Galvanostatic Polarization of All‐Solid‐State K+‐Selective Electrodes with Polypyrrole Ion‐to‐Electron Transducer

Influence of galvanostatic polarizations on potential vs. logarithm of ion activity dependences of all-solid-state ion-selective electrodes with conducting polymer ion-to-electron transducer was studied. As a model system K+-sensor with polypyrrole solid contact and poly(vinyl chloride) based membrane containing valinomycin was chosen. The influence of the lipophilic salt included to the membrane composition was of special interest.

[1]  J. Bobacka Conducting Polymer‐Based Solid‐State Ion‐Selective Electrodes , 2006 .

[2]  A. Michalska,et al.  Conducting polymer membranes for low activity potentiometric ion sensing. , 2004, Talanta.

[3]  A. Michalska,et al.  All solid-state hydrogen ion-selective electrode based on a conducting poly(pyrrole) solid contact , 1994 .

[4]  A. Michalska,et al.  The influence of spontaneous charging/discharging of conducting polymer ion-to-electron transducer on potentiometric responses of all-solid-state calcium-selective electrodes , 2005 .

[5]  Ernö Pretsch,et al.  Solid-contact polymeric membrane electrodes with detection limits in the subnanomolar range , 2004 .

[6]  A. Michalska,et al.  Potentiometric selectivity of p-doped polymer films , 2000 .

[7]  A. Meir,et al.  Normal Pulse Voltammetry as Improved Quantitative Detection Mode for Amperometric Solvent Polymeric Membrane Ion Sensors , 2000 .

[8]  E. Bakker,et al.  Pulsed galvanostatic control of ionophore-based polymeric ion sensors. , 2003, Analytical chemistry.

[9]  R. E. Gyurcsányi,et al.  Picomolar detection limits with current-polarized Pb2+ ion-selective membranes. , 2001, Analytical chemistry.

[10]  R. E. Gyurcsányi,et al.  Tailored transport through ion-selective membranes for improved detection limits and selectivity coefficients , 1999 .

[11]  Ernö Pretsch,et al.  Lowering the Detection Limit of Solvent Polymeric Ion-Selective Membrane Electrodes. 2. Influence of Composition of Sample and Internal Electrolyte Solution , 1999 .

[12]  A. Michalska,et al.  Optimizing the analytical performance and construction of ion-selective electrodes with conducting polymer-based ion-to-electron transducers , 2005, Analytical and bioanalytical chemistry.

[13]  A. Michalska,et al.  All-plastic, disposable, low detection limit ion-selective electrodes , 2004 .

[14]  W. E. Morf,et al.  Current response of ion-selective solvent polymeric membranes at controlled potential , 2004 .

[15]  Dermot Diamond,et al.  All-solid-state sodium-selective electrode based on a calixarene ionophore in a poly(vinyl chloride) membrane with a polypyrrole solid contact , 1992 .

[16]  A. Michalska,et al.  Lowering the Detection Limit of Ion-Selective Plastic Membrane Electrodes with Conducting Polymer Solid Contact and Conducting Polymer Potentiometric Sensors , 2003 .

[17]  A. Michalska,et al.  All‐solid‐state chloride‐selective electrode with poly(pyrrole) solid contact , 1995 .

[18]  K. Maksymiuk,et al.  Studies on Spontaneous Charging/Discharging Processes of Polypyrrole in Aqueous Electrolyte Solutions , 2001 .

[19]  E. Pretsch,et al.  Large Improvement of the Lower Detection Limit of Ion-Selective Polymer Membrane Electrodes , 1997 .

[20]  W. E. Morf,et al.  Effects of controlled current on the response behavior of polymeric membrane ion-selective electrodes , 2002 .

[21]  Qin,et al.  Improved detection limits and unbiased selectivity coefficients obtained by using ion-exchange resins in the inner reference solution of ion-selective polymeric membrane electrodes , 2000, Analytical chemistry.

[22]  Ernö Pretsch,et al.  A polypyrrole-based solid-contact Pb2+-selective PVC-membrane electrode with a nanomolar detection limit , 2004, Analytical and bioanalytical chemistry.

[23]  H. Hill,et al.  Evaluating the separation of amphetamines by electrospray ionization ion mobility spectrometry/MS and charge competition within the ESI process. , 2002, Analytical chemistry.

[24]  A. Lewenstam,et al.  Calcium ion-selective electrodes under galvanostatic current control , 2005 .

[25]  J. Bobacka,et al.  Potential Stability of All-Solid-State Ion-Selective Electrodes Using Conducting Polymers as Ion-to-Electron Transducers. , 1999, Analytical chemistry.

[26]  E. Pretsch,et al.  Potentiometric Cd2+-selective electrode with a detection limit in the low ppt range , 2001 .

[27]  Andrzej Lewenstam,et al.  Factors affecting the potentiometric response of all-solid-state solvent polymeric membrane calcium-selective electrode for low-level measurements. , 2004, Analytical chemistry.

[28]  E. Bakker,et al.  Optical determination of ionophore diffusion coefficients in plasticized poly(vinyl chloride) sensing films , 2004 .

[29]  E. Bakker,et al.  Selectivity behavior and multianalyte detection capability of voltammetric ionophore-based plasticized polymeric membrane sensors. , 2001, Analytical chemistry.

[30]  A. Michalska Improvement of Analytical Characteristic of Calcium Selective Electrode with Conducting Polymer Contact. The Role of Conducting Polymer Spontaneous Charge Transfer Processes and Their Galvanostatic Compensation , 2005 .

[31]  A. Michalska,et al.  Highly Selective All-Plastic, Disposable, Cu2+-Selective Electrodes , 2005 .

[32]  E. Pretsch,et al.  Influence of key parameters on the lower detection limit and response function of solvent polymeric membrane ion-selective electrodes , 2001 .

[33]  Eric Bakker,et al.  Solid contact potentiometric sensors for trace level measurements. , 2006, Analytical chemistry.

[34]  P. C. Meier Two-parameter debye-hückel approximation for the evaluation of mean activity coefficients of 109 electrolytes , 1982 .

[35]  E. Hall,et al.  An experimental study of membrane materials and inner contacting layers for ion-selective K+ electrodes with a stable response and good dynamic range. , 2004, Analytical chemistry.

[36]  R. E. Gyurcsányi,et al.  Microfabricated ISEs: critical comparison of inherently conducting polymer and hydrogel based inner contacts. , 2004, Talanta.