Indirect coal to liquid technologies

Abstract Indirect coal liquefaction has enormous potential applications. Increasingly, new synthetic technologies have been concentrating in this area, and a number of new large-scale indirect coal liquefaction plants have been set up during very recent years. Further, a large volume of papers on indirect coal liquefaction have been published over the last two decades, including those on Fischer–Tropsch synthesis, syngas to ethylene glycol, syngas to methanol, dimethyl ether as well as methanol to olefins. In this review, the recent literature of indirect liquefaction, including Fischer–Tropsch and syngas to chemicals, are summarized, with an emphasis on the reaction mechanisms, conditions and novel catalysts.

[1]  Michael Stöcker,et al.  Methanol-to-hydrocarbons: catalytic materials and their behavior 1 Dedicated to my wife Wencke Ophau , 1999 .

[2]  M. Fan,et al.  Adsorption of Mercury with Modified Thief Carbons , 2012 .

[3]  Wen-de Xiao,et al.  Characterization of Pd–CeO2/α-alumina catalyst for synthesis of dimethyl oxalate , 2005 .

[4]  Zhong-Ning Xu,et al.  An ultra-low Pd loading nanocatalyst with high activity and stability for CO oxidative coupling to dimethyl oxalate. , 2013, Chemical communications.

[5]  A. M. Saib,et al.  Fundamental understanding of deactivation and regeneration of cobalt Fischer-Tropsch synthesis catalysts , 2010 .

[6]  A. Dalai,et al.  Selective Production of C4 Hydrocarbons from Syngas Using Fe-Co/ZrO2 and SO42—/ZrO2 Catalysts , 2008 .

[7]  R. Quinn,et al.  An evaluation of synthesis gas contaminants as methanol synthesis catalyst poisons , 2004 .

[8]  Kangnian Fan,et al.  Highly active and selective copper-containing HMS catalyst in the hydrogenation of dimethyl oxalate to ethylene glycol , 2008 .

[9]  Surajit Chattopadhyay,et al.  Studies on the reactions of ruthenium(II) substrates with tridentate (N,N,O) azo ligands , 2010 .

[10]  Sunggyu Lee,et al.  Liquid phase methanol and dimethyl ether synthesis from syngas , 2005 .

[11]  Maohong Fan,et al.  Air Pollution and Control in Different Areas of China , 2010 .

[12]  Shengping Wang,et al.  Hydrogenation of dimethyl oxalate to ethylene glycol over mesoporous Cu‐MCM‐41 catalysts , 2013 .

[13]  H. Lei,et al.  Core–shell structured CuO–ZnO@H-ZSM-5 catalysts for CO hydrogenation to dimethyl ether , 2012 .

[14]  K. Asakura,et al.  Remarkable enhancement of Cu catalyst activity in hydrogenation of dimethyl oxalate to ethylene glycol using gold , 2012 .

[15]  Yong Yang,et al.  Effects of alkaline-earth metals on the structure, adsorption and catalytic behavior of iron-based Fischer–Tropsch synthesis catalysts , 2013 .

[16]  R. O'brien,et al.  Study of Deactivation of Iron-Based Fischer-Tropsch Synthesis Catalysts , 2001 .

[17]  B. Davis,et al.  Fischer-Tropsch synthesis: comparison of carbon-14 distributions when labeled alcohol is added to the synthesis gas , 1991 .

[18]  Kangnian Fan,et al.  Solvent feedstock effect: the insights into the deactivation mechanism of Cu/SiO2 catalysts for hydrogenation of dimethyl oxalate to ethylene glycol. , 2013, Chemical communications.

[19]  Alexis T. Bell,et al.  Studies of fischer-Tropsch synthesis over a fused iron catalyst , 1986 .

[20]  Yongqing Zhang,et al.  Fischer−Tropsch synthesis: activity and selectivity for Group I alkali promoted iron-based catalysts , 2002 .

[21]  Bin Zhang,et al.  Modification of the supported Cu/SiO2 catalyst by alkaline earth metals in the selective conversion of 1,4-butanediol to γ-butyrolactone , 2012 .

