  Spinosad: A Green Natural Product for Insect Control , 2002 .

[16]  István T. Horváth,et al.  Fluorous Biphase Chemistry , 1998 .

[17]  Martyn Poliakoff,et al.  Continuous hydrogenation of organic compounds in supercriticalfluids , 1997 .

[18]  R. Waymouth,et al.  Alternating Ethene/Propene Copolymerization with a Metallocene Catalyst. , 1998, Angewandte Chemie.

[19]  G M Whitesides,et al.  Molecule-mimetic chemistry and mesoscale self-assembly. , 2001, Accounts of chemical research.

[20]  Walter Leitner,et al.  Carbon dioxide as an environmentally benign reaction medium for chemical synthesis , 2000 .

[21]  Geoffrey W. Coates,et al.  Catalytic Reactions Involving C1 Feedstocks: New High-Activity Zn(II)-Based Catalysts for the Alternating Copolymerization of Carbon Dioxide and Epoxides , 1998 .

[22]  H. Harry Szmant,et al.  Organic Building Blocks of the Chemical Industry , 1989 .

[23]  Hong Fu,et al.  Diffusion coefficients of model contaminants in dense CO2 , 2000 .

[24]  J. W. Frost,et al.  Benzene-free synthesis of hydroquinone. , 2001, Journal of the American Chemical Society.

[25]  L. Lynd,et al.  Biocommodity Engineering , 1999, Biotechnology progress.

[26]  Martyn Poliakoff,et al.  Continuous, selective hydroformylation in supercritical carbon dioxide using an immobilised homogeneous catalyst , 2000 .

[27]  Leo A. Paquette.  Indium‐Promoted Coupling Reactions in Water , 2001 .

[28]  朱文祥.  绿色化学的范例--介绍Real-World Cases In Green Chemistry , 2001 .

[29]  Martyn Poliakoff,et al.  Continuous Hydrogenation of Organic Compounds in Supercritical Fluids , 1997 .

[30]  Roger Jones,et al.  Supercritical CO2Carbonation of Cement and Cement-Fiber Composites: The Supramics Process , 2000 .

[31]  Ron Dagani,et al.  Tempest in a tiny tube , 2002 .

[32]  C. Eckert,et al.  Asymmetric hydrogenation and catalyst recycling using ionic liquid and supercritical carbon dioxide. , 2001, Journal of the American Chemical Society.

[33]  Gary W. Breton,et al.  A Grignard-like Organic Reaction in Water , 1998 .

[34]  Joan F. Brennecke,et al.  A Steady-State and Time-Resolved Fluorescence Study of Quenching Reactions of Anthracene and 1,2-Benzanthracene by Carbon Tetrabromide and Bromoethane in Supercritical Carbon Dioxide , 1997 .

[35]  Vittal K. Yachandra,et al.  Fluorous Biphasic Catalysis: Complexation of 1,4,7‐[C8F17(CH2)3]3‐1,4,7‐Triazacyclononane with [M(C8F17(CH2)2CO2)2] (M = Mn, Co) To Provide Perfluoroheptane‐Soluble Catalysts for Alkane and Alkene Functionalization in the Presence of t‐BuOOH and O2 , 1997 .

[36]  Gregory F. Payne,et al.  Enzymatic gelation of the natural polymer chitosan , 2000 .

[37]  U. Epa,et al.  Office of Pollution Prevention and Toxics , 2000 .

[38]  R. Sheldon,et al.  Efficient and selective aerobic oxidation of alcohols into aldehydes and ketones using ruthenium/TEMPO as the catalytic system. , 2001, Journal of the American Chemical Society.

[39]  Ana Aguiar-Ricardo,et al.  Fluorinated Graft Stabilizers for Polymerization in Supercritical Carbon Dioxide: The Effect of Stabilizer Architecture , 2001 .

[40]  Harold S. Freeman,et al.  Iron-Complexed Dyes: Colorants in Green Chemistry , 2000 .

[41]  Chao-Jun Li,et al.  Water as Solvent for Organic and Material Synthesis , 2000 .

[42]  P. Anastas,et al.  Green Chemistry , 2018, Environmental Science.

[43]  Stephen C. DeVito,et al.  General Principles for the Design of Safer Chemicals: Toxicological Considerations for Chemists , 1996 .

[44]  C H Heathcock,et al.  A simple biomimetic synthesis of styelsamine B. , 2001, Organic letters.

[45]  P. Anastas,et al.  Green Chemical Syntheses and Processes: Introduction , 2000 .

[46]  Vittal K. Yachandra,et al.  Fluorous Biphasic Catalysis: Complexation of 1,4,7‐[C8F17(CH2)3] 3‐1,4,7‐Triazacyclononane with [M(C8F17 (CH2)2CO2)2] (M: Mn, Co) to Provide Perfluoroheptane‐Soluble Catalysts for Alkane and Alkene Functionalization in the Presence of t‐BuOOH and O2. , 1998 .

[47]  Hiroshi Hachiya,et al.  New Process for Producing Polycarbonate Without Phosgene and Methylene Chloride , 1996 .

[48]  Paul T. Anastas,et al.  Life cycle assessment and green chemistry: the yin and yang of industrial ecology , 2000 .

[49]  Albert S. Matlack,et al.  Introduction to Green Chemistry , 2022 .

[50]  Hironori Arakawa,et al.  Direct splitting of water under visible light irradiation with an oxide semiconductor photocatalyst , 2001, Nature.

[51]  J. Walton,et al.  Programming Organic Molecules: Design and Management of Organic Syntheses through Free-Radical Cascade Processes. , 2001, Angewandte Chemie.

[52]  Mary M. Kirchhoff,et al.  Designing Safer Polymers , 2000 .

[53]  R. S. Boethling.  Designing Biodegradable Chemicals , 1996 .

[54]  Steven V. Ley,et al.  Synthesis of the potent analgesic compound (±)-epibatidine using an orchestrated multi-step sequence of polymer supported reagents , 1999 .

[55]  Stephen C. DeVito,et al.  Designing safer chemicals : green chemistry for pollution prevention : developed from a symposium sponsored by the Division of Environmenal Chemistry, Inc. , 1996 .

[56]  파울 바그너,et al.  Preparation and Use of Iminodisuccinic Acid Salts , 1998 .

[57]  Paul T. Anastas,et al.  Benign by Design: Alternative Synthetic Design for Pollution Prevention , 1994 .

[58]  James H. Clark,et al.  A novel Suzuki reaction system based on a supported palladium catalyst , 2001 .

[59]  Roger L. Garrett.  Pollution Prevention, Green Chemistry, and the Design of Safer Chemicals , 1996 .

[60]  R. Sheldon,et al.  A four-step enzymatic cascade for the one-pot synthesis of non-natural carbohydrates from glycerol. , 2000, The Journal of organic chemistry.

[61]  Eric J. Beckman,et al.  Combined Reaction-Separation Processes in CO2 , 2000 .

[62]  Stu Borman,et al.  ASYMMETRIC CATALYSIS WINS: Chemistry Nobel honors Knowles, Noyori, Sharpless for chiral syntheses , 2001 .

[63]  W. Hoelderich,et al.  ‘One-pot’ reactions: a contribution to environmental protection , 2000 .

[64]  B. Trost,et al.  A three-component coupling approach to cyclopentanoids. , 2001, The Journal of organic chemistry.

[65]  Ronald Breslow,et al.  Water as a Solvent for Chemical Reactions , 1999 .

[66]  Glyn Roberts,et al.  Friedel–Crafts reactions in room temperature ionic liquids , 1998 .