The study of the structure rebuilding and yield stress of 3D printing geopolymer pastes

Abstract For 3D printing construction materials, workability and interlayer force of fresh printing pastes were necessary to ensured extrudability and buildability in the period from extrude to hardened of pastes. The workability and interlayer force of 3 Dimensional printing geopolymer pastes related to its rheological property and more particularly to its structure rebuilding and yield stress. The present study is aimed at investigating structure rebuilding and yield stress of 3 Dimensional printing geopolymer pastes at different Si/Na ratio of alkali activator by rheology method. Results revealed that rheology is an important research method for the extrudability and buildability of 3D printing geopolymer pastes. Structure rebuilding ability (SRE) and fast-growing yield stress of 3 Dimensional printing geopolymer ensured the stability of structure in the period from extrude to hardened of paste. Si/Na ratio of alkali activator has significantly influences on extrudability and buildability of 3D printing geopolymer pastes. High Si/Na ratio of alkali activator decreases the viscosity, yield stress and development rate of fresh pastes. Si/Na ratio of alkali activation significantly influences rate of structure rebuilding of pastes, and low Si/Na ratio of alkali activator exhibited high ability of recovery of pastes.

[1]  Clément Gosselin,et al.  Large-scale 3D printing of ultra-high performance concrete – a new processing route for architects and builders , 2016 .

[2]  André Nonat,et al.  Dynamic mode rheology of cement and tricalcium silicate pastes from mixing to setting , 2001 .

[3]  Silvio Delvasto,et al.  Morteros de cementos alcalinos. Resistencia química al ataque por sulfatos y al agua de mar , 2002 .

[4]  Y. Adachi,et al.  Effect of floc structure on the rate of Brownian coagulation. , 2006, Journal of colloid and interface science.

[5]  Francisca Puertas,et al.  Effect of activator mix on the hydration and strength behaviour of alkali-activated slag cements , 2003 .

[6]  Jay G. Sanjayan,et al.  Resistance of alkali-activated slag concrete to acid attack , 2003 .

[7]  M. Daimon,et al.  Hydration of fly ash cement , 2005 .

[8]  Anthony Atala,et al.  3D bioprinting of tissues and organs , 2014, Nature Biotechnology.

[9]  Fabio Gramazio,et al.  Complex concrete structures: Merging existing casting techniques with digital fabrication , 2015, Comput. Aided Des..

[10]  B. Rangan,et al.  FACTORS INFLUENCING THE COMPRESSIVE STRENGTH OF FLY ASH-BASED GEOPOLYMER CONCRETE , 2004 .

[11]  Phillip Frank Gower Banfill,et al.  Rheology of fresh cement and concrete , 1991 .

[12]  Jon Elvar Wallevik,et al.  Rheological properties of cement paste: Thixotropic behavior and structural breakdown , 2009 .

[13]  Arnaud Perrot,et al.  Non-linear modeling of yield stress increase due to SCC structural build-up at rest , 2017 .

[14]  T. T. Le,et al.  Mix design and fresh properties for high-performance printing concrete , 2012 .

[15]  Zhihui Sun,et al.  Rheological Method to Evaluate Structural Buildup in Self-Consolidating Concrete Cement Pastes , 2007 .

[16]  Longtu Li,et al.  A review: The comparison between alkali-activated slag (Si + Ca) and metakaolin (Si + Al) cements , 2010 .

[17]  Kenneth J. D. MacKenzie,et al.  Thermal behaviour of inorganic geopolymers and composites derived from sodium polysialate , 2003 .

[18]  N. Roussel,et al.  Correlation between L-box test and rheological parameters of a homogeneous yield stress fluid , 2006 .

[19]  Nicolas Roussel,et al.  The origins of thixotropy of fresh cement pastes , 2012 .

[20]  Damien Rangeard,et al.  Structural built-up of cement-based materials used for 3D-printing extrusion techniques , 2016 .

[21]  J. Provis Discussion of C. Li et al., “A review: The comparison between alkali-activated slag (Si + Ca) and metakaolin (Si + Al) cements” , 2010 .