Conceptual design of cost-effective and environmentally-friendly configurations for fuel ethanol production from sugarcane by knowledge-based process synthesis.

In this work, the hierarchical decomposition methodology was used to conceptually design the production of fuel ethanol from sugarcane. The decomposition of the process into six levels of analysis was carried out. Several options of technological configurations were assessed in each level considering economic and environmental criteria. The most promising alternatives were chosen rejecting the ones with a least favorable performance. Aspen Plus was employed for simulation of each one of the technological configurations studied. Aspen Icarus was used for economic evaluation of each configuration, and WAR algorithm was utilized for calculation of the environmental criterion. The results obtained showed that the most suitable synthesized flowsheet involves the continuous cultivation of Zymomonas mobilis with cane juice as substrate and including cell recycling and the ethanol dehydration by molecular sieves. The proposed strategy demonstrated to be a powerful tool for conceptual design of biotechnological processes considering both techno-economic and environmental indicators.

[1]  James M. Douglas,et al.  Conceptual Design of Chemical Processes , 1988 .

[2]  Heriberto Cabezas,et al.  Designing sustainable processes with simulation: the waste reduction (WAR) algorithm , 1999 .

[3]  Aline Carvalho da Costa,et al.  A Hybrid Neural Model of Ethanol Production by Zymomonas mobilis , 1999 .

[4]  John D. Perkins,et al.  Education in process systems engineering past, present and future , 2000 .

[5]  Carlos A. Cardona,et al.  Analysis of the environmental impact of butylacetate process through the WAR algorithm , 2004 .

[6]  Julius Žilinskas,et al.  Computer aided methods in optimal design and operations , 2006 .

[7]  Julián A. Quintero,et al.  Fuel ethanol production from sugarcane and corn: Comparative analysis for a Colombian case , 2008 .

[8]  Alistair McVittie,et al.  The economic viability of Environmental Management Systems: an application of Analytical Hierarchy Process as a methodological tool to rank trade-offs , 2008 .

[9]  Oscar Garro,et al.  Mathematical modelling of the alcoholic fermentation of glucose by Zymomonas mobilis mobilis , 1995 .

[10]  Carlos A. Cardona,et al.  ANALYSIS OF AN EXTRACTIVE FERMENTATION PROCESS FOR ETHANOL PRODUCTION USING A RIGOROUS MODEL AND A SHORT-CUT METHOD , 2006 .

[11]  Warren D. Seider,et al.  Process design principles : synthesis, analysis, and evaluation , 1999 .

[12]  Pramod Agrawal,et al.  A structured kinetic model for Zymomonas mobilis ATCC10988 , 1990, Biotechnology and bioengineering.

[13]  Chun-Po Juang,et al.  Evaluation of bioenergy recovery processes treating organic residues from ethanol fermentation process. , 2011, Bioresource technology.

[14]  Carlos A Cardona,et al.  Fuel ethanol production: process design trends and integration opportunities. , 2007, Bioresource technology.

[15]  Kazuyuki Shimizu,et al.  Performance evaluation of ethanol fermentor systems using a vector‐valued objective function , 1987, Biotechnology and bioengineering.

[16]  David R. Shonnard,et al.  Design Guidance for Chemical Processes Using Environmental and Economic Assessments , 2002 .

[17]  K. Ulgen,et al.  Mathematical description of ethanol fermentation by immobilised Saccharomyces cerevisiae , 1998 .

[18]  Robin Smith,et al.  Chemical Process: Design and Integration , 2005 .

[19]  C. Cardona,et al.  Process Synthesis for Fuel Ethanol Production , 2009 .

[20]  R. Baker Membrane Technology and Applications , 1999 .

[21]  Ethanol production by a flocculant yeast strain in a CSTR type fermentor with cell recycling , 1999, Applied biochemistry and biotechnology.

[22]  Shuichi Aiba,et al.  Kinetics of product inhibition in alcohol fermentation , 2000, Biotechnology and bioengineering.

[23]  Ignacio E. Grossmann,et al.  Systematic Methods of Chemical Process Design , 1997 .

[24]  J. Luong Kinetics of ethanol inhibition in alcohol fermentation , 1985, Biotechnology and bioengineering.

[25]  M. Taherzadeh,et al.  Techno-economical study of ethanol and biogas from spruce wood by NMMO-pretreatment and rapid fermentation and digestion. , 2011, Bioresource technology.

[26]  G A Coulman,et al.  Ethanol fermentation with cell recycling: Computer simulation , 1983, Biotechnology and bioengineering.

[27]  A. Navarro,et al.  Bio-concentration of vinasse from the alcoholic fermentation of sugar cane molasses , 2000 .

[28]  Xiao-Ning Li,et al.  Conceptual process synthesis: past and current trends , 2004 .

[29]  Silvia A. Nebra,et al.  Improving bioethanol production from sugarcane: evaluation of distillation, thermal integration and , 2011 .

[30]  A. Daugulis,et al.  Extractive fermentation by Zymomonas mobilis and the use of solvent mixtures , 2005, Biotechnology Letters.