The coordination chemistry of carbon dioxide and its relevance for catalysis: a critical survey

[1]  B. P. Sullivan,et al.  Kinetics and mechanism of CO2 insertion into a metal-hydride bond. A large solvent effect and an inverse kinetic isotope effect , 1986 .

[2]  C. Lau,et al.  Hydrogenation of carbon dioxide to formic acid using a 6,6′-dichloro-2,2′-bipyridine complex of ruthenium,cis-[Ru(6,6′-Cl2bpy)2(H2O)2](CF3SO3)2 , 1995 .

[3]  D. Walther.  Homogeneous-catalytic reactions of carbon dioxide with unsatureated substrates, reversible CO2-carriers and transcarboxylation reactions , 1987 .

[4]  P. W. Jolly.  η3‐Allylpalladium Compounds , 1985 .

[5]  D. Darensbourg,et al.  Catalytic Activity of Zinc(II) Phenoxides Which Possess Readily Accessible Coordination Sites. Copolymerization and Terpolymerization of Epoxides and Carbon Dioxide , 1995 .

[6]  P. Jessop,et al.  Homogeneous catalytic hydrogenation of supercritical carbon dioxide , 1994, Nature.

[7]  Yi Pan,et al.  Carbon Dioxide as a Phosgene Replacement: Synthesis and Mechanistic Studies of Urethanes from Amines, CO2, and Alkyl Chlorides , 1995 .

[8]  M. Aresta,et al.  Carbon dioxide coordination chemistry. 3. Vibrational, NMR, theoretical studies of (carbon dioxide)bis(tricyclohexylphosphine)nickel , 1993 .

[9]  A. Behr.  Carbon Dioxide as an Alternative C1 Synthetic Unit: Activation by Transition‐Metal Complexes , 1988 .

[10]  H. Masuda,et al.  Ab initio Density Functional Calculations on Copper(I)–CO2 Coordinations , 1993 .

[11]  J. Bäckvall,et al.  Stereochemistry of copper- and nickel-catalyzed insertion of carbon dioxide into epoxides. A microwave study , 1981 .

[12]  J. Ibers,et al.  Studies on the reactions of carbon dioxide with transition metal complexes. Preparation and structure of .mu.-carbonato-pentakis(triphenylphosphine)dirhodium-benzene , 1976 .

[13]  W. Leitner,et al.  [()2RhH]‐ und [()2 Rh] [O2 CH]‐Komplexe als Modelle für die Katalytisch aktiven Zwischenstufen der Rh‐Katalysierten Hydrierung von CO2 zu HCOOH , 1993 .

[14]  T. Tsuda,et al.  Nickel(0)-Catalyzed Cycloaddition Copolymerization of Ether Diynes with Carbon Dioxide to Poly(2-pyrone)s , 1995 .

[15]  H. Nakajima,et al.  Multistep CO2 Reduction Catalyzed by [Ru(bpy)2(qu)(CO)]2+ (bpy = 2,2'-Bipyridine, qu = Quinoline). Double Methylation of the Carbonyl Moiety Resulting from Reductive Disproportionation of CO2 , 1995 .

[16]  G. Geoffroy,et al.  Addition and cycloaddition reactions of the nucleophilic oxo and sulfido complexes [tmtaa]Ti=X (X=O, S; tmtaa = dianion of 7,16-dihydro-6,8,15,17-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecine) , 1992 .

[17]  K. Nicholas,et al.  Rhodium-catalysed, carbon dioxide-mediated aerobic oxidation of ethers , 1992 .

[18]  I. Hierro,et al.  Electrochemical and chemical reduction of niobocene dichlorides in the presence of carbon dioxide , 1995 .

[19]  G. Geoffroy,et al.  Net [2 + 2] cycloaddition reactions of the oxo complexes Cp2M:O (M = Mo, W) with electrophilic organic and organometallic substrates. Formation of bimetallic .mu.2-.eta.3-CO2 complexes , 1990 .

[20]  Koji Tanaka.  Carbon Dioxide Fixation Catalyzed By Metal Complexes , 1995 .

[21]  P. Pérez,et al.  Rotational isomerism in bis(carbon dioxide) complexes of molybdenum generated by conrotatory motion of the CO2 ligands , 1990 .

[22]  D. Walther,et al.  Nickelacyclen als isolobale C8-Ringe: die Struktur von [(CH3CN)NiP(C6H11)3]4 und der Vergleich mit anderen Azaolefinkomplexen , 1988 .

[23]  J. Périchon,et al.  First example of direct carbon dioxide incorporation into 1,3-diynes: a highly regio- and stereo-selective nickel-catalysed electrochemical reaction , 1991 .

[24]  Y. Inoue,et al.  Direct synthesis of alkyl 2-alkynoates from alk-1-ynes, CO2, and bromoalkanes catalysed by copper(I) or silver(I) salt , 1994 .

[25]  W. J. Kruper,et al.  Catalytic Formation of Cyclic Carbonates from Epoxides and CO2 with Chromium Metalloporphyrinates , 1995 .

