Methanol Economy: Environment, Demand, and Marketing With a Focus on the Waste-to-Methanol Process

Abstract Methanol is an ideal energy vector to guarantee a smooth and effective transition from the actual oil-centric energy system to the new, more sustainable future of energy and chemistry. After introducing this changing scenario and the main paths for the use of methanol as a fuel and chemical, this chapter discusses more specifics regarding the economics of the production of methanol from waste-derived fuel as residue-derived fuel (Rdf). It is shown that biomethanol produced in this way, which may be counted double for its bioenergy content, may have a value in the 400–450 € per ton range against a cost of production that, in the worst-case scenario, does not exceed 200 € per ton. For a 300 t/d methanol plant, a return of investment (ROI) of 29% is expected; meanwhile for a 150 t/d capacity, the ROI is reduced to 18%.

[1]  G. Olah Beyond oil and gas: the methanol economy. , 2006, Angewandte Chemie.

[2]  G. Vicente,et al.  Main technologies in biodiesel production: State of the art and future challenges , 2012 .

[3]  S. El‐Safty,et al.  Development of Mesoscopically Assembled Sulfated Zirconia Nanoparticles as Promising Heterogeneous and Recyclable Biodiesel Catalysts , 2013 .

[4]  S. Mullens,et al.  Structured catalysts for methanol-to-olefins conversion: a review , 2014, Chemical Papers.

[5]  De Chen,et al.  A methanol to olefins review: Diffusion, coke formation and deactivation on SAPO type catalysts , 2012 .

[6]  Y. Yoneyama,et al.  Catalysis Chemistry of Dimethyl Ether Synthesis , 2014 .

[7]  K. Lillerud,et al.  Conversion of methanol to hydrocarbons: how zeolite cavity and pore size controls product selectivity. , 2012, Angewandte Chemie.

[8]  M. Bertau,et al.  Methanol findet zu wenig Beachtung als Kraftstoff und Chemierohstoff der Zukunft , 2010 .

[9]  Zoha Azizi,et al.  Dimethyl ether: A review of technologies and production challenges , 2014 .

[10]  Yanyong Liu,et al.  Synthesis of ethanol from methanol and syngas through an indirect route containing methanol dehydrogenation, DME carbonylation, and methyl acetate hydrogenolysis , 2013 .

[11]  K. Lillerud,et al.  Chapter 6:Shape selectivity in zeolite catalysis. The Methanol to Hydrocarbons (MTH) reaction , 2014 .

[12]  G. Olah,et al.  Chemical recycling of carbon dioxide to methanol and dimethyl ether: from greenhouse gas to renewable, environmentally carbon neutral fuels and synthetic hydrocarbons. , 2009, The Journal of organic chemistry.

[13]  Georg Menges,et al.  Methanol Needs More Attention as a Fuel and Raw Material for the Future , 2010 .

[14]  G. Centi,et al.  A New Scenario for Green & Sustainable Chemical Production , 2014 .

[15]  John-Paul Jones,et al.  Recycling of carbon dioxide to methanol and derived products - closing the loop. , 2014, Chemical Society reviews.

[16]  Zhongmin Liu,et al.  Methanol to Olefins (MTO): From Fundamentals to Commercialization , 2015 .

[17]  Siglinda Perathoner,et al.  Catalysis for biomass and CO2 use through solar energy: opening new scenarios for a sustainable and low-carbon chemical production. , 2014, Chemical Society reviews.

[18]  G. Centi,et al.  Energy Related Catalysis , 2015 .

[19]  A. Vonortas,et al.  Comparative analysis of biodiesel versus green diesel , 2014 .

[20]  S. Khadzhiev,et al.  Mechanism of olefin synthesis from methanol and dimethyl ether over zeolite catalysts: A review , 2014, Petroleum Chemistry.

[21]  D. Simonetti,et al.  Selective homogeneous and heterogeneous catalytic conversion of methanol/dimethyl ether to triptane. , 2012, Accounts of chemical research.

[22]  Siglinda Perathoner,et al.  Chemical Energy Conversion as Enabling Factor to Move to a Renewable Energy Economy , 2015 .

[23]  Siglinda Perathoner,et al.  Trading Renewable Energy by using CO2: An Effective Option to Mitigate Climate Change and Increase the use of Renewable Energy Sources , 2014 .