Life cycle analysis of biodiesel production

Abstract Biodiesel has attracted considerable attention as a renewable, biodegradable, and nontoxic fuel and can contribute to solving the energy problems, significantly reducing the emission of gases which cause global warming. The first stage of this work was to simulate different alternative processes for producing biodiesel. The method used for the production of biodiesel is the transesterification of vegetable oils with an alcohol in the presence of a catalyst. The raw materials used were palm oils and waste cooking oil. The second stage was a life cycle analysis for all alternatives under study, followed by an economic analysis for the alternatives that present minor impacts and which are more promising from an economic point of view. Finally, we proceeded to compare the different alternatives from both the point of view of life cycle and economic analysis. The feasibility of all processes was proven and the biodiesel obtained had good specifications. From the standpoint of life cycle analysis, the best alternative was the process of alkaline catalysis with acid pre-treatment for waste cooking oil. The economic analysis was done to the previous mentioned process and to the process that uses raw virgin oils, methanol, and sodium hydroxide. This process has lower investment costs but the process of alkaline catalysis with acid pre-treatment, whose main raw material is waste oil, is much more profitable and has less environmental impacts.

[1]  James M. Douglas,et al.  Conceptual Design of Chemical Processes , 1988 .

[2]  L. Canoira,et al.  Catalytic production of biodiesel from soy-bean oil, used frying oil and tallow , 2000 .

[3]  M. Dubé,et al.  Biodiesel production from waste cooking oil: 1. Process design and technological assessment. , 2003, Bioresource technology.

[4]  Klaus D. Timmerhaus,et al.  Plant design and economics for chemical engineers , 1958 .

[5]  Mahmoud M. El-Halwagi,et al.  Process analysis and optimization of biodiesel production from soybean oil , 2009 .

[6]  S. Cataldo,et al.  Determination of the Kinetics of Biodiesel Production Using Proton Nuclear Magnetic Resonance Spectroscopy (1H NMR) , 2006 .

[7]  E. H. Pryde,et al.  Variables affecting the yields of fatty esters from transesterified vegetable oils , 1984 .

[8]  Naoko Ellis,et al.  Assessment of four biodiesel production processes using HYSYS.Plant. , 2008, Bioresource technology.

[9]  Joseph R. Davis Corrosion: Understanding The Basics , 2000 .

[10]  J. Goodrum Volatility and boiling points of biodiesel from vegetable oils and tallow , 2002 .

[11]  P. Monsan,et al.  Lipase-catalyzed enantioselective transesterification toward esters of 2-bromo-tolylacetic acids , 2003 .

[12]  M. G. Kulkarni,et al.  WASTE COOKING OIL – AN ECONOMICAL SOURCE FOR BIODIESEL: A REVIEW , 2006 .

[13]  F. Karaosmanôglu,et al.  Optimization of Base-Catalyzed Transesterification Reaction of Used Cooking Oil , 2004 .

[14]  D. Skala,et al.  The problems in design and detailed analyses of energy consumption for biodiesel synthesis at supercritical conditions , 2009 .

[15]  Yoshio Tominaga,et al.  Enzymatic conversion of waste edible oil to biodiesel fuel in a fixed-bed bioreactor , 2001 .