[26]  D. H. Gibson,et al.  Synthesis and characterization of .mu.2-.eta.2- and .mu.2-.eta.3-CO2 complexes of iron and rhenium , 1992 .

[27]  D. H. Gibson,et al.  Synthesis and Characterization of Carboxyethylene-Bridged Bimetallic Compounds , 1995 .

[28]  M. Aresta,et al.  Direct synthesis of 1,3-benzodioxol-2-one from styrene, dioxygen and carbon dioxide promoted by Rh(I) , 1987 .

[29]  L. Dahlenburg,et al.  Metallorganische verbindungen des iridiums und rhodiums ☆ ☆☆: XXIX. CO2-transformationen am trisphosphanrhodium(I)-komplex Rh(4-MeC6H4)[t-BuP(CH2CH2CH2PPh2)2] , 1985 .

[30]  I. Hisatsune,et al.  Infrared Spectrum of Carbon Dioxide Anion Radical , 1966 .

[31]  Ryoji Noyori,et al.  Homogeneous Hydrogenation of Carbon Dioxide , 1995 .

[32]  Tetsuya Hayashi,et al.  Preparation and properties of molybdenum and tungsten dinitrogen complexes. 38. Hydrido-carbonato, hydrido-carbamato, and carbon dioxide complexes of tungsten derived from the carbonyl-dinitrogen complex trans-[W(CO)(N2)(Ph2PCH2CH2PPh2)2] , 1992 .

[33]  J. Llorca,et al.  Activation of carbon dioxide by a silica-supported platinum–tin bimetallic complex , 1994 .

[34]  D. A. Palmer,et al.  THE CHEMISTRY OF METAL CARBONATO AND CARBON DIOXIDE COMPLEXES , 1983 .

[35]  K. Pandey.  Reactivities of carbonyl sulfide (COS), carbon disulfide (CS2) and carbon dioxide(CO2)with transition metal complexes , 1995 .

[36]  J. Mague,et al.  Formation of monometallic bis(bicarbonato) complexes of palladium(II) by the insertion of carbon dioxide into palladium(II)-hydroxide bonds , 1992 .

[37]  E. Fujita,et al.  Properties and reactivity of metallocarboxylates. Crystal and molecular structure of the -CO22--bridged "polymer" {[CoIII(en)2(CO2)](ClO4).cntdot.H2O}n , 1992 .

[38]  C. Floriani,et al.  Bifunctional activation of carbon dioxide. Synthesis and structure of a reversible carbon dioxide carrier , 1978 .

[39]  Walter Leitner,et al.  Carbon Dioxide as a Raw Material: The Synthesis of Formic Acid and Its Derivatives from CO2 , 1995 .

[40]  J. Field,et al.  Oxidation of diphosphazane-bridged derivatives of diruthenium nonacarbonyl by silver(I) salts in protic solvents: synthesis, structural characterization and protonation of the adduct [Ru2{µ-η2-OC(O)}(CO)4{µ-(RO)2PN(Et)P(OR)2}2](R = Me or Pri) involving a novel mode of co-ordination of carbon dioxide , 1993 .

[41]  K. Nicholas,et al.  Rhodium-catalyzed hydrogenation of carbon dioxide to formic acid , 1992 .

[42]  K. Nicholas,et al.  Reduction of coordinated carbon dioxide by transition-metal hydrides , 1991 .

[43]  V. Branchadell,et al.  Carbon dioxide rotational isomerism in bis(ethylene)(carbon dioxide)molybdenum complexes: a theoretical study , 1987 .

[44]  W. Leitner.  The Photochemical Activation of Carbon Dioxide Using a Nickel Complex , 1994 .

[45]  P. Hitchcock,et al.  A novel carbon dioxide complex: synthesis and crystal structure of [Nb(η-C5H4Me)2(CH2SiMe3)(η2-CO2)] , 1981 .

[46]  M. Aresta,et al.  Carbon dioxide)bis(trialkylphosphine)nickel complexes , 1977 .

[47]  Pierre Braunstein,et al.  Carbon dioxide activation and catalytic lactone synthesis by telomerization of butadiene and carbon dioxide , 1988 .

[48]  J. Mascetti,et al.  Bonding modes of carbon dioxide in organometallic complexes from FTIR spectra , 1991 .

[49]  C. Krüger,et al.  Nickel(0)-induzierte CC-verknüpfung zwischen kohlendioxid und alkinen sowie alkenen , 1984 .

[50]  T. Koike,et al.  A zinc(II) complex of 1,5,9-triazacyclododecane ([12]aneN3) as a model for carbonic anhydrase , 1990 .

[51]  P. Jessop,et al.  Catalytic Production of Dimethylformamide from Supercritical Carbon Dioxide , 1994 .

[52]  R. Kempe,et al.  Aktivierung von CO2 an übergangsmetallzentren: Zum ablauf der homogen-katalytischen Bildung von 2-Pyron aus Kohlendioxid und Hex-3-in an Nickel(0)-Fragmenten , 1992 .

