Nickel(II) complexes based on l-amino-acid-derived ligands: synthesis, characterization and study of the role of the supramolecular structure in carbon dioxide capture

Two l-amino-acid-based NiII complexes are reported; while the l-tyrosine derivative is a symmetrical μ3-carbonate-bridged self-assembled trinuclear NiII complex whose formation involves CO2 uptake, the l-phenylalanine analog is a mononuclear system which does not exhibit the same behaviour.

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