Experimental observation of extremely weak optical scattering from an interlocking carbon nanotube array.

We experimentally demonstrate a nearly wavelength-independent optical reflection from an extremely rough carbon nanotube sample. The sample is made of a vertically aligned nanotube array, is a super dark material, and exhibits a near-perfect blackbody emission at T=450 K-600 K. No other material exhibits such optical properties, i.e., ultralow reflectance accompanied by a lack of wavelength scaling behavior. This observation is a result of the lowest ever measured reflectance (R=0.0003) of the sample over a broad infrared wavelength of 3 μm < λ < 13 μm. This discovery may be attributed to the unique interlocking surface of the nanotube array, consisting of both a global, large scale and a short-range randomness.

[1]  Satoshi Yasuda,et al.  A black body absorber from vertically aligned single-walled carbon nanotubes , 2009, Proceedings of the National Academy of Sciences.

[2]  Bernard Sapoval,et al.  Enhanced wave absorption through irregular interfaces , 2009 .

[3]  F. García-Vidal Metamaterials: Towards the dark side , 2008 .

[4]  Lijie Ci,et al.  Experimental observation of an extremely dark material made by a low-density nanotube array. , 2008, Nano letters.

[5]  C. Pan,et al.  Improved broadband and quasi-omnidirectional anti-reflection properties with biomimetic silicon nanostructures. , 2007, Nature nanotechnology.

[6]  Robert Vajtai,et al.  Ultrathick Freestanding Aligned Carbon Nanotube Films , 2007 .

[7]  Robert Vajtai,et al.  Vertically Aligned Large-Diameter Double-Walled Carbon Nanotube Arrays Having Ultralow Density , 2007 .

[8]  Steven R. Meier Comparisons of the optical, surface, and constituent properties of morphologically variant black materials , 2004, SPIE Optics + Photonics.

[9]  Application of diamond-like Carbon (DLC) coatings for gravitational wave detectors , 2004 .

[10]  Joachim Luther,et al.  An overview of the fifth conference on thermophotovoltaic generation of electricity , 2003 .

[11]  Martin J T Milton,et al.  The physical and chemical properties of electroless nickel–phosphorus alloys and low reflectance nickel–phosphorus black surfaces , 2002 .

[12]  L. Hanssen,et al.  Integrating-sphere system and method for absolute measurement of transmittance, reflectance, and absorptance of specular samples. , 2001, Applied optics.

[13]  Electronic response of aligned multishell carbon nanotubes , 2000, cond-mat/0011184.

[14]  M. J. Persky Review of black surfaces for space-borne infrared systems , 1999 .

[15]  J. Pendry,et al.  EFFECTIVE MEDIUM THEORY OF THE OPTICAL PROPERTIES OF ALIGNED CARBON NANOTUBES , 1997, cond-mat/9705110.

[16]  Eli Yablonovitch,et al.  Ultrahigh spontaneous emission quantum efficiency, 99.7% internally and 72% externally, from AlGaAs/GaAs/AlGaAs double heterostructures , 1993 .

[17]  Shunichi Kodama,et al.  Ultra-black nickel-phosphorus alloy optical absorber , 1989, 6th IEEE Conference Record., Instrumentation and Measurement Technology Conference.

[18]  L. G. Shirley,et al.  Diffuser radiation patterns over a large dynamic range. 1: Strong diffusers. , 1988, Applied optics.

[19]  H. Philipp,et al.  Optical Properties of Graphite , 1965 .

[20]  H. Queisser,et al.  Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells , 1961 .