[53]  J. Mascetti,et al.  Carbon dioxide coordination chemistry. 2. Synthesis and FTIR study of (carbon dioxide)bis(cyclopentadienyl)(trimethylphosphine)titanium , 1991 .

[54]  W. Baumann,et al.  Regioselektive reaktionen der fremdligandfreien titanocen-alkin-komplexe Cp2Ti(RC2SiMe3) (R = Me3Si,Ph, tBu, nBu) , 1995 .

[55]  W. Leitner,et al.  Activation of carbon dioxide: IV. Rhodium-catalysed hydrogenation of carbon dioxide to formic acid☆ , 1994 .

[56]  Gernot Frenking,et al.  Theoretical Studies of Organometallic Compounds. XIX. Complexes of Transition Metals in High and Low Oxidation States with Side-On-Bonded .pi.-Ligands , 1995 .

[57]  M. Aresta,et al.  Reduction of co-ordinated carbon dioxide to carbon monoxide via protonation by thiols and other Brønsted acids promoted by Ni-systems: a contribution to the understanding of the mode of action of the enzyme carbon monoxide dehydrogenase , 1988 .

[58]  H. Schönberg,et al.  Aktivierung von Kohlendioxid an Übergangsmetallzentren: Selektive Cooligomerisation mit Hexin(−3) durch das Katalysatorsystem Acetonitril/Trialkylphosphan/Nickel(0) und Struktur eines Nickel(0)-Komplexes mit side-on gebundenem Acetonitril , 1987 .

[59]  D. O′Hare,et al.  Rotational isomerism and fluxional behavior of bis(carbon dioxide) adducts of molybdenum , 1991 .

[60]  W. Leitner,et al.  Hydrogenation of carbon dioxide to formic acid using water-soluble rhodium catalyststs , 1993 .

[61]  T. Tsuda,et al.  Nickel(0)-catalyzed cycloaddition of diynes and carbon dioxide to give bicyclic .alpha.-pyrones , 1988 .

[62]  M. Saito,et al.  Homogeneous Hydrogenation of Carbon Dioxide to Methanol Catalyzed by Ruthenium Cluster Anions in the Presence of Halide Anions , 1995 .

[63]  P. Jessop,et al.  Methyl formate synthesis by hydrogenation of supercritical carbon dioxide in the presence of methanol , 1995 .

[64]  N. Alcock.  Bonding and Structure , 1990 .

[65]  D. Darensbourg,et al.  Supercritical carbon dioxide as solvent for the copolymerization of carbon dioxide and propylene oxide using a heterogeneous zinc carboxylate catalyst , 1995 .

[66]  P. Jessop,et al.  Homogeneous Catalysis in Supercritical Fluids , 1995, Science.

[67]  H. Kisch,et al.  Metal‐Catalyzed Synthesis of Cyclic Carbonates from Carbon Dioxide and Oxiranes , 1980 .

[68]  A. Fukuoka,et al.  Synthesis, structure and reactions of a carbon dioxide complex of iron(0) containing 1,2-bis(diethylphosphino)ethane ligands , 1994 .

[69]  J. Pinkes,et al.  Iron-Tin Carbon Dioxide Complexes (.eta.5-C5Me5)(CO)2FeCO2SnR3 (R = Me, Ph): Observations Pertaining to Unsymmetrical Metallocarboxylates and Carboxylate-Carbonyl 13C-Label Exchange , 1994 .

[70]  J. Gladysz,et al.  Synthesis, structure, and reactivity of transition metal/main group metal bridging carboxylate complexes of the formula (.eta.5-C5H5)Re(NO)(PPh3)(CO2MLn) (M = Li, K, Ge, Sn, Pb) , 1987 .

[71]  G. Sheldrick,et al.  Synthesis and X-ray structure of an osmium carbonyl anion [HOs3(CO)10·O2C·Os6(CO)17]– , 1976 .

[72]  Michele Aresta,et al.  The Role of Metal Centers in Reduction and Carboxylation Reactions Utilizing Carbon Dioxide , 1994 .

[73]  B. Brunschwig,et al.  Mechanistic and kinetic studies of cobalt macrocycles in a photochemical CO2 reduction system: Evidence of Co-CO2 adducts as intermediates , 1995 .

[74]  L. Dahlenburg,et al.  Oligophosphan-Liganden. XXX: Mono- und Bis(distickstoff)molybdän(0)-Komplexe des dreizähnigen Chelat-Phosphans MeP(CH2CH2CH2PMe2)2: Synthesen, Strukturen und Reaktionen mit Kohlendioxid , 1989 .

[75]  J. Mascetti,et al.  Carbon dioxide coordination chemistry. 1. Vibrational study of trans-bis(carbon dioxide)tetrakis (trimethylphosphine)molybdenum and (carbon dioxide) tetrakis(trimethylphosphine)iron , 1991 .

[76]  A. Behr.  Carbon Dioxide as Building Block for Fine Chemicals Synthesis by Homogeneous Catalysis , 1988 .

[77]  H. Kisch,et al.  Metallkatalysierte Synthese von cyclischen Carbonaten aus Kohlendioxid und Oxiranen , 1980 .