[22]  G. Menchi,et al.  Homogeneous catalytic hydrogenation of dicarboxylic acid esters , 1984 .

[23]  I. Císařová,et al.  Synthesis, structural characterisation and electrochemistry of bis[(diphenylphosphino)ferrocene]diruthenium complexes [Ru2(μ-RCO2)2(CO)4(FcPPh2)2] (R = H and Me) , 2009 .

[24]  Mathieu J-L Tschan,et al.  New processes for the selective production of 1-octene , 2011 .

[25]  Xinbin Ma,et al.  Ethylene glycol: properties, synthesis, and applications. , 2012, Chemical Society reviews.

[26]  J. Gaube,et al.  The promoter effect of alkali in Fischer-Tropsch iron and cobalt catalysts , 2008 .

[27]  Q. Xin,et al.  Catalytic Activity and Characterization of Oxygen Mobility on Pt/Ce0.75Zr0.25O2 Catalyst by Isotopic Exchange with 18O , 2006 .

[28]  C. H. Bartholomew Mechanisms of catalyst deactivation , 2001 .

[29]  M. Khademi,et al.  DME synthesis and cyclohexane dehydrogenation reaction in an optimized thermally coupled reactor , 2011 .

[30]  Hengyong Xu,et al.  Study on the sulfur tolerance of catalysts for syngas to methanol , 2008 .

[31]  Zhongmin Liu,et al.  Nanosize-Enhanced Lifetime of SAPO-34 Catalysts in Methanol-to-Olefin Reactions , 2013 .

[32]  Jianwei Zheng,et al.  Efficient low-temperature selective hydrogenation of esters on bimetallic Au-Ag/SBA-15 catalyst , 2013 .

[33]  Wenzhang Wu,et al.  Methanol conversion to olefins (MTO) over H-ZSM-5: Evidence of product distribution governed by methanol conversion , 2013 .

[34]  Q. Lin,et al.  Effects of Precursors on Preparation of Pd/α-alumina Catalyst for Synthesis of Dimethyl Oxalate , 2007 .

[35]  Yulei Zhu,et al.  Promoting effect of boron oxide on Cu/SiO2 catalyst for glycerol hydrogenolysis to 1,2-propanediol , 2013 .

[36]  Hong Wang,et al.  Effect of magnesium promoter on iron-based catalyst for Fischer–Tropsch synthesis , 2006 .

[37]  T. Greibrokk,et al.  Separation of technical waxes by temperature-programmed packed-capillary liquid chromatography , 2000 .

[38]  T. Turek,et al.  Hydrogenolysis of Dimethyl Maleate on Cu/ZnO/Al2O3 Catalysts , 2001 .

[39]  M. Dry,et al.  Heats of chemisorption on promoted iron surfaces and the role of alkali in Fischer-Tropsch synthesis , 1969 .

[40]  J. F. Creemer,et al.  Nanoscale chemical imaging of a working catalyst by scanning transmission X-ray microscopy , 2008, Nature.

[41]  N. Ostrovskii General equation for linear mechanisms of catalyst deactivation , 2006 .

[42]  Gongshin Qi,et al.  DME Synthesis From CO/H2 over Cu-Mn/Ă-Al2O3 Catalyst , 2001 .

[43]  Yi-Ning Wang,et al.  Heterogeneous modeling for fixed-bed Fischer–Tropsch synthesis: Reactor model and its applications , 2003 .

[44]  Delphine Bazer-Bachi,et al.  New insight on the ZnO sulfidation reaction: Evidences for an outward growth process of the ZnS phase , 2012 .

[45]  Agustín Martínez,et al.  Direct synthesis of DME from syngas on hybrid CuZnAl/ZSM-5 catalysts: New insights into the role of zeolite acidity , 2012 .

[46]  A. Indarto,et al.  A review of C1 chemistry synthesis using yttrium-stabilized zirconia catalyst , 2008 .

