Synthesis of radio frequency plasma polymerized non-synthetic Terpinen-4-ol thin films

Recent advancements in the area of organic polymer applications demand novel and advanced materials with desirable surface, optical and electrical properties to employ in emerging technologies. This study examines the fabrication and characterization of polymer thin films from non-synthetic Terpinen-4-ol monomer using radio frequency plasma polymerization. The optical properties, thickness and roughness of the thin films were studied in the wavelength range 200–1000 nm using ellipsometry. The polymer thin films of thickness from 100 nm to 1000 nm were fabricated and the films exhibited smooth and defect-free surfaces. At 500 nm wavelength, the refractive index and extinction coefficient were found to be 1.55 and 0.0007 respectively. The energy gap was estimated to be 2.67 eV, the value falling into the semiconducting Eg region. The obtained optical and surface properties of Terpinen-4-ol based films substantiate their candidacy as a promising low-cost material with potential applications in electronics, optics, and biomedical industries.

[1]  B. Ratner,et al.  Surface characterization of plasma deposited organic thin films , 1996 .

[2]  N. Mott,et al.  Conduction in non-crystalline systems V. Conductivity, optical absorption and photoconductivity in amorphous semiconductors , 1970 .

[3]  R. Ledzion,et al.  Electronic band structure of insulating hydrogenated carbon-germanium films , 1999 .

[4]  H. Biederman,et al.  Plasma polymer films and their future prospects , 2000 .

[5]  I. Karube,et al.  Plasma Polymerized Films for Sensor Devices , 2000 .

[6]  J. Sanetra,et al.  Ellipsometric studies of carbazole-containing polymer layers , 2007 .

[7]  H. Yasuda,et al.  Some aspects of plasma polymerization investigated by pulsed R.F. discharge , 1977 .

[8]  Donal D. C. Bradley,et al.  Exploring the potential of ellipsometry for the characterisation of electronic, optical, morphologic and thermodynamic properties of polyfluorene thin films , 2005 .

[9]  H. Yasuda,et al.  Creation of Polymerizable Species in Plasma Polymerization , 2004 .

[10]  S. Jayalekshmi,et al.  Conduction mechanism in plasma polymerized aniline thin films , 2003 .

[11]  B. Hong,et al.  High-rate deposition of plasma polymerized thin films using PECVD method and characterization of their optical properties , 2003 .

[12]  J. Tauc,et al.  Optical and Magnetic Investigations of the Localized States in Semiconducting Glasses , 1970 .

[13]  Mohan V. Jacob,et al.  Fabrication of a novel organic polymer thin film , 2008 .

[14]  G. Jellison,et al.  Parameterization of the optical functions of amorphous materials in the interband region , 1996 .

[15]  D. Avasthi,et al.  Estimation of optical band gap and carbon cluster sizes formed in heavy ion irradiated polycarbonate , 2005 .

[16]  Sorin Manolache,et al.  Macromolecular plasma-chemistry: an emerging field of polymer science , 2004 .

[17]  Hirotsugu Yasuda,et al.  Glow discharge polymerization , 1981 .

[18]  C. B. Lee,et al.  Preparation, characterization and electronic and optical properties of plasma-polymerized nitriles , 2005 .

[19]  L. Hanley,et al.  Deposition and Basic Properties of Thiophene Plasma Polymer Films , 2008 .

[20]  F. Shi Recent advances in polymer thin films prepared by plasma polymerization Synthesis, structural characterization, properties and applications , 1996 .

[21]  B. Hong,et al.  Electrical, mechanical, and optical properties of the organic–inorganic hybrid-polymer thin films deposited by PECVD , 2008 .

[22]  F. Gan,et al.  Optical parameters and absorption studies of azo dye-doped polymer thin films on silicon , 2000 .

[23]  H. Biederman,et al.  Plasma polymerization processes , 1992 .

[24]  M. Muccini A bright future for organic field-effect transistors , 2006, Nature materials.

[25]  R. Rochotzki,et al.  Optical properties of plasma polymer films (hexamethyldisiloxane) , 1993 .

[26]  U. Sajeev,et al.  On the optical and electrical properties of rf and a.c. plasma polymerized aniline thin films , 2006 .

[27]  Stephen R. Forrest,et al.  The path to ubiquitous and low-cost organic electronic appliances on plastic , 2004, Nature.

[28]  J. Boo,et al.  Physical and optical properties of plasma polymerized thin films deposited by PECVD method , 2003 .