[78]  T. Tsuda,et al.  Nickel(0)-catalyzed cycloaddition of silyl diynes with carbon dioxide to silyl bicyclic .alpha.-pyrones , 1990 .

[79]  C. Bo,et al.  Carbon dioxide interaction with pentacarbonylhydridochromate(1-): theoretical study of the thermodynamic aspects , 1989 .

[80]  D. H. Gibson,et al.  CHARACTERIZATION AND THERMOLYSIS REACTIONS OF CO2-BRIDGED IRON-TIN AND RHENIUM-TIN COMPLEXES. STRUCTURE-REACTIVITY CORRELATIONS , 1995 .

[81]  M Aresta,et al.  二酸化炭素の酵素的活用対化学的活用 1 カルボキシル化反応における金属中心の役割 , 1995 .

[82]  T. Tsuda,et al.  Carbon dioxide insertion into organocopper and organosilver compounds , 1974 .

[83]  P. Jessop,et al.  HOMOGENEOUS CATALYSIS IN SUPERCRITICAL FLUIDS : HYDROGENATION OF SUPERCRITICAL CARBON DIOXIDE TO FORMIC ACID, ALKYL FORMATES, AND FORMAMIDES , 1996 .

[84]  G. Parkin,et al.  Zinc Pyrazolylborate Complexes Relevant to the Biological Function of Carbonic Anhydrase , 1992 .

[85]  S. Sakaki,et al.  An ab initio molecular-orbital study of insertion of CO2 into a RhI–H bond , 1994 .

[86]  K. Morokuma,et al.  Ab initio MO and SD-CI study of (carbon dioxide)bis(phosphine)nickel. Electron correlation effects on geometry, binding energy, and electronic structure , 1990 .

[87]  R. Perutz,et al.  Matrix photooxidation of the metal carbonyls (M(CO)6 (M=Cr, W) by the isoelectronic molecules carbon dioxide and nitrous oxide , 1985 .

[88]  D. H. Gibson,et al.  Synthesis and characterization of rhenium metallocarboxylates , 1994 .

[89]  C. Amatore,et al.  Carbon dioxide as a C1 building block. Mechanism of palladium-catalyzed carboxylation of aromatic halides , 1992 .

[90]  D. Darensbourg,et al.  Mechanistic aspects of decarboxylation reactions of Group 10 metal formato hydrido tricyclohexylphosphine [(PCy3)2M(H)O2CH] derivatives , 1990 .

[91]  Kiyotsuna Toyohara,et al.  Ruthenium Formyl Complexes as the Branch Point in Two- and Multi-Electron Reductions of CO2 , 1995 .

[92]  M. Aresta,et al.  New nickel–carbon dioxide complex: synthesis, properties, and crystallographic characterization of (carbon dioxide)-bis(tricyclohexylphosphine)nickel , 1975 .

[93]  Ying-Chih Lin,et al.  Homonuclear dirhenium complex bridged by CO2: Molecular structure of a rhenium dimer bridged by CO2 and a rhenium chloride complex , 1994 .

[94]  D. Blake,et al.  Reactions of peroxobis(triphenylphosphine) platinum (II) and analogs with with carbon dioxide, carbon disulfide, and other unsaturated molecules , 1970 .

[95]  H. Hoberg,et al.  Oxanickelacyclopenten-Derivate aus Nickel(0), Kohlendioxid und Alkinen , 1982 .

[96]  J. Périchon,et al.  Activation of carbon dioxide : nickel-catalyzed electrochemical carboxylation of diynes , 1993 .

[97]  B. P. Sullivan,et al.  Formation of a metal-hydride bond and the insertion of CO2 key steps in the electrocatalytic reduction of carbon dioxide to formate anion , 1991 .

[98]  S. Sakaki,et al.  Ab initio MO study of carbon dioxide insertion into a methyl-copper(I) bond. Critical difference from CO2 insertion into a hydrogen-copper(I) bond , 1989 .

[99]  J. Calabrese,et al.  Carbon dioxide coordination chemistry. 5. The preparation and structure of the rhodium complex Rh(.eta.1-CO2)(Cl)(diars)2 , 1983 .

[100]  H. Schwarz,et al.  Gas-phase generation and structural characterization of the Fe(CO2)+ cluster , 1994 .

[101]  W. Leitner,et al.  Activation of Carbon Dioxide, VI. Ligand Effects in the Catalytic Hydrogenation of Carbon Dioxide to Formic Acid Using in situ Catalysts Formed from [{(cod)Rh(μ-Cl)}2] and Monodentate and Bidentate Phosphorus Ligands† , 1996 .

[102]  S. Sakaki,et al.  Formation of the Oxanickelacyclopentene Complex from Nickel(0), Carbon Dioxide, and Alkyne. An ab initio MO/SD-CI Study. Part II. Reactivity and Regioselectivity of Hydroxyacetylene , 1995 .

[103]  A. Dedieu,et al.  Monohapto‐ oder Dihapto‐Koordination von CO2 in Bis(amin)‐Ni0 ‐Komplexen: Eine ab‐initio‐Unterschung , 1989 .