[47]  Im Ionel Ciobica,et al.  Atomic and polymeric carbon on Co(0001) : surface reconstruction, graphene formation, and catalyst poisoning , 2012 .

[48]  Beatriz Fidalgo,et al.  CO2 reforming of coke oven gas over a Ni/γAl2O3 catalyst to produce syngas for methanol synthesis , 2012 .

[49]  Chikezie Nwaoha,et al.  Gas-to-liquids (GTL): A review of an industry offering several routes for monetizing natural gas , 2012 .

[50]  J. Dumesic,et al.  Migration of potassium on iron and alumina surfaces as studied by Auger electron spectroscopy , 1985 .

[51]  G. Menchi,et al.  Homogeneous catalytic hydrogenation of the esters of bicarboxylic acids. Part III. Ethylene glycol from dimethyl oxalate , 1988 .

[52]  C. J. Elsevier,et al.  Ruthenium catalyzed hydrogenation of dimethyl oxalate to ethylene glycol , 1997 .

[53]  Martin J. Hanton,et al.  A tripodal sulfur ligand for the selective ruthenium-catalysed hydrogenation of dimethyl oxalate. , 2006, Chemical communications.

[54]  Z. Hou,et al.  Synthesis of dimethyl ether (DME) on modified HY zeolite and modified HY zeolite-supported Cu–Mn–Zn catalysts , 2006 .

[55]  M. Haghighi,et al.  Direct syngas to DME as a clean fuel: The beneficial use of ultrasound for the preparation of CuO–ZnO–Al2O3/HZSM-5 nanocatalyst , 2013 .

[56]  Jing Chen,et al.  Progress in synthesis of ethylene glycol through C1 chemical industry routes , 2013 .

[57]  F. G. Botes,et al.  The Effects of Water and CO2 on the Reaction Kinetics in the Iron‐Based Low‐Temperature Fischer‐Tropsch Synthesis: A Literature Review , 2008 .

[58]  K. Xie,et al.  The Structure Properties of CuZnAl Slurry Catalysts Prepared by a Complete Liquid-Phase Method and its Catalytic Performance for DME Synthesis from Syngas , 2009 .

[59]  Denzil Dj Moodley On the deactivation of cobalt-based Fischer-Tropsch synthesis catalysts , 2011 .

[60]  W.-Y. Li,et al.  The Development of Methanol Industry and Methanol Fuel in China , 2009 .

[61]  P. Edwards,et al.  Turning carbon dioxide into fuel , 2010, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[62]  Zifeng Yan,et al.  Key parameters in hydrothermal synthesis and characterization of low silicon content SAPO-34 molecular sieve , 2009 .

[63]  J. Liang,et al.  Methanol to olefin conversion catalysts , 1999 .

[64]  A. Borgna,et al.  Density Functional Theory Study of the CO Insertion Mechanism for Fischer−Tropsch Synthesis over Co Catalysts , 2009 .

[65]  B. Toseland,et al.  A novel mechanism of catalyst deactivation in liquid phase synthesis Gas-to-DME reactions , 1997 .

[66]  K. Jun,et al.  Effect of precipitants during the preparation of Cu-ZnO-Al2O3/Zr-ferrierite catalyst on the DME synthesis from syngas , 2009 .

[67]  Oh-Shim Joo,et al.  DME synthesis from synthesis gas on the admixed catalysts of Cu/ZnO/Al2O3 and ZSM-5 , 2004 .

[68]  Zhongyang Luo,et al.  The Influence of Copper Particle Dispersion in Cu/SiO2 Catalysts on the Hydrogenation Synthesis of Ethylene Glycol , 2010 .

[69]  Ali Haghtalab,et al.  Fischer‐Tropsch Synthesis Over Co‐Ru/γ‐Al2O3 Catalyst in Supercritical Media , 2008 .

[70]  Jinlin Li,et al.  Effects of Ru nanoparticle sizes confined in cavities of SBA-16 on the catalytic performance of Fischer-Tropsch synthesis reaction , 2012 .

