Seasonal variation of UV radiation in the ocean under clear and cloudy conditions

Seasonal variability of solar UV radiation in ocean waters is estimated on a global scale by combining satellite measurements of scene reflectivity (TOMS), column ozone (TOMS) and chlorophyll concentration (SeaWiFS) with radiative transfer calculations for an ocean-atmosphere system. The new features are an extension of underwater radiative transfer (scattering and absorption) into the UV, inclusion of polarization in the above water diffuse radiances, the proper treatment of Fresnel reflection, and first order atmospheric backscatter of water-leaving radiance to the oceans. Maps of downwelling diffuse irradiances (Ed) at ocean surface and at different depths in the ocean, diffuse attenuation coefficient (Kd), and ten percent penetration depth (Z10) of solar irradiation are computed for open ocean waters. Results on spectral irradiances at 310 nm in UV-B and at 380 nm in UV-A part of the spectrum are presented with particular emphasis on the role of aerosols, clouds, and ozone in the atmosphere and chlorophyll concentrations in the ocean.

[1]  Ziauddin Ahmad,et al.  An Iterative Radiative Transfer Code For Ocean-Atmosphere Systems , 1982 .

[2]  James B. Kerr,et al.  Satellite estimation of spectral surface UV irradiance in the presence of tropospheric aerosols , 1998 .

[3]  Shea L. Valley Handbook of Geophysics and Space Environments , 1966 .

[4]  Jay R. Herman,et al.  Distribution of UV radiation at the Earth's surface from TOMS-measured UV-backscattered radiances , 1999 .

[5]  John J. Cullen,et al.  Interactive effects of ozone depletion and vertical mixing on photosynthesis of Antarctic phytoplankton , 1998, Nature.

[6]  K. Arrigo,et al.  Global mapping of underwater UV irradiances and DNA‐weighted exposures using Total Ozone Mapping Spectrometer and Sea‐viewing Wide Field‐of‐view Sensor data products , 2001 .

[7]  Ziauddin Ahmad,et al.  Satellite Estimation of Spectral Surface UV Irradiance. 2; Effect of Horizontally Homogeneous Clouds , 1998 .

[8]  Ulrich Schmidt,et al.  Vertical profile measurements of carbonylsulfide in the stratosphere , 1994 .

[9]  E. Fry,et al.  Absorption spectrum (380-700 nm) of pure water. II. Integrating cavity measurements. , 1997, Applied optics.

[10]  Eyvind Aas,et al.  A relationship for the penetration of ultraviolet B radiation into the Norwegian Sea , 1991 .

[11]  Kr Arrigo,et al.  Impact of ozone depletion on phytoplankton growth in the Southern Ocean: large-scale spatial and temporal variaoility , 1994 .

[12]  John H. Morrow,et al.  The effects of UV radiation in the marine environment: UV physics and optics , 2000 .

[13]  M. Kahru,et al.  Spectral reflectance and absorption of a massive red tide off southern California , 1998 .

[14]  K. Arrigo,et al.  Global Mapping of Underwater UV Irradiances and DNA-Weighted Exposures using TOMS and SeaWiFS Data Products , 1999 .

[15]  J. Hovenier Multiple Scattering of Polarized Light in Planetary Atmospheres , 1971 .

[16]  Meinrat O. Andreae,et al.  Factors affecting the photochemical production of carbonyl sulfide in seawater , 1994 .

[17]  C. Mobley Light and Water: Radiative Transfer in Natural Waters , 1994 .

[18]  Maria Vernet,et al.  The effects of UV radiation in the marine environment: Index , 2000 .

[19]  Dan Lubin,et al.  Ultraviolet Radiation and Its Effects on Organisms in Aquatic Environments , 1993 .

[20]  G. E. Brueckner,et al.  The solar ultraviolet spectral irradiance monitor (SUSIM) experiment on board the Upper Atmosphere Research Satellite (UARS) , 1993 .

[21]  W. Rossow,et al.  Advances in understanding clouds from ISCCP , 1999 .

[22]  Jay R. Herman,et al.  Problems in assessment of the UV penetration into natural waters from space-based measurements , 2002, SPIE Optics + Photonics.

[23]  K. Stamnes,et al.  Numerically stable algorithm for discrete-ordinate-method radiative transfer in multiple scattering and emitting layered media. , 1988, Applied optics.

[24]  D. Deirmendjian Electromagnetic scattering on spherical polydispersions , 1969 .

[25]  A. R. Bohne,et al.  AIR FORCE GEOPHYSICS LABORATORY , 1988 .

[26]  W. Munk,et al.  Measurement of the Roughness of the Sea Surface from Photographs of the Sun’s Glitter , 1954 .

[27]  Dan Lubin,et al.  Impact of a deep ozone hole on Southern Ocean primary production , 2003 .

[28]  John J. Cullen,et al.  Inhibition of marine photosynthesis by ultraviolet radiation: Variable sensitivity of phytoplankton in the Weddell‐Scotia Confluence during the austral spring , 1998 .

[29]  T. I. Quickenden,et al.  The ultraviolet absorption spectrum of liquid water , 1980 .

[30]  Michael P. Lesser,et al.  The effects of UV radiation in the marine environment , 2001 .

[31]  Harshvardhan,et al.  Comparative accuracy of the Albedo, transmission and absorption for selected radiative transfer approximations , 1986 .

[32]  P. Bhartia,et al.  UV‐B increases (1979–1992) from decreases in total ozone , 1996 .

[33]  K. Baker,et al.  Ozone depletion: ultraviolet radiation and phytoplankton biology in antarctic waters. , 1992, Science.

[34]  James B. Kerr,et al.  Satellite estimation of spectral UVB irradiance using TOMS derived total ozone and UV reflectivity , 1995 .

[35]  A. Jursa,et al.  Handbook of geophysics and the space environment , 1985 .

[36]  J. Hansen,et al.  Multiple Scattering of Polarized Light in Planetary Atmospheres. Part I. The Doubling Method , 1971 .

[37]  Jay R. Herman,et al.  Interannual variability of ozone and UV‐B ultraviolet exposure , 2000 .

[38]  Paul J. Crutzen,et al.  The possible importance of CSO for the sulfate layer of the stratosphere , 1976 .

[39]  R. Charlson,et al.  Sulphate aerosol and climate , 1990, Nature.

[40]  K. Baker,et al.  Optical properties of the clearest natural waters (200-800 nm). , 1981, Applied optics.