论文信息 - PARAMAGNETIC ABSORPTION OF SINGLE CRYSTALS OF SUCCINIC ACID IRRADIATED AT LOW TEMPERATURE.

PARAMAGNETIC ABSORPTION OF SINGLE CRYSTALS OF SUCCINIC ACID IRRADIATED AT LOW TEMPERATURE.

Electron spin resonance absorption was observed in single crystals of (–CH2–COOH)2, (–CH2–;COOD)2, and (–CH2–13COOH)2 irradiated at 77°K. The principal paramagnetic species observed at low temperature has an unpaired electron in a 2pπ orbital on the carbon atom of the carboxyl group. It is probably ionized succinic acid with the oxygen of the carboxyl group carrying a negative charge.

H. Box | H. Freund | K. Lilga

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