[71]  Weiguo Song,et al.  The mechanism of methanol to hydrocarbon catalysis. , 2003, Accounts of chemical research.

[72]  Siddharth Jain,et al.  Impact analysis of biodiesel on engine performance—A review , 2011 .

[73]  K. Xie,et al.  Research on Si–Al based catalysts prepared by complete liquid-phase method for DME synthesis in a slurry reactor , 2011 .

[74]  A. Slawin,et al.  Hydrogenation of Aldehydes, Esters, Imines, and Ketones Catalyzed by a Ruthenium Complex of a Chiral Tridentate Ligand , 2007 .

[75]  V. Nivin Molecular-mass distribution of saturated hydrocarbons in gas of the Lovozerskii nepheline-syenite massif , 2009 .

[76]  Shengping Wang,et al.  Hydrogenation of dimethyl oxalate to ethylene glycol on a Cu/SiO2/cordierite monolithic catalyst: Enhanced internal mass transfer and stability , 2012 .

[77]  Kangnian Fan,et al.  One Pot Synthesis of Ultra-High Copper Contented Cu/SBA-15 Material as Excellent Catalyst in the Hydrogenation of Dimethyl Oxalate to Ethylene Glycol , 2009 .

[78]  Cyril Knottenbelt,et al.  Mossgas “gas-to-liquid” diesel fuels—an environmentally friendly option , 2002 .

[79]  Kangnian Fan,et al.  High activity and selectivity of Ag/SiO2 catalyst for hydrogenation of dimethyl oxalate. , 2010, Chemical communications.

[80]  Yong Yang,et al.  Study of an iron-manganese Fischer–Tropsch synthesis catalyst promoted with copper , 2006 .

[81]  Martyn V. Twigg,et al.  Deactivation of supported copper metal catalysts for hydrogenation reactions , 2001 .

[82]  G. Menchi,et al.  Selective reduction of dimethyl oxalate by ruthenium carbonyl carboxylates in homogeneous phase Part IV , 1991 .

[83]  Freek Kapteijn,et al.  Cobalt particle size effects in the Fischer-Tropsch reaction studied with carbon nanofiber supported catalysts. , 2006, Journal of the American Chemical Society.

[84]  E. McFarland,et al.  Improved light olefin yield from methyl bromide coupling over modified SAPO-34 molecular sieves. , 2011, Physical chemistry chemical physics : PCCP.

[85]  José Luis Valverde,et al.  Fischer-Tropsch diesel production over calcium-promoted Co/alumina catalyst: Effect of reaction conditions , 2011 .

[86]  A. Russell,et al.  Dynamic separation of ultradilute CO2 with a nanoporous amine-based sorbent , 2012 .

[87]  Isabel Díaz,et al.  Fischer–Tropsch synthesis of hydrocarbons over mesoporous Co/SBA-15 catalysts: the influence of metal loading, cobalt precursor, and promoters , 2003 .

[88]  Zhenhua Li,et al.  Study on the reaction of CO coupling to oxalate , 2003 .

[89]  R. Crabtree Current Ideas and Future Prospects in Metal-Catalyzed Methane Conversion , 1994 .

[90]  Landong Li,et al.  Mechanisms of the Deactivation of SAPO-34 Materials with Different Crystal Sizes Applied as MTO Catalysts , 2013 .

[91]  Prasant Kumar Rout,et al.  Production of first and second generation biofuels: A comprehensive review , 2010 .

[92]  M. Haghighi,et al.  Preparation and catalytic performance of CuO-znO-AlO3/clinoptilolite nanocatalyst for single-step synthesis of dimethyl ether from syngas as a green fuel. , 2013, Journal of nanoscience and nanotechnology.

[93]  P. Frediani,et al.  Hydrogenation of dimethyl oxalate in the presence of ruthenium carbonyl carboxylates ethylene glycol formation , 1985 .

[94]  G. Olah,et al.  Chemical recycling of carbon dioxide to methanol and dimethyl ether: from greenhouse gas to renewable, environmentally carbon neutral fuels and synthetic hydrocarbons. , 2009, The Journal of organic chemistry.