[104]  W. Leitner.  Kohlendioxid als Rohstoff am Beispiel der Synthese von Ameisensäure und ihren Derivaten , 1995 .

[105]  A. Cutler,et al.  Carbon monoxide and carbon dioxide fixation: relevant C1 and C2 ligand reactions emphasizing (.eta.5-C5H5)Fe-containing complexes , 1988 .

[106]  U. Nagel,et al.  A μ3‐CO2 Bridged, Tetranuclear Carbonylrhenium Complex: [(OC)5Re(CO2)Re(CO)4]2 , 1982 .

[107]  W. Leitner,et al.  New insights into the palladium-catalysed synthesis of δ-lactones from 1,3-dienes and carbon dioxide , 1995 .

[108]  D. Walther,et al.  CO2 als synthesebaustein: Seitenkettenaufbau von steroid-17β-pentensäuren via oxidative kopplung von CO2 mit einem steroiddien an nickel(0)-verbindungen , 1993 .

[109]  Y. Wada,et al.  Phenazine-Photosensitized Reduction of CO2 Mediated by a Cobalt-Cyclam Complex through Electron and Hydrogen Transfer , 1995 .

[110]  M. Aresta,et al.  Carbon dioxide-transition metals complexes. III. Rhodium(I)-CO2 complexes , 1977 .

[111]  D. Roundhill,et al.  Synthesis and reaction chemistry of monomeric and dimeric amide complexes of platinum(II) , 1991 .

[112]  C. Eigenbrot,et al.  Donor-acceptor metal-metal bonding instead of metathesis with Vaska's compound and the silver(I) salt of the weakly coordinating anion dodecahydrocarbaundecaborate(1-) , 1987 .

[113]  M. Aresta,et al.  Tetraphenylborate Anion as a Phenylating Agent: Chemical and Electrochemical Reactivity of BPh4--Rh Complexes toward Mono- and Dienes and Carbon Dioxide , 1995 .

[114]  P. W. Jolly,et al.  The preparation, reactions and structure of bis[bis(tricyclohexylphosphine)nickel] dinitrogen, {[(C6H11)3P]2Ni}2N2 , 1971 .

[115]  K. Nicholas,et al.  Carbon dioxide complexes via aerobic oxidation of transition metal carbonyls , 1992 .

[116]  W. Leitner.  Ein Nickelkomplex zur photochemischen Aktivierung von Kohlendioxid , 1994 .

[117]  R. Bergman,et al.  Comparison of the reactivity of (CO)3L2ReOR, (CO)3L2ReOAr and (CO)3L2ReNHAr with carbon dioxide and other electrophiles , 1992 .

[118]  H. Alt,et al.  Cp2Ti(PMe3)(C2H2), eine Ausgangsverbindung für KohlenstoffKohlenstoff-Verknüpfungsreaktionen des Alkins mit Kohlendioxid, Aceton, Acetaldehyd und Ethylen , 1988 .

[119]  A. Cutler,et al.  Reduction of the heterobimetallic .mu.-.eta.1(C):.eta.2(O,O')-CO2 complex Cp(CO)2Ru(CO2)Zr(Cl)Cp2 to its .mu.-.eta.1(C):.eta.1(O)-formaldehyde derivative Cp(CO)2Ru(CH2O)Zr(Cl)Cp2: hydride transfer occurs at ligated carbon monoxide , 1991 .

[120]  M. Holl,et al.  Reversible Insertion Reactions of a Platinum Germylene Complex , 1995 .

[121]  H. H. Karsch.  Funktionelle Trimethylphosphinderivate, III. Ambivalentes Verhalten von Tetrakis(trimethylphosphin)eisen : Reaktion mit CO2 , 1977 .

[122]  A. Fukuoka,et al.  Homogeneous Bimetallic Catalysts for Production of Carboxylic Acids from Carbon Dioxide, Hydrogen, and Organic Iodides , 1995 .

[123]  D. H. Gibson,et al.  Synthesis and Characterization of CO2-Bridged Bimetallic Compounds Derived from a Rhenium Metallocarboxylate. Correlation of IR Spectral Data with Coordination Geometry and Bonding Type , 1995 .

[124]  P. S. Braterman.  Reactions of coordinated ligands , 1987 .

[125]  D. Darensbourg,et al.  Reaction of (Cy3P)2Ni(H)(CH3) with carbon dioxide. Formation of an hydridonickel formate complex, HNi(O2CH)(Cy3P)2 , 1987 .

[126]  K. Nicholas,et al.  Lewis acid-promoted decarbonylation of coordinated carbon dioxide: reactions of (.eta.5-MeC5H4)2Nb(.eta.2-CO2)CH2SiMe3 with Lewis acids , 1992 .

[127]  Kiyotsuna Toyohara,et al.  Crystal Structure of [Ru(bpy)2(CO)(η1-C(O)OH)]+ (bpy = 2,2′-bipyridine) as a Key Intermediate in CO2/CO Conversion , 1996 .

