Analysis and simulation of scale-up potentials in reverse electrodialysis

AbstractThe reverse electrodialysis (RED) process has been widely accepted as a viable and promising technology to produce electric energy from salinity difference (salinity gradient power e.g. using river water/seawater or seawater and concentrated brines). Recent R&D efforts demonstrated how an appropriate design of the RED unit and a suitable selection of process conditions may crucially enhance the process performance. With this regard, a process simulator was developed and validated with experimental data collected on a laboratory-scale unit, providing a new modelling tool for process optimisation. In this work, performed within the REAPower project (www.reapower.eu), a process simulator previously proposed by the same authors has been modified in order to predict the behaviour of a cross-flow RED unit. The model was then adopted to investigate the influence of the most important variables (i.e. solution properties and stack geometry) on the overall process performance. In particular, the use of diff...

[1]  J. Post,et al.  Energy recovery from controlled mixing salt and fresh water with a reverse electrodialysis system. , 2008, Environmental science & technology.

[2]  Michele Ciofalo,et al.  CFD Simulation of Mass Transfer Phenomena in Spacer Filled Channel for Reverse Electrodyalisis Applications , 2013 .

[3]  Michele Ciofalo,et al.  CFD prediction of concentration polarization phenomena in spacer-filled channels for reverse electrodialysis , 2014 .

[4]  Dorothea C. Nijmeijer,et al.  Theoretical power density from salinity gradients using reverse electrodialysis , 2012 .

[5]  Michael Papapetrou,et al.  REAPOWER – USE OF DESALINATION BRINE FOR POWER PRODUCTION THROUGH REVERSE ELECTRODIALYSIS , 2015 .

[6]  J. Veerman,et al.  Reducing power losses caused by ionic shortcut currents in reverse electrodialysis stacks by a validated model , 2008 .

[7]  Ian T. Cameron,et al.  Process Modelling and Model Analysis , 2013 .

[8]  Andrea Cipollina,et al.  CFD analysis of the fluid flow behavior in a reverse electrodialysis stack , 2012 .

[9]  J. Post,et al.  Salinity-gradient power : Evaluation of pressure-retarded osmosis and reverse electrodialysis , 2007 .

[10]  Dc Kitty Nijmeijer,et al.  Experimentally obtainable energy from mixing river water, seawater or brines with reverse electrodialysis , 2014 .

[11]  P. M. Biesheuvel,et al.  Direct power production from a water salinity difference in a membrane-modified supercapacitor flow cell. , 2010, Environmental science & technology.

[12]  F. Helfferich,et al.  Ion-exchange membrane separation processes (Membrane science and technology series, vol. 9), H. Strathmann. Elsevier, Amsterdam (2004), ISBN: 044450236-X , 2005 .

[13]  Rien Herber,et al.  Upscale potential and financial feasibility of a reverse electrodialysis power plant , 2014 .

[14]  R. Lacey Energy by reverse electrodialysis , 1980 .

[15]  E. Brauns,et al.  Salinity gradient power by reverse electrodialysis: effect of model parameters on electrical power output , 2009 .

[16]  Andrea Cipollina,et al.  Modelling the Reverse ElectroDialysis process with seawater and concentrated brines , 2012 .

[17]  D. Brogioli Extracting renewable energy from a salinity difference using a capacitor. , 2009, Physical review letters.

[18]  Michele Ciofalo,et al.  CFD simulation of channels for direct and reverse electrodialysis , 2012 .

[19]  Giorgio Micale,et al.  A simulation tool for analysis and design of reverse electrodialysis using concentrated brines , 2015 .

[20]  Michele Ciofalo,et al.  CFD modelling of profiled-membrane channels for reverse electrodialysis , 2015 .

[21]  Guy Z. Ramon,et al.  Membrane-based production of salinity-gradient power , 2011 .

[22]  Menachem Elimelech,et al.  High Efficiency in Energy Generation from Salinity Gradients with Reverse Electrodialysis , 2013 .

[23]  J. Veerman,et al.  Reverse electrodialysis: A validated process model for design and optimization , 2011 .