X-ray photon correlation spectroscopy.

In recent years, X-ray photon correlation spectroscopy (XPCS) has emerged as one of the key probes of slow nanoscale fluctuations, applicable to a wide range of condensed matter and materials systems. This article briefly reviews the basic principles of XPCS as well as some of its recent applications, and discusses some novel approaches to XPCS analysis. It concludes with a discussion of the future impact of diffraction-limited storage rings on new types of XPCS experiments, pushing the temporal resolution to nanosecond and possibly even picosecond time scales.

[1]  M. Sutton,et al.  X-ray intensity fluctuation spectroscopy by heterodyne detection. , 2006, Journal of synchrotron radiation.

[2]  Andrew Schofield,et al.  Slow dynamics and aging in colloidal gels studied by x-ray photon correlation spectroscopy. , 2007, Physical review. E, Statistical, nonlinear, and soft matter physics.

[3]  Mark Sutton,et al.  Entanglement-controlled subdiffusion of nanoparticles within concentrated polymer solutions. , 2012, Physical review letters.

[4]  M. Sutton,et al.  Memory effect in composites of liquid crystal and silica aerosil. , 2011, Physical review. E, Statistical, nonlinear, and soft matter physics.

[5]  G. Grübel,et al.  Dynamics in dense suspensions of charge-stabilized colloidal particles , 2008, The European physical journal. E, Soft matter.

[6]  T. M. Rice,et al.  Electric field depinning of charge density waves , 1979 .

[7]  L Berthier,et al.  Heterogeneous dynamics of coarsening systems. , 2004, Physical review letters.

[8]  M D Ediger,et al.  Spatially heterogeneous dynamics in supercooled liquids. , 2003, Annual review of physical chemistry.

[9]  Christian Gutt,et al.  System-level simulation of a X-ray imager with nonlinear gain and per-pixel digitizer: XPCS case study , 2010 .

[10]  S. Narayanan,et al.  Surface Layer Dynamics in Miscible Polymer Blends. , 2013, ACS macro letters.

[11]  C. Gutt,et al.  Capillary waves at the transition from propagating to overdamped behavior. , 2004, Physical review letters.

[12]  Takeshi Kawasaki,et al.  Correlation between dynamic heterogeneity and medium-range order in two-dimensional glass-forming liquids. , 2007, Physical review letters.

[13]  Mark Sutton,et al.  Using coherence to measure two-time correlation functions. , 2003, Optics express.

[14]  D J Durian,et al.  Speckle visibility spectroscopy and variable granular fluidization. , 2003, Physical review letters.

[15]  D A Weitz,et al.  Universal aging features in the restructuring of fractal colloidal gels. , 2000, Physical review letters.

[16]  Christian Gutt,et al.  XPCS at the European X-ray free electron laser facility , 2007 .

[17]  H. Fukuyama,et al.  Dynamics of the charge-density wave. I. Impurity pinning in a single chain , 1978 .

[18]  P. Littlewood,et al.  Sliding charge-density wave in manganites. , 2007, Nature materials.

[19]  C. Gutt,et al.  Partially wetting thin liquid films: structure and dynamics studied with coherent x rays. , 2007, Physical review letters.

[20]  Short-?and long-range correlated motion observed in colloidal glasses and liquids , 2006, cond-mat/0610195.

[21]  O. Shpyrko,et al.  Collective pinning dynamics of charge-density waves in 1T-TaS2 , 2012 .

[22]  S. Mochrie,et al.  Dynamics of colloidal particles in ice. , 2010, The Journal of chemical physics.

[23]  Mark Sutton,et al.  X-ray intensity fluctuation spectroscopy studies on phase-ordering systems. , 2005, Physical review letters.

[24]  O. Shpyrko,et al.  Capillary wave dynamics of thin polymer films over submerged nanostructures. , 2012, Physical review letters.

[25]  Amish J. Patel,et al.  Dynamic Signatures of Microphase Separation in a Block Copolymer Melt Determined by X-ray Photon Correlation Spectroscopy and Rheology , 2010 .

[26]  A. Menzel,et al.  Fast two-dimensional detection for X-ray photon correlation spectroscopy using the PILATUS detector. , 2009, Journal of synchrotron radiation.

[27]  S. Narayanan,et al.  Polymer Film Surface Fluctuation Dynamics in the Limit of Very Dense Branching , 2013 .

[28]  M. Borland Progress Toward an Ultimate Storage Ring Light Source , 2013 .

[29]  Dynamical heterogeneity close to the jamming transition in a sheared granular material. , 2005, Physical review letters.

[30]  R. Thorne Charge‐Density‐Wave Conductors , 1996 .

[31]  Evolution of particle-scale dynamics in an aging clay suspension. , 2004, Physical review letters.

[32]  A. Yodh,et al.  Cooperative rearrangement regions and dynamical heterogeneities in colloidal glasses with attractive versus repulsive interactions. , 2011, Physical review letters.