[128]  H. Vahrenkamp,et al.  Pyrazolylboratozink-Komplexe mit Bezug zur biologischen Funktion der Carboanhydrase , 1992 .

[129]  I. Bernal.  Stereochemistry of Organometallic and Inorganic Compounds , 1990 .

[130]  A. Schmidt,et al.  Metallorganische CO2‐Speichersysteme aus Nickel(0)‐1‐azadieneinheiten und ihre Reaktivität bei der Carboxylierung von Acetophenon , 1995 .

[131]  D. Darensbourg,et al.  The Activation of Carbon Dioxide by Metai Complexes , 1983 .

[132]  D. H. Gibson,et al.  Synthesis and Characterization of CO2-Bridged Ruthenium-Zirconium and Rhenium-Zirconium Complexes , 1995 .

[133]  D. Darensbourg,et al.  Mechanistic studies of carbon dioxide insertion into metal hydrides and extrusion from the corresponding metal formates utilizing Group 6 metal carbonyl derivatives as reaction probes , 1990 .

[134]  K. Nicholas,et al.  Thermal and photochemical decarbonylation of niobium complex (MeC5H4)2Nb(.eta.2-CO2)CH2SiMe3 , 1991 .

[135]  C. Bruneau,et al.  A simple synthesis of oxazolidinones in one step from carbon dioxide , 1990 .

[136]  K. Schick,et al.  Intermediates in the palladium-catalyzed reactions of 1,3-dienes. 2. Preparation and structure of (.eta.1,.eta.3-octadienediyl)palladium complexes , 1985 .

[137]  S. Sakaki,et al.  Formation of the oxanickelacyclopentene complex from nickel(0), carbon dioxide, and alkyne. An ab initio MO/SD-CI study , 1993 .

[138]  M. Aresta,et al.  Carbon dioxide as modulator of the oxidative properties of dioxygen in the presence of transition metal systems , 1992 .

[139]  B. P. Sullivan,et al.  Electrochemical and electrocatalytic reactions of carbon dioxide , 1993 .

[140]  Kiyotsuna Toyohara,et al.  Comparison of Ru-C Bond Characters Involved in Successive Reduction of Ru-CO2 to Ru-CH2OH , 1995 .

[141]  D. Riley,et al.  Palladium-catalyzed generation of O-allylic urethanes and carbonates from amines/alcohols, carbon dioxide, and allylic chlorides , 1993 .

[142]  M. Aresta,et al.  Reaction of alkali-metal tetraphenylborates with amines in the presence of CO2: a new easy way to aliphatic and aromatic alkali-metal carbamates , 1995 .

[143]  Jan Paul Pradier,et al.  Carbon dioxide chemistry : environmental issues , 1994 .

[144]  A. Dedieu,et al.  Monohapto versus Dihapto CO2 Coordination in Bis(amine)Ni0 Complexes: A CAS‐SCF Study , 1989 .

[145]  C. Bruneau,et al.  Catalytic synthesis of vinyl carbamates from carbon dioxide and alkynes with ruthenium complexes , 1989 .

[146]  R. Kempe,et al.  Metallacyclische acyl-carboxylate des nickels: Reaktivität der acylgruppe und synthesepotential bei kreuzkopplungsreaktionen mit alkylhalogeniden , 1993 .

[147]  D. Ho,et al.  Reaction of electrophiles with manganese(I) and rhenium(I) alkoxide complexes: reversible absorption of atmospheric carbon dioxide , 1993 .

[148]  A. Behr,et al.  Synthese von 2-Ethyliden-6-hepten-5-olid , 1983 .

[149]  W. Leitner,et al.  σ-Metathese als entscheidender Schritt für die Übergangsmetall-katalysierte Bildung von Ameisensäure aus Kohlendioxid und Wasserstoff? – Eine ab-initio-Untersuchung† , 1995 .

[150]  W. Leitner,et al.  σ Metathesis as a Critical Step for the Transition Metal Catalyzed Formation of Formic Acid from CO2 and H2? An Ab Initio Investigation , 1995 .

[151]  H. Yamazaki,et al.  Reaction of (dioxygen)(dithiocarbamato)rhodium complexes with carbon dioxide. Formation and chemical cleavage of rhodium peroxycarbonato and carbonato rings , 1990 .

[152]  A. Rokicki,et al.  Synthesis, x-ray structural analysis, and thermal decomposition of the platinum(II) carboxylic acid (hydroxycarbonyl) trans-Pt(CO2H)(C6H5)(PEt3)2. Formation of a diplatinum(II) complex containing carbon dioxide , 1988 .

[153]  D. Riley,et al.  Palladium-mediated synthesis of urethanes from amines, carbon dioxide, and cyclic diolefins , 1992 .

[154]  Y. Inoue,et al.  Reaction of carbon dioxide with butadiene catalysed by palladium complexes. Synthesis of 2-ethylidenehept-5-en-4-olide , 1976 .

[155]  Koji Tanaka,et al.  Electrochemical CO2 reduction catalyzed by ruthenium complexes [Ru(bpy)2(CO)2]2+ and [Ru(bpy)2(CO)Cl]+. Effect of pH on the formation of CO and HCOO- , 1987 .