[95]  J. Goodwin,et al.  La, V, and Fe promotion of Rh/SiO2 for CO hydrogenation: Effect on adsorption and reaction , 2009 .

[96]  M. Dry,et al.  The Fischer–Tropsch process: 1950–2000 , 2002 .

[97]  D. Elliott,et al.  Conversion of Biomass Syngas to DME Using a Microchannel Reactor , 2005 .

[98]  Xiangping Zhang,et al.  Synthesis, characterization and catalytic performance of SAPO-34 molecular sieves for methanol-to-olefin (MTO) reaction , 2011 .

[99]  J. G. Goodwin,et al.  Zr Promotion of Co/SiO2 for Fischer-Tropsch Synthesis , 1995 .

[100]  A. Bliek,et al.  Ester hydrogenolysis over promoted Cu/SiO2 catalysts , 1999 .

[101]  Frerich J. Keil,et al.  Methanol-to-hydrocarbons: process technology , 1999 .

[102]  N. G. Gallegos,et al.  Effect of thermal pretreatment on the structural properties of catalysts in hydrocarbon synthesis from CO and H2 , 1991 .

[103]  A. Holmen,et al.  Study of the effect of water on Fischer–Tropsch synthesis over supported cobalt catalysts , 2005 .

[104]  Nimir O. Elbashir,et al.  Advancement of Fischer‐Tropsch synthesis via utilization of supercritical fluid reaction media , 2009 .

[105]  K. Jun,et al.  Synthesis of DME from syngas on the bifunctional Cu–ZnO–Al2O3/Zr-modified ferrierite: Effect of Zr content , 2009 .

[106]  Yuhan Sun,et al.  Effect of SAPO-34 molecular sieve morphology on methanol to olefins performance , 2013 .

[107]  Kyoung‐Su Ha,et al.  Ru promoted cobalt catalyst on γ-Al2O3 support: Influence of pre-synthesized nanoparticles on Fischer–Tropsch reaction , 2011 .

[108]  K. Lillerud,et al.  Conversion of methanol to hydrocarbons: how zeolite cavity and pore size controls product selectivity. , 2012, Angewandte Chemie.

[109]  R. E. Kelly,et al.  Fischer--Tropsch synthesis. Some important variables of the synthesis on iron catalysts. [Increased activity obtained using Fe catalyst D-3001 containing MgO 6. 8, SiO/sub 2/, 1. 05, C/sub 2/O/sub 3/ 0. 96, and K/sub 2/O 0. 85% as promoters] , 1952 .

[110]  E. Munson,et al.  An in situ solid-state NMR study of the formation and reactivity of trialkylonium ions in zeolites , 1993 .

[111]  J. F. Haw,et al.  Methylbenzene Chemistry on Zeolite HBeta: Multiple Insights into Methanol-to-Olefin Catalysis , 2002 .

[112]  Kangnian Fan,et al.  Effect of Si/Al Ratio of Mesoporous Support on the Structure Evolution and Catalytic Performance of the Cu/Al-HMS Catalyst , 2010 .

[113]  E. Steen,et al.  Re‐dispersion of Cobalt on a Model Fischer–Tropsch Catalyst During Reduction–Oxidation–Reduction Cycles , 2012 .

[114]  J. Topp-Jørgensen Topsøe Integrated Gasoline Synthesis – The Tigas Process , 1988 .

[115]  Weiwei Lu,et al.  Low-temperature synthesis of DME from CO2/H2 over Pd-modified CuO–ZnO–Al2O3–ZrO2/HZSM-5 catalysts , 2004 .

[116]  Wei Li,et al.  The mechanism of CO coupling reaction to form dimethyl oxalate over Pd/α-Al2O3 , 2009 .

[117]  A. Rodrigues,et al.  Syngas Stoichiometric Adjustment for Methanol Production and Co-Capture of Carbon Dioxide by Pressure Swing Adsorption , 2012 .