[33]  S. Mochrie,et al.  Optimizing the signal-to-noise ratio for X-ray photon correlation spectroscopy. , 2006, Journal of synchrotron radiation.

[34]  Luca Cipelletti,et al.  Slow dynamics in glasses, gels and foams , 2002 .

[35]  G. Stephenson,et al.  Time-delayed beam splitting with energy separation of x-ray channels , 2013, 1307.1462.

[36]  G. Grübel,et al.  X-ray photon correlation spectroscopy using the Mythen 1D detector , 2013 .

[37]  C. Zukoski,et al.  Microscopic dynamics of recovery in sheared depletion gels. , 2006, Physical review letters.

[38]  Zhang Jiang,et al.  Evidence for viscoelastic effects in surface capillary waves of molten polymer films. , 2007, Physical review letters.

[39]  C. Gutt,et al.  Dynamics at the liquid-vapor interface of a supercooled organic glass former. , 2010, Physical review letters.

[40]  G. Grübel,et al.  Dynamics and correlations in magnetic colloidal systems studied by X-ray photon correlation spectroscopy , 2001 .

[41]  L. Cipelletti,et al.  Unexpected drop of dynamical heterogeneities in colloidal suspensions approaching the jamming transition , 2008, 0807.0281.

[42]  A. Maignan,et al.  Correlation between phase diagrams and spontaneous magnetization jumps in narrow-band manganites , 2007 .

[43]  FLUCTUATIONS AND NOISE IN TIME-RESOLVED LIGHT SCATTERING EXPERIMENTS: MEASURING TEMPORALLY HETEROGENEOUS DYNAMICS , 2005 .

[44]  K. Ludwig,et al.  Direct measurement of microstructural avalanches during the martensitic transition of cobalt using coherent x-ray scattering. , 2011, Physical review letters.

[45]  C. Gutt,et al.  Slow aging dynamics and avalanches in a gold-cadmium alloy investigated by x-ray photon correlation spectroscopy. , 2011, Physical review letters.

[46]  R. Thorne,et al.  TEMPORALLY ORDERED COLLECTIVE CREEP AND DYNAMIC TRANSITION IN THE CHARGE-DENSITY-WAVE CONDUCTOR NBSE3 , 1999, cond-mat/9907106.

[47]  Michael Borland,et al.  Ultimate storage ring based on fourth-order geometric achromats , 2012 .

[48]  Luca Cipelletti,et al.  Slow dynamics in glassy soft matter , 2005 .

[49]  D. Rana,et al.  Magnetic avalanchelike behavior in the disordered manganite (Eu 0.4 La 0.1 )(Sr 0.4 Ca 0.1 )MnO 3 , 2006, cond-mat/0608114.

[50]  L. Stadler,et al.  Time-resolved study of the crystallization dynamics in a metallic glass , 2012 .

[51]  E. D. Isaacs,et al.  Direct measurement of antiferromagnetic domain fluctuations , 2007, Nature.

[52]  G. Grüner,et al.  The dynamics of charge-density waves , 1988 .

[53]  M. Sutton,et al.  X-ray coherent scattering in metal physics , 2012 .

[54]  Robert L. Leheny,et al.  XPCS: Nanoscale motion and rheology , 2012 .

[55]  Meier,et al.  Photon Correlation Spectroscopy of Colloidal Palladium Using a Coherent X-Ray Beam. , 1996, Physical review letters.

[56]  L. Berthier,et al.  Direct Experimental Evidence of a Growing Length Scale Accompanying the Glass Transition , 2005, Science.

[57]  D. Kuberkar,et al.  Field-induced abrupt change in magnetization of the manganite compounds(LaR)0.45(CaSr)0.55MnO3(R=Euand Tb) , 2006 .

[58]  A. Nogales,et al.  Slow dynamics of nanocomposite polymer aerogels as revealed by X-ray photocorrelation spectroscopy (XPCS). , 2014, The Journal of chemical physics.

[59]  G. Grüner,et al.  Onset of charge-density-wave conduction: Switching and hysteresis in Nb Se 3 , 1982 .

[60]  J. Rouxel Crystal Chemistry and Properties of Materials with Quasi-One-Dimensional Structures , 1986 .

[61]  Agnes Duri,et al.  Length scale dependence of dynamical heterogeneity in a colloidal fractal gel , 2006, cond-mat/0606051.

[62]  G. Grübel,et al.  Viscosity of a liquid crystal near the nematic-smectic A phase transition. , 2003, Physical review letters.

[63]  M. Hervieu,et al.  Avalanche like field dependent magnetization of Mn-site doped charge-ordered manganites , 2002 .

[64]  Laurence Lurio,et al.  Area detector based photon correlation in the regime of short data batches: Data reduction for dynamic x-ray scattering , 2000 .