[156]  K. Nicholas,et al.  Metal formates via oxidation of metal carbonyl hydrides , 1994 .

[157]  J. Ibers,et al.  Reactivity of some transition metal systems toward liquid carbon dioxide , 1982 .

[158]  C. Bruneau,et al.  RUTHENIUM-CATALYZED SYNTHESIS OF SYMMETRICAL N,N'-DIALKYLUREAS DIRECTLY FROM CARBON DIOXIDE AND AMINES , 1991 .

[159]  Yehoshoa Ben‐David,et al.  Complexation of N2, H2, CO2, and Ethylene to a T-Shaped Rhodium(I) Core , 1996 .

[160]  C. Nobile,et al.  Carbon dioxide-transition metal complexes. IV. New Ni(0)CO2 complexes with chelating diphosphines: influence of PNiP angle on complex stabilities , 1992 .

[161]  T. Okano,et al.  Hydration and reduction of carbon dioxide by rhodium hydride compounds. Preparation and reactions of rhodium bicarbonate and formate complexes, and the molecular structure of RhH2(O2COH)(P(i-Pr)3)2 , 1979 .

[162]  C. Yeh,et al.  Photodissociation spectroscopy of the Mg+–CO2 complex and its isotopic analogs , 1993 .

[163]  S. Peng,et al.  Comparative study on crystal structures of ruthenium bipyridine carbonyl complexes [Ru(bpy)2(CO)2](PF6)2, [Ru(bpy)2(CO)(C(O)OCH3)]B(C6H5)4.cntdot.CH3CN, and [Ru(bpy)2(CO)(.eta.1-CO2)].cntdot.3H2O (bpy = 2,2'-bipyridyl) , 1993 .

[164]  H. Vahrenkamp,et al.  Ein L3ZnOH‐Komplex als funktionelles Modell des Enzyms Carboanhydrase , 1993 .

[165]  M. Reetz,et al.  Supercritical Carbon Dioxide as a Reaction Medium and Reaction Partner , 1993, CHIMIA.

[166]  L. Mussmann,et al.  Kinetic resolution of oxiranes by use of chiral Lewis acid catalysts , 1993 .

[167]  B. Brunschwig,et al.  Carbon dioxide activation by cobalt macrocycles: evidence of hydrogen bonding between bound CO2 and the macrocycle in solution , 1993 .

[168]  D. Darensbourg,et al.  Investigations into the steric influences on the reaction mechanism of carbon dioxide insertion into metal-oxygen bonds. Carbonyl sulfide activation as a model for CO2 , 1991 .

[169]  D. H. Gibson,et al.  Synthesis, characterization, and reactions of carbon dioxide bridged iron-rhenium complexes , 1994 .

[170]  J. Pinkes,et al.  Carbon dioxide insertion into the iron-zirconium and ruthenium-zirconium bonds of the heterobimetallic complexes Cp(CO)2MZr(Cl)Cp2: direct production of the .mu.-.eta.1(C):.eta.2(O,O')-CO2 compounds Cp(CO)2MCO2Zr(Cl)Cp2 , 1994 .

[171]  K. Nicholas,et al.  Thermolysis of (MeCp) 2Nb(η2−CO2)R complexes: decarbonylation vs. insertion , 1996 .

[172]  A. Baranger,et al.  Reaction of Carbon Dioxide and Heterocumulenes with an Unsymmetrical Metal-Metal Bond. Direct Addition of Carbon Dioxide across a Zirconium-Iridium Bond and Stoichiometric Reduction of Carbon Dioxide to Formate , 1995 .

[173]  N. Ravasio,et al.  Catalytic activity of Pd (AcO)2 coordinated to cross-linked polymeric isocyanides , 1993 .

[174]  T. Endo,et al.  Polymer reaction of epoxide and carbon dioxide. Incorporation of carbon dioxide into epoxide polymers , 1995 .

[175]  H. Hoberg,et al.  Ni0-induzierte Herstellung cyclischer C8-Carbonsäuren aus Cyclooctenen und Kohlendioxid , 1991 .

[176]  Y. Sasaki.  Reaction of carbon dioxide with propargyl alcohol catalyzed by a combination of Ru3(CO)12 and Et3N , 1986 .

[177]  I. Shimizu,et al.  Synthesis of the first carbon dioxide coordinated palladium(0) complex, Pd(η2-CO2)(PMePh2)2 , 1994 .

[178]  M. Aresta,et al.  A bonding-reactivity relationship for (carbon dioxide)bis(tricyclohexylphosphine)nickel: a comparative solid-state-solution nuclear magnetic resonance study (phosphorus-31, carbon-13) as a diagnostic tool to determine the mode of bonding of carbon dioxide to a metal center , 1992 .

[179]  K. G. Caulton,et al.  Synthesis and reactivity of a heterometallic carbon dioxide complex , 1990 .

[180]  I. S. Kolomnikov,et al.  Carbon dioxide in coordination chemistry and catalysis , 1990 .

