Using COSMO-RS in the Design of Deep Eutectic Solvents for the Extraction of Antioxidants from Rosemary

Trial and error remain the most common method to select the right solvent for the extraction of natural products, in particular when dealing with novel, poorly studied solvents such as deep eutecti...

[1]  J. Romero,et al.  Design of natural deep eutectic solvents for the ultrasound-assisted extraction of hydroxytyrosol from olive leaves supported by COSMO-RS , 2020 .

[2]  J. Płotka-Wasylka,et al.  The role of water in deep eutectic solvent-base extraction , 2020 .

[3]  M. Marina,et al.  Sustainable extraction of proteins and bioactive substances from pomegranate peel (Punica granatum L.) using pressurized liquids and deep eutectic solvents , 2020 .

[4]  M. Minceva,et al.  Design of Deep Eutectic Systems: A Simple Approach for Preselecting Eutectic Mixture Constituents , 2020, Molecules.

[5]  M. R. Mafra,et al.  Deep eutectic solvents applied in the extraction and stabilization of rosemary (Rosmarinus officinalis L.) phenolic compounds , 2020 .

[6]  O. H. Gonçalves,et al.  Substitution of synthetic antioxidant by curcumin microcrystals in mortadella formulations. , 2019, Food chemistry.

[7]  J. Winterburn,et al.  Orange peel waste valorisation through limonene extraction using bio-based solvents , 2019, Biochemical Engineering Journal.

[8]  Maria Gonzalez-Miquel,et al.  Alkanediol-based deep eutectic solvents for isolation of terpenoids from citrus essential oil: Experimental evaluation and COSMO-RS studies , 2019, Separation and Purification Technology.

[9]  J. Morillas-Ruiz,et al.  Comparative study of rosemary extracts and several synthetic and natural food antioxidants. Relevance of carnosic acid/carnosol ratio. , 2019, Food chemistry.

[10]  Grzegorz Boczkaj,et al.  Deep eutectic solvents based highly efficient extractive desulfurization of fuels – Eco-friendly approach , 2019 .

[11]  João A. P. Coutinho,et al.  Using COSMO-RS to design choline chloride pharmaceutical eutectic solvents , 2019, Fluid Phase Equilibria.

[12]  Hongdeng Qiu,et al.  Effective extraction of flavonoids from Lycium barbarum L. fruits by deep eutectic solvents-based ultrasound-assisted extraction. , 2019, Talanta.

[13]  S. R. Ferreira,et al.  Which is the best food emerging solvent: IL, DES or NADES? , 2019, Trends in Food Science & Technology.

[14]  C. Theodoropoulos,et al.  Polyol-Based Deep Eutectic Solvents for Extraction of Natural Polyphenolic Antioxidants from Chlorella vulgaris , 2019, ACS Sustainable Chemistry & Engineering.

[15]  Maria Gonzalez-Miquel,et al.  Extraction of polyphenolic antioxidants from orange peel waste using deep eutectic solvents , 2018, Separation and Purification Technology.

[16]  Pengfei Zhou,et al.  Enhanced phenolic compounds extraction from Morus alba L. leaves by deep eutectic solvents combined with ultrasonic-assisted extraction , 2018, Industrial Crops and Products.

[17]  G. Ros,et al.  Antioxidant and Antimicrobial Properties of Rosemary (Rosmarinus officinalis, L.): A Review , 2018, Medicines.

[18]  João A. P. Coutinho,et al.  Insights into the Nature of Eutectic and Deep Eutectic Mixtures , 2018, Journal of Solution Chemistry.

[19]  P. Tůma,et al.  Menthol-based hydrophobic deep eutectic solvents: Towards greener and efficient extraction of phytocannabinoids , 2018, Journal of Cleaner Production.

[20]  P. Galtier,et al.  Refined exposure assessment of extracts of rosemary (E 392) from its use as food additive , 2018, EFSA journal. European Food Safety Authority.

[21]  P. Galtier,et al.  Re‐evaluation of propane‐1,2‐diol (E 1520) as a food additive , 2018, EFSA journal. European Food Safety Authority.

[22]  C. Brett,et al.  Deep eutectic solvents for the production and application of new materials , 2018 .

