Short-channel field-effect transistors with 9-atom and 13-atom wide graphene nanoribbons

Bottom-up synthesized graphene nanoribbons and graphene nanoribbon heterostructures have promising electronic properties for high-performance field-effect transistors and ultra-low power devices such as tunneling field-effect transistors. However, the short length and wide band gap of these graphene nanoribbons have prevented the fabrication of devices with the desired performance and switching behavior. Here, by fabricating short channel (Lch ~ 20 nm) devices with a thin, high-κ gate dielectric and a 9-atom wide (0.95 nm) armchair graphene nanoribbon as the channel material, we demonstrate field-effect transistors with high on-current (Ion > 1 μA at Vd = −1 V) and high Ion/Ioff ~ 105 at room temperature. We find that the performance of these devices is limited by tunneling through the Schottky barrier at the contacts and we observe an increase in the transparency of the barrier by increasing the gate field near the contacts. Our results thus demonstrate successful fabrication of high-performance short-channel field-effect transistors with bottom-up synthesized armchair graphene nanoribbons.Graphene nanoribbons show promise for high-performance field-effect transistors, however they often suffer from short lengths and wide band gaps. Here, the authors use a bottom-up synthesis approach to fabricate 9- and 13-atom wide ribbons, enabling short-channel transistors with 105 on-off current ratio.

[1]  H. Fuchs,et al.  Electronic structure of spatially aligned graphene nanoribbons on Au(788). , 2012, Physical review letters.

[2]  P. Ruffieux,et al.  On‐Surface Synthesis of Atomically Precise Graphene Nanoribbons , 2016, Advanced materials.

[3]  J. Bokor,et al.  Bottom-up graphene nanoribbon field-effect transistors , 2013, 1310.0495.

[4]  Jeffrey Bokor,et al.  Ultimate device scaling: Intrinsic performance comparisons of carbon-based, InGaAs, and Si field-effect transistors for 5 nm gate length , 2011, 2011 International Electron Devices Meeting.

[5]  Thomas Dienel,et al.  On-surface Synthesis of Graphene Nanoribbons with Zigzag Edge Topology References and Notes , 2022 .

[6]  Aaron D. Franklin,et al.  Electronics: The road to carbon nanotube transistors , 2013, Nature.

[7]  A. Ferrari,et al.  Raman Fingerprints of Atomically Precise Graphene Nanoribbons , 2016, Nano letters.

[8]  L. Reichl,et al.  Selection rule for the optical absorption of graphene nanoribbons , 2007 .

[9]  P. Lambin,et al.  Theoretical study of the vibrational edge modes in graphene nanoribbons , 2008 .

[10]  Reinhard Berger,et al.  Graphene nanoribbon heterojunctions. , 2014, Nature nanotechnology.

[11]  Fujita,et al.  Edge state in graphene ribbons: Nanometer size effect and edge shape dependence. , 1996, Physical review. B, Condensed matter.

[12]  Mark S. Lundstrom,et al.  Sub-10 nm carbon nanotube transistor , 2011, 2011 International Electron Devices Meeting.

[13]  Jing Guo,et al.  Effect of edge roughness in graphene nanoribbon transistors , 2007, 0712.3928.

[14]  C. Pignedoli,et al.  On-Surface Synthesis and Characterization of 9-Atom Wide Armchair Graphene Nanoribbons. , 2017, ACS nano.

[15]  H. Dai,et al.  Narrow graphene nanoribbons from carbon nanotubes , 2009, Nature.

[16]  Kang L. Wang,et al.  Vapor-phase transport deposition, characterization, and applications of large nanographenes. , 2015, Journal of the American Chemical Society.

[17]  Jing Guo,et al.  Computational study of tunneling transistor based on graphene nanoribbon. , 2009, Nano letters.

[18]  Cheol-Hwan Park,et al.  Self-interaction in Green ’ s-function theory of the hydrogen atom , 2007 .

[19]  M. Radosavljevic,et al.  Tunneling versus thermionic emission in one-dimensional semiconductors. , 2004, Physical review letters.

[20]  K. Müllen,et al.  New advances in nanographene chemistry. , 2015, Chemical Society reviews.

[21]  William R. Dichtel,et al.  Ambipolar Transport in Solution-Synthesized Graphene Nanoribbons. , 2016, ACS nano.

[22]  Yoshihiro Iwasa,et al.  Ambipolar MoS2 thin flake transistors. , 2012, Nano letters.

[23]  S. Wind,et al.  Field-modulated carrier transport in carbon nanotube transistors. , 2002, Physical review letters.

[24]  Ari Harju,et al.  Ultra-narrow metallic armchair graphene nanoribbons , 2015, Nature Communications.

[25]  Zhihong Chen,et al.  Length scaling of carbon nanotube transistors. , 2010, Nature nanotechnology.

[26]  Ting Cao,et al.  Molecular bandgap engineering of bottom-up synthesized graphene nanoribbon heterojunctions. , 2015, Nature nanotechnology.

[27]  Phaedon Avouris,et al.  The role of metal-nanotube contact in the performance of carbon nanotube field-effect transistors. , 2005, Nano letters.

[28]  H. Dai,et al.  Chemically Derived, Ultrasmooth Graphene Nanoribbon Semiconductors , 2008, Science.

[29]  W. Haensch,et al.  Schottky-to-Ohmic crossover in carbon nanotube transistor contacts. , 2013, Physical review letters.

[30]  F. Fischer,et al.  Tuning the band gap of graphene nanoribbons synthesized from molecular precursors. , 2013, ACS nano.

[31]  Gerald J. Brady,et al.  Direct oriented growth of armchair graphene nanoribbons on germanium , 2015, Nature Communications.

[32]  Xinran Wang,et al.  Etching and narrowing of graphene from the edges. , 2010, Nature chemistry.

[33]  H. Wong,et al.  Schottky-Barrier Carbon Nanotube Field-Effect Transistor Modeling , 2007, IEEE Transactions on Electron Devices.

[34]  A. Seitsonen,et al.  Atomically precise bottom-up fabrication of graphene nanoribbons , 2010, Nature.

[35]  Chongwu Zhou,et al.  Deposition, characterization, and thin-film-based chemical sensing of ultra-long chemically synthesized graphene nanoribbons. , 2014, Journal of the American Chemical Society.

[36]  M. Bonn,et al.  Synthesis of structurally well-defined and liquid-phase-processable graphene nanoribbons. , 2014, Nature chemistry.