Effect of surface stress on the stiffness of thin elastic plates and beams

Nanomechanical doubly-clamped beams and cantilever plates are often used to sense a host of environmental effects, including biomolecular interations, mass measurements, and responses to chemical stimuli. Understanding the effects of surface stress on the stiffness of such nanoscale devices is essential for rigorous analysis of experimental data. Recently, we explored the effects of surface stress on cantilever plates and presented a theoretical framework valid for thin plate structures. Here, we generalize this framework and apply it to cantilever plates and doubly-clamped beams, exploring in detail the relative physical mechanisms causing a stiffness change in each case. Specifically, Poisson’s ratio is found to exert a dramatically different effect in cantilevers than in doubly-clamped beams, and here we explain why. The relative change in effective spring constant is also examined, and its connection to the relative frequency shift is discussed. Interestingly, this differs from what is naively expected from elementary mechanics. Finally, a discussion of the practical implications of our theoretical findings is presented, which includes an assessment of available experimental results and potential future measurements on nanoscale devices.

[1]  James K. Gimzewski,et al.  Surface stress in the self-assembly of alkanethiols on gold , 1997 .

[2]  Thomas Thundat,et al.  Adsorption-induced surface stress and its effects on resonance frequency of microcantilevers , 1995 .

[3]  Harry C. Gatos,et al.  Surface stress and the normal mode of vibration of thin crystals :GaAs , 1975 .

[4]  Ya-Pu Zhao,et al.  Modelling analysis of surface stress on a rectangular cantilever beam , 2004 .

[5]  Xi-Qiao Feng,et al.  Effects of surface elasticity and residual surface tension on the natural frequency of microbeams , 2007 .

[6]  Thomas Thundat,et al.  Determination of adsorption-induced variation in the spring constant of a microcantilever , 2002 .

[7]  E. H. Mansfield The Bending and Stretching of Plates , 1963 .

[8]  Huiling Duan,et al.  Surface stress induced by interactions of adsorbates and its effect on deformation and frequency of microcantilever sensors , 2009 .

[9]  Scheffler,et al.  Reconstruction mechanism of fcc transition metal (001) surfaces. , 1993, Physical review letters.

[10]  Javier Tamayo,et al.  Study of the Origin of Bending Induced by Bimetallic Effect on Microcantilever , 2007, Sensors.

[11]  D. Gerstenberg,et al.  Physics of Thin Films , 1964 .

[12]  Javier Tamayo,et al.  Arrays of dual nanomechanical resonators for selective biological detection. , 2009, Analytical chemistry.

[13]  Tae Song Kim,et al.  Effect of mass and stress on resonant frequency shift of functionalized Pb(Zr0.52Ti0.48)O3 thin film microcantilever for the detection of C-reactive protein , 2004 .

[14]  M. Sepaniak,et al.  Cantilever transducers as a platform for chemical and biological sensors , 2004 .

[15]  T. Thundat,et al.  Investigating the Mechanical Effects of Adsorption of Ca2+ Ions on a Silicon Nitride Microcantilever Surface , 2002 .

[16]  G. Stoney The Tension of Metallic Films Deposited by Electrolysis , 1909 .

[17]  Seyyed M. Hasheminejad,et al.  Surface effects on nonlinear free vibration of nanobeams , 2011 .

[18]  M. R. Freeman,et al.  Multifunctional Nanomechanical Systems via Tunably Coupled Piezoelectric Actuation , 2007, Science.

[19]  E. A. Wachter,et al.  Detection of mercury vapor using resonating microcantilevers , 1995 .

[20]  Heow Pueh Lee,et al.  Surface stress effects on the resonance properties of cantilever sensors , 2005 .

[21]  Shyamsunder Erramilli,et al.  Dynamical response of nanomechanical oscillators in immiscible viscous fluid for in vitro biomolecular recognition. , 2006, Physical review letters.

[22]  H. Duan Surface-enhanced cantilever sensors with nano-porous films , 2010 .

[23]  Laura M Lechuga,et al.  Microcantilever-based platforms as biosensing tools. , 2010, The Analyst.

[24]  S. Timoshenko,et al.  THEORY OF PLATES AND SHELLS , 1959 .

[25]  K. Dahmen,et al.  Bending of crystalline plates under the influence of surface stress — a finite element analysis , 2000 .

[26]  Thomas Thundat,et al.  Simulation of adsorption-induced stress of a microcantilever sensor , 2005 .

[27]  Javier Tamayo,et al.  Shedding light on axial stress effect on resonance frequencies of nanocantilevers. , 2011, ACS nano.

[28]  Harald Ibach,et al.  The role of surface stress in reconstruction, epitaxial growth and stabilization of mesoscopic structures , 1997 .

[29]  Jung Ho Park,et al.  Dominant surface stress driven by biomolecular interactions in the dynamical response of nanomechanical microcantilevers , 2006 .

[30]  Axel Scherer,et al.  Nanowire-Based Very-High-Frequency Electromechanical Resonator , 2003 .

[31]  Jonathan S. Colton,et al.  Influence of surface stress on the resonance behavior of microcantilevers , 2005 .

[32]  R. Maranganti,et al.  Length scales at which classical elasticity breaks down for various materials. , 2007, Physical review letters.

[33]  R. N. Thurston,et al.  Effect of surface stress on the natural frequency of thin crystals , 1976 .

[34]  Morton E. Gurtin,et al.  A continuum theory of elastic material surfaces , 1975 .

[35]  J. Sader,et al.  Rheological measurements using microcantilevers , 2002 .

[36]  John E Sader,et al.  Effect of surface stress on the stiffness of cantilever plates. , 2007, Physical review letters.

[37]  John E. Sader,et al.  Effect of surface stress on the stiffness of cantilever plates. , 2007 .

[38]  Dae Sung Yoon,et al.  Nanomechanical resonators and their applications in biological/chemical detection: Nanomechanics pri , 2011 .

[39]  Pierre Müller,et al.  About the measurement of absolute isotropic surface stress of crystals , 1994 .

[40]  T. Dumitricǎ,et al.  Bending ultrathin graphene at the margins of continuum mechanics. , 2011, Physical review letters.

[41]  E. M. Lifshitz,et al.  Theory of Elasticity: Vol. 7 of Course of Theoretical Physics , 1960 .

[42]  Javier Tamayo,et al.  Effect of the adsorbate stiffness on the resonance response of microcantilever sensors , 2006 .