Shedding of ash deposits

Abstract Ash deposits formed during fuel thermal conversion and located on furnace walls and on convective pass tubes, may seriously inhibit the transfer of heat to the working fluid and hence reduce the overall process efficiency. Combustion of biomass causes formation of large quantities of troublesome ash deposits which contain significant concentrations of alkali, and earth-alkali metals. The specific composition of biomass deposits give different characteristics as compared to coal ash deposits, i.e. different physical significance of the deposition mechanisms, lower melting temperatures, etc. Low melting temperatures make straw ashes especially troublesome, since their stickiness is higher at lower temperatures, compared to coal ashes. Increased stickiness will eventually lead to a higher collection efficiency of incoming ash particles, meaning that the deposit may grow even faster. Deposit shedding can be defined as the process of deposit removal from the heat transfer surfaces. Mechanical and thermal shock devices for deposit removal can be implemented within into the boiler, which can be then referred to as artificial shedding. Sootblowing is one such process, where a pressurized fluid is used to cause a mechanical and/or thermal shock that would cause a failure or fissure in the deposit. On the other hand, shedding can be caused without any operational or mechanical influence by erosion, gravity shedding, or simply by a thermal shock. The mechanism that will be dominant depends on the ash characteristics and the boiler operation. Different deposit characteristics will govern the ash deposit behaviour, and thus the mechanism of deposit shedding. The deposit strength will influence the erosion and gravity shedding mechanisms. The ash viscosity and the melting behaviour will govern the gravity shedding mechanism, while the thermal expansion coefficient will influence the thermal shock behaviour of the deposit.

[1]  I. Obernberger Decentralized biomass combustion: state of the art and future development 1 1 Paper to the keynote l , 1998 .

[2]  D. Hasselman Griffith Criterion and Thermal Shock Resistance of Single‐Phase Versus Multiphase Brittle Ceramics , 1969 .

[3]  H. Livbjerg,et al.  The formation of submicron aerosol particles, HCl and SO2 in straw-fired boilers , 1998 .

[4]  Eugene Ryshkewitch,et al.  Compression Strength of Porous Sintered Alumina and Zirconia , 1953 .

[5]  K. Dam-Johansen,et al.  Rheological properties of high-temperature melts of coal ashes and other silicates , 2001 .

[6]  D. Hasselman,et al.  Unified Theory of Thermal Shock Fracture Initiation and Crack Propagation in Brittle Ceramics , 1969 .

[7]  L. Douglas Smoot,et al.  Fundamentals of coal combustion : for clean and efficient use , 1993 .

[8]  A. W. Hull,et al.  Glass‐to‐Metal Seals. II , 1941 .

[9]  Larry L. Baxter,et al.  Boiler deposits from firing biomass fuels , 1996 .

[10]  E. Raask Erosion Wear In Coal Utilization , 1988 .

[11]  D. Hasselman Micromechanical Thermal Stresses and Thermal Stress Resistance of Porous Brittle Ceramics , 1969 .

[12]  Peter Glarborg,et al.  Combustion Chemistry - Activities in the CHEC Research Programme: Separate print from Power Plant Chemical Technology International Conference , 1996 .

[13]  A. Robinson,et al.  Experimental Measurements of the Thermal Conductivity of Ash Deposits: Part 2. Effects of Sintering and Deposit Microstructure , 2000 .

[14]  B. Latella,et al.  Effect of Porosity on the Erosive Wear of Liquid-Phase-Sintered Alumina Ceramics , 2004 .

[15]  F. Frandsen Utilizing biomass and waste for power production—a decade of contributing to the understanding, interpretation and analysis of deposits and corrosion products , 2005 .

[16]  J. Harb,et al.  Ash formation and deposition , 1993 .

[17]  K. Dam-Johansen,et al.  Influence of deposit formation on corrosion at a straw-fired boiler , 2000 .

[18]  W. D. Kingery,et al.  Introduction to Ceramics , 1976 .

[19]  Y. Oka,et al.  The impact angle dependence of erosion damage caused by solid particle impact , 1997 .

[20]  Terry Wall,et al.  Thermal conductivity of coal ash and slags and models used , 2000 .

[21]  M. I. Jameel,et al.  Sootblower optimization. Fundamental hydrodynamics of a sootblower nozzle and jet , 1994 .

[22]  P. Bernath,et al.  IN SITU ANALYSIS OF ASH DEPOSITS FROM BLACK LIQUOR COMBUSTION , 1996 .

[23]  Y. Oka,et al.  Practical estimation of erosion damage caused by solid particle impact: Part 2: Mechanical properties of materials directly associated with erosion damage , 2005 .

[24]  F. Frandsen,et al.  Ash Deposition Trials at Three Power Stations in Denmark , 1998 .

[25]  H. N. Tran,et al.  Sintering of fireside deposits and its impact on plugging in kraft recovery boilers , 1988 .

[26]  Peter Arendt Jensen,et al.  SEM Investigation of Superheater Deposits from Biomass-Fired Boilers , 2004 .

[27]  L. Holland,et al.  The properties of glass surfaces , 1964 .

[28]  Larry L. Baxter,et al.  Ash deposition during biomass and coal combustion: A mechanistic approach , 1993 .

[29]  G. P. Tilly,et al.  Study of Erosion by Solid Particles , 1969 .

[30]  Y. Oka,et al.  Relationship between surface hardness and erosion damage caused by solid particle impact , 1993 .

[31]  Peter Glarborg,et al.  Experimental investigation of ash deposit shedding in a straw-fired boiler , 2006 .

[32]  D. Chandra,et al.  Mineral Impurities in Coal Combustion , 1986 .

[33]  Kim Dam-Johansen,et al.  Deposition and High-Temperature Corrosion in Biomass-Fired Boilers , 1999 .

[34]  Bo Sander,et al.  Properties of Danish biofuels and the requirements for power production , 1997 .

[35]  P. Walsh,et al.  Deposition of bituminous coal ash on an isolated heat exchanger tube: Effects of coal properties on deposit growth , 1990 .

[36]  Seyed Abdolreza Ebrahimi-Sabet,et al.  A laboratory study of deposit removal by debonding and its application to fireside deposits in kraft recovery boilers , 2001 .

[37]  D. Hasselman Griffith Flaws and the Effect of Porosity on Tensile Strength of Brittle Ceramics , 1969 .

[38]  Y. Oka,et al.  Practical estimation of erosion damage caused by solid particle impact: Part 1: Effects of impact parameters on a predictive equation , 2005 .

[39]  Peter Glarborg,et al.  Heat transfer in ash deposits: A modelling tool-box , 2005 .

[40]  Honghi Tran,et al.  Effects of chemical composition on the removability of recovery boiler fireside deposits , 2001 .

[41]  S. Bhattacharya,et al.  The properties and thermal effects of ash deposits in coal-fired furnaces , 1993 .

[42]  G. Sundararajan,et al.  Solid particle erosion behaviour of metallic materials at room and elevated temperatures , 1997 .

[43]  Edward J. Garboczi,et al.  Elastic Properties of Model Porous Ceramics , 2000, cond-mat/0006334.

[44]  K. Hanjalić,et al.  Detonation-Wave Technique for On-Load Deposit Removal From Surfaces Exposed to Fouling: Part I—Experimental Investigation and Development of the Method , 1994 .

[45]  Peter Arendt Jensen,et al.  Deposition investigation in straw fired boilers , 1997 .

[46]  D. Hasselman Crack Growth and Creep in Brittle Ceramics , 1969 .