Regiospecific templated synthesis of D2h-symmetrical tetrakis-adduct C64(COOEt)8 by reversible tether-directed remote functionalization of C60

Tether-directed remote functionalization of C60, followed by further addition step and subsequent removal of the tether-reactive group conjugate(template), led to the first D2h-symmetrical tetrakis-adduct n a regiospecific manner.

[1]  Andreas Hirsch,et al.  Reversible Template‐Directed Activation of Equatorial Double Bonds of the Fullerene Framework: Regioselective Direct Synthesis, Crystal Structure, and Aromatic Properties of Th‐C66(COOEt)12 , 1995 .

[2]  A. Hirsch,et al.  Reversible Templataktivierung äquatorialer Doppelbindungen des C60‐Gerüstes: regioselektive Direktsynthese, Struktur und aromatische Eigenschaften von Th‐C66 (COOEt)12 , 1995 .

[3]  F. Diederich,et al.  Solubilized Derivatives of C195 and C260: The First Members of a New Class of Carbon Allotropes Cn(60 + 5) , 1995 .

[4]  P. Seiler,et al.  Lösliche Derivate von C195 und C260: die ersten Verbindungen einer neuen Klasse von Kohlenstoffallotropen Cn(60 + 5) , 1995 .

[5]  B. Kräutler,et al.  A Highly Symmetric Sixfold Cycloaddition Product of Fullerene C60 , 1995 .

[6]  Bernhard Kräutler,et al.  Ein hochsymmetrisches Produkt einer sechsfachen [4 + 2]‐Cycloaddition des C60‐Fullerens , 1995 .

[7]  F. Diederich,et al.  Tether-Directed Remote Functionalization of Buckminsterfullerene: Regiospecific Hexaadduct Formation† , 1994 .

[8]  François Diederich,et al.  Spacer‐kontrollierte Fernfunktionalisierung von Buckminsterfulleren: regiospezifische Bildung eines Hexaadduktes , 1994 .

[9]  A. Hirsch,et al.  Regiochemistry of Multiple Additions to the Fullerene Core: Synthesis of a Th-Symmetric Hexakis adduct of C60 with Bis(ethoxycarbonyl)methylene , 1994 .

[10]  L. Echegoyen,et al.  Kinetic effects in the electrochemistry of fullerene derivatives at very negative potentials , 1994 .

[11]  Y. Maruyama,et al.  Redox properties of organofullerenes , 1994 .

[12]  D. Walton,et al.  The structure and reactivity of C60 , 1994 .

[13]  F. Wudl,et al.  Synthesis of m-phenylene- and p-phenylenebis(phenylfulleroids): two-pearl sections of pearl necklace polymers , 1992 .

[14]  P. Fagan,et al.  A multiply-substituted buckminsterfullerene (C60) with an octahedral array of platinum atoms , 1991 .

[15]  Robert L. Whetten,et al.  Photophysical properties of C60 , 1991 .