Modeling the hydration of concrete incorporating fly ash or slag

Granulated slag from metal industries and fly ash from the combustion of coal are industrial by-products that have been widely used as mineral admixtures in normal and high strength concrete. Due to the reaction between calcium hydroxide and fly ash or slag, the hydration of concrete containing fly ash or slag is much more complex compared with that of Portland cement. In this paper, the production of calcium hydroxide in cement hydration and its consumption in the reaction of mineral admixtures is considered in order to develop a numerical model that simulates the hydration of concrete containing fly ash or slag. The heat evolution rates of fly ash- or slag-blended concrete is determined by the contribution of both cement hydration and the reaction of the mineral admixtures. The proposed model is verified through experimental data on concrete with different water-to-cement ratios and mineral admixture substitution ratios.

[1]  A.L.A. Fraaij,et al.  Three-dimensional microstructure analysis of numerically simulated cementitious materials , 2003 .

[2]  Satoshi Tanaka,et al.  Methods of Estimating Hydration Heat and Temperature Rise in Blast Furnace Slag Blended Cement , 1995 .

[3]  D. Bentz Modeling the influence of limestone filler on cement hydration using CEMHYD3D , 2006 .

[4]  D. Bentz,et al.  Kinetics of Slag Hydration in the Presence of Calcium Hydroxide , 2002 .

[5]  Pietro Lura,et al.  Early development of properties in a cement paste: A numerical and experimental study , 2003 .

[6]  K. van Breugel,et al.  Simulation of the effect of geometrical changes of the microstructure on the deformational behaviour of hardening concrete , 1997 .

[7]  Dale P Bentz,et al.  CEMHYD3D:: a three-dimensional cement hydration and microstructure development modelling package , 1997 .

[8]  P. Navi,et al.  Simulation of cement hydration and the connectivity of the capillary pore space , 1996 .

[9]  J. Sharp,et al.  The microstructure and mechanical properties of blended cements hydrated at various temperatures , 2001 .

[10]  K. van Breugel,et al.  NUMERICAL MODELLING OF AUTOGENOUS SHRINKAGE OF HARDENING CEMENT PASTE , 1997 .

[11]  D. Bentz,et al.  Stoichiometry of Slag Hydration with Calcium Hydroxide , 2004 .

[12]  Luc Taerwe,et al.  Towards a more fundamental non-linear basic creep model for early age concrete. , 1997 .

[13]  Han-seung Lee,et al.  A model predicting carbonation depth of concrete containing silica fume , 2009 .

[14]  W. A. Gutteridge,et al.  FILLER CEMENT: THE EFFECT OF THE SECONDARY COMPONENT ON THE HYDRATION OF PORTLAND CEMENT , 1990 .

[15]  Dale P. Bentz,et al.  Prediction of Adiabatic Temperature Rise in Conventional and High-Performance Concretes Using a 3-D Microstructural Model , 1998 .

[16]  Koichi Maekawa,et al.  Multi-scale modeling of structural concrete , 2008 .

[17]  Dale P Bentz,et al.  A three-dimensional cement hydration and microstructure program. I. hydration rate, heat of hydration, and chemical shrinkage , 1995 .

[18]  Luc Taerwe,et al.  General hydration model for portland cement and blast furnace slag cement , 1995 .

[19]  K. Breugel Numerical simulation of hydration and microstructural development in hardening cement-based materials: (II) applications , 1995 .

[20]  Vagelis G. Papadakis,et al.  Experimental investigation and theoretical modeling of silica fume activity in concrete , 1999 .

[21]  Wei Chen,et al.  Three-dimensional computer modeling of slag cement hydration , 2007 .

[22]  In-Seok Yoon,et al.  Prediction of Temperature Distribution in High-Strength Concrete Using Hydration Model , 2008 .

[23]  V. Papadakis Effect of fly ash on Portland cement systems. Part II. High-calcium fly ash , 1999 .

[24]  V. Papadakis Effect of supplementary cementing materials on concrete resistance against carbonation and chloride ingress , 2000 .

[25]  K. van Breugel,et al.  Numerical Simulation of Hydration and Microstructural Development in Hardening Cement-Based Materials , 1995 .

