Ion current behaviors of mesoporous zeolite-polymer composite nanochannels prepared by water-assisted self-assembly.

Inspired by the asymmetry of biological ion channels in structure and composition, we designed a novel type of artificial asymmetric nanochannels based on mesoporous zeolite (MCM-41) and polyimide (PI) by water-assisted self-assembly. Meanwhile, we studied ionic current behaviors and rectifying characteristics of the mesoporous zeolite-polymer composite nanochannels.

[1]  Shaobin Wang,et al.  Ordered mesoporous materials for drug delivery , 2009 .

[2]  Jin Zhai,et al.  Light and pH Cooperative Nanofluidic Diode Using a Spiropyran‐Functionalized Single Nanochannel , 2012, Advanced materials.

[3]  T. Sakakura,et al.  Efficient catalysis of mesoporous Al-MCM-41 for Mukaiyama aldol reactions , 2009 .

[4]  Younan Xia,et al.  Pushing nanocrystal synthesis toward nanomanufacturing. , 2009, ACS nano.

[5]  Zeng-Qiang Wu,et al.  Solution‐pH‐Modulated Rectification of Ionic Current in Highly Ordered Nanochannel Arrays Patterned with Chemical Functional Groups at Designed Positions , 2013 .

[6]  Z. Siwy,et al.  Ion‐Current Rectification in Nanopores and Nanotubes with Broken Symmetry , 2006 .

[7]  Lei Jiang,et al.  Photo-induced current amplification in L-histidine modified nanochannels based on a highly charged photoacid in solution. , 2013, Chemical communications.

[8]  Xu Hou,et al.  - 1-Supporting Information Fabrication of Stable Single Nanochannels with Controllable Ionic Rectification , 2009 .

[9]  Jing-chao Tao,et al.  A novel Na+ coordination mediated supramolecular organogel based on isosteviol: water-assisted self-assembly, in situ forming and selective gelation abilities , 2013 .

[10]  Meihua Lu,et al.  Preparation of porous materials with ordered hole structure. , 2006, Advances in colloid and interface science.

[11]  Myungeun Seo,et al.  Lithographically Patterned Breath Figure of Photoresponsive Small Molecules: Dual‐Patterned Honeycomb Lines from a Combination of Bottom‐Up and Top‐Down Lithography , 2009 .

[12]  C. R. Martin,et al.  Developing synthetic conical nanopores for biosensing applications. , 2007, Molecular bioSystems.

[13]  Jin Zhai,et al.  Light‐Gating Titania/Alumina Heterogeneous Nanochannels with Regulatable Ion Rectification Characteristic , 2014 .

[14]  D. Woermann Electrochemical transport properties of a cone-shaped nanopore: high and low electrical conductivity states depending on the sign of an applied electrical potential difference , 2003 .

[15]  Martina H. Stenzel,et al.  Honeycomb structured polymer films via breath figures , 2012 .

[16]  Z. Siwy,et al.  Conical-nanotube ion-current rectifiers: the role of surface charge. , 2004, Journal of the American Chemical Society.

[17]  Mingzhong Cai,et al.  Diphosphino-Functionalized MCM-41-Immobilized Rhodium Complex: A Highly Efficient and Recyclable Catalyst for the Hydrophosphinylation of Terminal Alkynes , 2012, Catalysis Letters.

[18]  Olivier Sudre,et al.  Control of ionic transport through gated single conical nanopores , 2009, Analytical and bioanalytical chemistry.

[19]  Wei Wang,et al.  Nanofluidic diode in a suspended nanoparticle crystal , 2010 .

[20]  Jianfeng Chen,et al.  Mesoporous silica nanotubes coated with multilayered polyelectrolytes for pH-controlled drug release. , 2010, Acta biomaterialia.

[21]  Lei Jiang,et al.  Light-regulated ion transport through artificial ion channels based on TiO2 nanotubular arrays. , 2012, Chemical communications.

[22]  Q. Ouyang,et al.  Asymmetric properties of ion transport in a charged conical nanopore. , 2007, Physical review. E, Statistical, nonlinear, and soft matter physics.

[23]  Jang-Hoon Ha,et al.  Hydrogen storage characteristics of metal oxide doped Al–MCM-41 mesoporous materials , 2007 .

[24]  Ryan J. White,et al.  Biomimetic glass nanopores employing aptamer gates responsive to a small molecule. , 2010, Chemical communications.

[25]  Xu Hou,et al.  Building bio-inspired artificial functional nanochannels: from symmetric to asymmetric modification. , 2012, Angewandte Chemie.

[26]  P. Apel,et al.  Effect of nanopore geometry on ion current rectification , 2011, Nanotechnology.

[27]  G. Kalies,et al.  Cavitation and pore blocking in nanoporous glasses. , 2011, Langmuir : the ACS journal of surfaces and colloids.

[28]  Lei Jiang,et al.  Malachite Green Derivative–Functionalized Single Nanochannel: Light‐and‐pH Dual‐Driven Ionic Gating , 2012, Advanced materials.

[29]  J. Atwood,et al.  Water-assisted self-assembly of harmonic single and triple helices in a polymeric coordination complex. , 2005, Chemical communications.