[118]  Alternative Source of Propylene , 2005 .

[119]  Carlotta Giannelli,et al.  Ruthenium complexes with 1,1′-biisoquinoline as ligand. Synthesis and hydrogenation activity , 2003 .

[120]  Maohong Fan,et al.  Use of Nanoporous FeOOH as a Catalytic Support for NaHCO3 Decomposition Aimed at Reduction of Energy Requirement of Na2CO3/NaHCO3 Based CO2 Separation Technology , 2011 .

[121]  K. Ataka,et al.  Oxidative reactions by a palladium–alkyl nitrite system , 1999 .

[122]  R. Herman,et al.  Catalytic synthesis of methanol from COH2: II. Electron microscopy (TEM, STEM, microdiffraction, and energy dispersive analysis) of the CuZnO and Cu/ZnO/Cr2O3 catalysts , 1979 .

[123]  W. Li,et al.  Effect of copper loading on texture, structure and catalytic performance of Cu/SiO2 catalyst for hydrogenation of dimethyl oxalate to ethylene glycol , 2012 .

[124]  A. Datye,et al.  Carbon deposition as a deactivation mechanism of cobalt-based Fischer-Tropsch synthesis catalysts under realistic conditions , 2009 .

[125]  Richard G. Herman,et al.  Catalytic synthesis of methanol from COH2: I. Phase composition, electronic properties, and activities of the Cu/ZnO/M2O3 catalysts , 1979 .

[126]  J. F. Haw,et al.  Conversion of methyl halides to hydrocarbons on basic zeolites: a discovery by in situ NMR , 1993 .

[127]  M. Hanna,et al.  THERMOCHEMICAL BIOMASS GASIFICATION—A REVIEW OF THE CURRENT STATUS OF THE TECHNOLOGY , 2009 .

[128]  A. Russell,et al.  Mesoporous amine-modified SiO2 aerogel: a potential CO2 sorbent , 2011 .

[129]  Tadashi Yoshida,et al.  Characterization of Different Possible Solvent−Coal Interaction Mechanisms by the Relationship between the Volumetric Swelling of Coals and Heat Release in Swelling Solvent , 1998 .

[130]  V. Kirillov,et al.  A Mathematical Model of Fisher-Tropsch Synthesis in a Slurry Reactor , 1998 .

[131]  M. Dry,et al.  Stability of nanocrystals: thermodynamic analysis of oxidation and re-reduction of cobalt in water/hydrogen mixtures. , 2005, The journal of physical chemistry. B.

[132]  S. Hong,et al.  SAPO-34 and ZSM-5 nanocrystals’ size effects on their catalysis of methanol-to-olefin reactions , 2012 .

[133]  E. Munson,et al.  Carbon monoxide is neither an intermediate nor a catalyst in MTG chemistry on zeolite HZSM-5 , 1991 .

[134]  A. Russell,et al.  New CO2 Sorbent Synthesized with Nanoporous TiO(OH)2 and K2CO3 , 2013 .

[135]  M. Fan,et al.  CO2 Separation by a New Solid K−Fe Sorbent , 2011 .

[136]  Ali Taheri Najafabadi,et al.  Improvement of light olefins selectivity and catalyst lifetime in MTO reaction; using Ni and Mg-modified SAPO-34 synthesized by combination of two templates , 2011 .

[137]  Xiao-Ming Jiang,et al.  High-Performance and Long-Lived Pd Nanocatalyst Directed by Shape Effect for CO Oxidative Coupling to Dimethyl Oxalate , 2013 .

[138]  Brent M. T. Lok,et al.  Silicoaluminophosphate molecular sieves: another new class of microporous crystalline inorganic solids , 1984 .

[139]  Martin J. Hanton,et al.  Ruthenium-catalysed hydrogenation of esters using tripodal phosphine ligands , 2011 .

[140]  W. Ying,et al.  Effects of Zr and K Promoters on Precipitated Iron-Based Catalysts for Fischer–Tropsch Synthesis , 2011, Catalysis Letters.