[23]  Tamal Banerjee,et al.  Liquid–Liquid Extraction of Lower Alcohols Using Menthol-Based Hydrophobic Deep Eutectic Solvent: Experiments and COSMO-SAC Predictions , 2018 .

[24]  Jason P. Hallett,et al.  Green and Sustainable Solvents in Chemical Processes. , 2018, Chemical reviews.

[25]  Pablo Navarro,et al.  Choline Chloride-Based Deep Eutectic Solvents in the Dearomatization of Gasolines , 2018 .

[26]  A. Klamt.  The COSMO and COSMO‐RS solvation models , 2018 .

[27]  T. Næs,et al.  Making sense of the "clean label" trends: A review of consumer food choice behavior and discussion of industry implications. , 2017, Food research international.

[28]  Maan Hayyan,et al.  New horizons in the extraction of bioactive compounds using deep eutectic solvents: A review. , 2017, Analytica chimica acta.

[29]  F. Cao,et al.  Tailor-made hydrophobic deep eutectic solvents for cleaner extraction of polyprenyl acetates from Ginkgo biloba leaves , 2017 .

[30]  Tao Wu,et al.  Green and efficient extraction of rutin from tartary buckwheat hull by using natural deep eutectic solvents. , 2017, Food chemistry.

[31]  M. Laguerre,et al.  Novel perspective on botanical extraction – Natural deep eutectic solvents (NaDES) as enhancers of biological activity , 2016, Planta Medica.

[32]  E. D. da Conceição,et al.  Multiresponse optimization of an extraction procedure of carnosol and rosmarinic and carnosic acids from rosemary. , 2016, Food chemistry.

[33]  E. Ida,et al.  Multi-response optimisation of the extraction solvent system for phenolics and antioxidant activities from fermented soy flour using a simplex-centroid design. , 2016, Food chemistry.

[34]  Y. Zu,et al.  Green extraction of five target phenolic acids from Lonicerae japonicae Flos with deep eutectic solvent , 2016 .

[35]  Y. Choi,et al.  Tailoring properties of natural deep eutectic solvents with water to facilitate their applications. , 2015, Food chemistry.

[36]  Emma L. Smith,et al.  Deep eutectic solvents (DESs) and their applications. , 2014, Chemical reviews.

[37]  E. Voutsas,et al.  Evaluation of COSMO-RS model in binary and ternary mixtures of natural antioxidants, ionic liquids and organic solvents , 2014 .

[38]  J. Chen,et al.  Extraction and separation of proteins by ionic liquid aqueous two-phase system. , 2013, The Analyst.

[39]  Geert-Jan Witkamp,et al.  Natural deep eutectic solvents as new potential media for green technology. , 2013, Analytica chimica acta.

[40]  María José Cocero,et al.  Assisted extraction of rosemary antioxidants with green solvents , 2012 .

[41]  R. Singh,et al.  Genesis and development of DPPH method of antioxidant assay , 2011, Journal of food science and technology.

[42]  Arnim Hellweg,et al.  TmoleX—A graphical user interface for TURBOMOLE , 2010, J. Comput. Chem..

[43]  A. Klamt,et al.  COSMO-RS as a tool for property prediction of IL mixtures—A review , 2010 .

[44]  A. Klamt,et al.  COSMO-RS: an alternative to simulation for calculating thermodynamic properties of liquid mixtures. , 2010, Annual review of chemical and biomolecular engineering.

[45]  J. Dolatabadi,et al.  A review on DNA interaction with synthetic phenolic food additives , 2010 .

[46]  R. K. Saxena,et al.  Microbial production and applications of 1,2-propanediol , 2010, Indian Journal of Microbiology.

[47]  Raymond K. Rasheed,et al.  Deep eutectic solvents formed between choline chloride and carboxylic acids: versatile alternatives to ionic liquids. , 2004, Journal of the American Chemical Society.

[48]  A. Klamt,et al.  Fast solvent screening via quantum chemistry: COSMO‐RS approach , 2002 .

[49]  O. Aruoma,et al.  Antioxidant and pro-oxidant properties of active rosemary constituents: carnosol and carnosic acid. , 1992, Xenobiotica; the fate of foreign compounds in biological systems.