[26]  P. K. Mehta,et al.  Concrete: Microstructure, Properties, and Materials , 2005 .

[27]  Geert De Schutter,et al.  Hydration and temperature development of concrete made with blast-furnace slag cement. , 1999 .

[28]  Erick Ringot,et al.  Mineral Admixtures in Mortars Effect of Type, Amount and Fineness of Fine Constituents on Compressive Strength , 2005 .

[29]  Han-seung Lee,et al.  Simulation of Low-Calcium Fly Ash Blended Cement Hydration , 2009 .

[30]  F. Puertas,et al.  Determination of Kinetic Equations of Alkaline Activation of Blast Furnace Slag by Means of Calorimetric Data , 1998 .

[31]  K. Takemoto Hydration of pozzolanic cements , 1980 .

[32]  M. Cyr,et al.  Mineral Admixtures in Mortars. Quantification of the Physical Effects of Inert Materials on Short-Term Hydration , 2005 .

[33]  Dale P. Bentz,et al.  Influence of silica fume on diffusivity in cement-based materials: II. Multi-scale modeling of concrete diffusivity , 2000 .

[34]  Koichi Maekawa,et al.  MULTI-COMPONENT MODEL FOR HYDRATION HEAT OF PORTLAND CEMENT , 1995 .

[35]  Erick Ringot,et al.  Mineral admixtures in mortars Effect of inert materials on short-term hydration , 2003 .

[36]  K. Breugel,et al.  Modelling of cement-based systems: the alchemy of cement chemistry , 2004 .

[37]  Somsak Swaddiwudhipong,et al.  Simulation of the exothermic hydration process of Portland cement , 2002 .

[38]  M. Fardis,et al.  Physical and Chemical Characteristics Affecting the Durability of Concrete , 1991 .

[39]  Luc Taerwe,et al.  Degree of hydration-based description of mechanical properties of early age concrete , 1996 .

[40]  Vagelis G. Papadakis,et al.  Effect of fly ash on Portland cement systems , 1999 .

[41]  G. de Schutter,et al.  Numerical simulation of the hydration process and the development of microstructure of self-compacting cement paste containing limestone as filler , 2007 .

[42]  Tatsuhiko Saeki,et al.  A model to predict the amount of calcium hydroxide in concrete containing mineral admixtures , 2005 .

[43]  G. De Schutter,et al.  Finite element simulation of thermal cracking in massive hardening concrete elements using degree of hydration based material laws , 2002 .

[44]  J. Escalante,et al.  Reactivity of blast-furnace slag in Portland cement blends hydrated under different conditions , 2001 .

[45]  Ravindra K. Dhir,et al.  Experimental study and modelling of heat evolution of blended cements , 2005 .

[46]  Will Hansen,et al.  Investigation of blended cement hydration by isothermal calorimetry and thermal analysis , 2005 .

[47]  D. Logan A First Course in the Finite Element Method , 2001 .

[48]  Erick Ringot,et al.  Efficiency of mineral admixtures in mortars: Quantification of the physical and chemical effects of fine admixtures in relation with compressive strength , 2006 .

[49]  S. Swaddiwudhipong,et al.  Numerical simulation of temperature rise of highstrength concrete incorporating silica fume and superplasticiser , 2003 .

[50]  Dale P. Bentz,et al.  Influence of Water-to-Cement Ratio on Hydration Kinetics: Simple Models Based on Spatial Considerations , 2006 .

[51]  Dale P. Bentz,et al.  Influence of silica fume on diffusivity in cement-based materials: I. Experimental and computer modeling studies on cement pastes , 2000 .

[52]  Dale P. Bentz,et al.  Modelling cement microstructure: Pixels, particles, and property prediction , 1999 .

[53]  Koichi Maekawa,et al.  Modeling of structural performances under coupled environmental and weather actions , 2002 .

[54]  G. D. Schutter,et al.  Cement Hydration In The Presence Of High Filler Contents , 2005 .

[55]  W. A. Gutteridge,et al.  Filler cement: The effect of the secondary component on the hydration of Portland cement: Part I. A fine non-hydraulic filler , 1990 .

[56]  Han-Seung Lee,et al.  A model for predicting the carbonation depth of concrete containing low-calcium fly ash , 2009 .