[141]  G. Menchi,et al.  Homogeneous catalytic hydrogenation dicarboxylic acid esters. II , 1986 .

[142]  D. Leckel,et al.  Diesel production in coal-based high-temperature Fischer–Tropsch plants using fixed bed dry bottom gasification technology , 2011 .

[143]  Baowei Wang,et al.  A Pd–Fe/α-Al2O3/cordierite monolithic catalyst for CO coupling to oxalate , 2011 .

[144]  Guoli Fan,et al.  Highly-Dispersed Copper-Based Catalysts from Cu–Zn–Al Layered Double Hydroxide Precursor for Gas-Phase Hydrogenation of Dimethyl Oxalate to Ethylene Glycol , 2012, Catalysis Letters.

[145]  K. Klier,et al.  Characterization of cu/ZnO methanol synthesis catalysts by analytical electron microscopy , 1983 .

[146]  Kangnian Fan,et al.  Cu/SiO2 catalysts prepared by the ammonia-evaporation method: Texture, structure, and catalytic performance in hydrogenation of dimethyl oxalate to ethylene glycol , 2008 .

[147]  Qingxia Wang,et al.  CO Hydrogenation to Light Alkenes Over Mn/Fe Catalysts Prepared by Coprecipitation and Sol-gel Methods , 2005 .

[148]  Guohui Yang,et al.  Confinement effect and synergistic function of H-ZSM-5/Cu-ZnO-Al2O3 capsule catalyst for one-step controlled synthesis. , 2010, Journal of the American Chemical Society.

[149]  Wei Wang,et al.  Mechanistic investigations of the methanol-to-olefin (MTO) process on acidic zeolite catalysts by in situ solid-state NMR spectroscopy , 2006 .

[150]  Shurong Wang,et al.  Hydrogen Production via Acetic Acid Steam Reforming over HZSM-5 and Pd/HZSM-5 Catalysts and Subsequent Mechanism Studies , 2013 .

[151]  Alberto Boretti,et al.  Renewable hydrogen to recycle CO2 to methanol , 2013 .

[152]  S. Ihm,et al.  Effect of metal dispersion on CO hydrogenation over Pd/HZSM-5 catalysts , 1995 .

[153]  W. Yuan,et al.  Synthesis of Dimethyl Oxalate from CO and CH3ONO on Carbon Nanofiber Supported Palladium Catalysts , 2004 .

[154]  B. Jager,et al.  Advances in low temperature Fischer-Tropsch synthesis , 1995 .

[155]  F. J. Waller Recent achievements, trends and prospects in homogeneous catalysis , 1985 .

[156]  Jeffery L. White Methanol-to-hydrocarbon chemistry: The carbon pool (r)evolution , 2011 .

[157]  He Fei,et al.  Combined XPS and in situ DRIRS study of mechanism of Pd–Fe/α-Al2O3 catalyzed CO coupling reaction to diethyl oxalate , 2005 .

[158]  N. R. Shiju,et al.  Bimetallic catalysts for the Fischer-Tropsch reaction , 2011 .

[159]  Jianwei Zheng,et al.  Highly efficient mesostructured Ag/SBA-15 catalysts for the chemoselective synthesis of methyl glycolate by dimethyl oxalate hydrogenation , 2013 .

[160]  Ejm Emiel Hensen,et al.  Structure sensitivity of the Fischer–Tropsch reaction; molecular kinetics simulations , 2011 .

[161]  E. Iglesia,et al.  Chain growth reactions of methanol on SAPO-34 and H-ZSM5 , 1998 .

[162]  Qiang Zhang,et al.  Pore-structure-mediated hierarchical SAPO-34: Facile synthesis, tunable nanostructure, and catalysis applications for the conversion of dimethyl ether into olefins , 2013 .

[163]  A. Basu,et al.  Introduction and advancement of a new clean global fuel: The status of DME developments in China and beyond , 2012 .

[164]  D. Brands,et al.  Modification of Cu/ZnO/SiO2 catalysts by high temperature reduction , 2000 .