[181]  H. Hoberg,et al.  Oxanickelacyclopentene Derivatives from Nickel(0), Carbon Dioxide, and Alkynes , 1982 .

[182]  D. Walther.  Chemie des Kohlendioxids an Metallzentren , 1992 .

[183]  S. Peng,et al.  Crystal structure of cis-(carbon monoxide)({eta}{sup 1}-carbon dioxide)bis(2,2{prime}-bipyridyl)ruthenium, an active species in catalytic CO{sub 2} reduction affording CO and HCOO{sup -} , 1992 .

[184]  W. Leitner,et al.  Direct formation of formic acid from carbon dioxide and dihydrogen using the [{Rh(cod)Cl}2]–Ph2P(CH2)4PPh2 catalyst system , 1992 .

[185]  V. Rotello,et al.  The chemistry of vicinal tricarbonyls use of vinyl tricarbonyl esters in the formation of 3-hydroxypyrole-2-carboxylates , 1989 .

[186]  S. Sakaki,et al.  Characteristic features of carbon dioxide insertion into a copper-hydrogen bond. An ab initio MO study , 1988 .

[187]  P. Schleyer,et al.  Carboxylation of lithium compounds: ab initio mechanisms , 1989 .

[188]  D. Darensbourg,et al.  Syntheses and Structures of Epoxide Adducts of Soluble Cadmium(II) Carboxylates. Models for the Initiation Process in Epoxide/CO2 Coupling Reactions , 1995 .

[189]  Y. Inoue,et al.  Palladium(0)-catalyzed carboxylative cyclized coupling of propargylic alcohol with aryl halides , 1990 .

[190]  I. K. Gregor,et al.  Gas‐phase chemistry of first transition series carbonyl metallate ions, [Metal(CO)x]−: Reactions with 13C‐ and 18O‐Labelled carbon dioxide. A Fourier‐transform ion cyclotron resonance study , 1992 .

[191]  T. Tsuda,et al.  Efficient spontaneous 1 : 1 copolymerization of bis(ynamine)s with carbon dioxide to poly(4-pyrone)s , 1995 .

[192]  A. Behr.  Carbon Dioxide Activation by Metal Complexes , 1988 .

[193]  Youfeng Zheng,et al.  The observation of gas-phase carbon dioxide complex W (CO)5(CO2). Kinetics and bond energy for reaction of CO2 with W(CO)5 , 1993 .

[194]  Chae S. Yi,et al.  Ruthenium-Mediated Hydrogenation of Carbon Dioxide by NaBH4 via the Formation of the Formate Complex C5Me5Ru(PCy3)(.eta.2-OCHO) , 1995 .

[195]  S. Sakaki,et al.  Coordination mode and bonding nature of carbon dioxide in d8 [Co(alcn(2(CO2)]- (alcn = HNCHCHCHO-). An ab initio MO study , 1987 .

[196]  D. H. Gibson,et al.  1-Carbonyl-μ-carboxylato-1κC:2κO:2κO'-1-η5-indenyl-2,2,2-triphenyl-1-(triphenylphosphine)irontin , 1993 .

[197]  T. Tsuda,et al.  Nickel(0)-catalyzed alternating copolymerization of carbon dioxide with diynes to poly(2-pyrones) , 1992 .

[198]  S. Mandal,et al.  The preparation and x-ray crystal structure of the first homobimetallic μ(η2-O,O′:η1-C) carbon dioxide complex: (dppp)(CO)2ReO2CRe(CO)3(dppp) , 1993 .

[199]  A. Behr.  Kohlendioxid als alternativer C1‐Baustein: Aktivierung durch Übergangsmetallkomplexe , 1988 .

[200]  Pierre Braunstein,et al.  Reactions of carbon dioxide with carbon-carbon bond formation catalyzed by transition-metal complexes , 1988 .

[201]  Y. Inoue,et al.  Reaction of dialkyl-substituted alkynes with carbon dioxide catalyzed by nickel(0) complexes. Incorporation of carbon dioxide in alkyne dimers and novel cyclotrimerization of the alkynes. , 1980 .

[202]  W. Leitner,et al.  [RhH] and [Rh][O2CH] Complexes as Models for the Catalytically Active Intermediates in the Rh‐Catalyzed Hydrogenation of CO2 to HCOOH , 1993 .

[203]  P. W. Jolly.  η3‐Allylpalladium‐Verbindungen , 1985 .

[204]  A. Behr,et al.  Steuerungsmöglichkeiten bei der übergangsmetall‐katalysierten Umsetzung von 1,3‐Dienen mit Kohlendioxid , 1986 .

[205]  K. G. Caulton,et al.  Conversion of carbon dioxide to carbonate using a rhodium .mu.-hydroxy species , 1987 .

[206]  D. Walther,et al.  Nickelalactone als Synthesebausteine: Sonochemische und Bimetallaktivierung der Kreuzkopplungsreaktion mit Alkyl-halogeniden , 1992 .

[207]  S. Sakaki.  Can carbon dioxide coordinate to a nickel(I) complex? An ab initio MO/SD-CI study , 1990 .