[65]  I. Dolbnya,et al.  Surface and bulk elasticity determined fluctuation regimes in smectic membranes. , 2003, Physical review letters.

[66]  A. Takahara,et al.  X-ray photon correlation spectroscopy using a fast pixel array detector with a grid mask resolution enhancer , 2012, Journal of synchrotron radiation.

[67]  Zaitsev-Zotov Classical-to-quantum crossover in charge-density wave creep at low temperatures. , 1993, Physical review letters.

[68]  R. Pecora,et al.  Soft-matter characterization , 2008 .

[69]  Pulse-duration memory effect and deformable charge-density waves. , 1987, Physical review. B, Condensed matter.

[70]  Hugo Bissig,et al.  Time-resolved correlation: a new tool for studying temporally heterogeneous dynamics , 2003 .

[71]  H. Graafsma,et al.  Advantages of a logarithmic sampling scheme for XPCS experiments at the European XFEL using the AGIPD detector , 2012 .

[72]  Michael Leitner,et al.  Atomic diffusion studied with coherent X-rays. , 2009, Nature materials.

[73]  S. Manley,et al.  Universal non-diffusive slow dynamics in aging soft matter. , 2003, Faraday discussions.

[74]  Fleming,et al.  X-Ray photon correlation spectroscopy study of Brownian motion of gold colloids in glycerol. , 1995, Physical review letters.

[75]  D. Durian,et al.  Speckle-visibility spectroscopy: A tool to study time-varying dynamics , 2005, cond-mat/0506081.

[76]  Y. Amemiya,et al.  Indirectly illuminated X-ray area detector for X-ray photon correlation spectroscopy. , 2010, Journal of synchrotron radiation.

[77]  P. Monceau Electronic properties of inorganic quasi-one-dimensional compounds , 1985 .

[78]  M. Sutton,et al.  Materials science and X-ray techniques , 2008 .

[79]  M A Borthwick,et al.  Fluctuation dynamics of block copolymer vesicles. , 2005, Physical review letters.

[80]  Schofield,et al.  Three-dimensional direct imaging of structural relaxation near the colloidal glass transition , 2000, Science.

[81]  Mark Sutton,et al.  Nanoparticle motion within glassy polymer melts. , 2009, Physical review letters.

[82]  Gerhard Grübel,et al.  Dynamics of Block Copolymer Micelles Revealed by X-Ray Intensity Fluctuation Spectroscopy , 1997 .

[83]  L Cipelletti,et al.  Investigation of q-dependent dynamical heterogeneity in a colloidal gel by x-ray photon correlation spectroscopy. , 2007, Physical review. E, Statistical, nonlinear, and soft matter physics.

[84]  S. Mochrie,et al.  Crossover from stretched to compressed exponential relaxations in a polymer-based sponge phase. , 2006, Physical review letters.

[85]  Equilibrium and out-of-equilibrium dynamics in a molecular layer of azopolymer floating on water studied by Interfacial Shear Rheology , 2010, 1005.3156.

[86]  Edward Roy Pike,et al.  Photon correlation and light beating spectroscopy , 1974 .

[87]  Kazuto Yamauchi,et al.  A Bragg beam splitter for hard x-ray free-electron lasers. , 2013, Optics express.

[88]  Suresh Narayanan,et al.  Particle dynamics in polymer-metal nanocomposite thin films on nanometer-length scales. , 2007, Physical review letters.

[89]  Sharon C. Glotzer,et al.  Measurement of growing dynamical length scales and prediction of the jamming transition in a granular material , 2007, 1012.4830.

[90]  I. Dolbnya,et al.  Smectic membranes in motion: approaching the fast limits of x-ray photon correlation spectroscopy. , 2002, Physical review letters.

[91]  Hugo Bissig,et al.  Time-resolved-correlation measurements of temporally heterogeneous dynamics. , 2005, Physical review. E, Statistical, nonlinear, and soft matter physics.

[92]  M. Stone,et al.  Field-induced avalanche to the ferromagnetic state in the phase-separated ground state of manganites , 2004, cond-mat/0404183.

[93]  Laurence Lurio,et al.  COHERENT X-RAY STUDY OF FLUCTUATIONS DURING DOMAIN COARSENING , 1998 .

[94]  A. Heuer,et al.  Cage Effect, Local Anisotropies, and Dynamic Heterogeneities at the Glass Transition: A Computer Study of Hard Spheres , 1998 .

[95]  R. Pecora Dynamic Light Scattering , 1985 .

[96]  S. Sinha,et al.  Jamming behavior of domains in a spiral antiferromagnetic system. , 2013, Physical review letters.

[97]  Marcin Sikorski,et al.  Real-time compression of streaming X-ray photon correlation spectroscopy area-detector data , 2011 .

[98]  R. Pecora,et al.  Dynamic Light Scattering: Applications of Photon Correlation Spectroscopy , 2011 .

[99]  Horst Schulte-Schrepping,et al.  Performance of a picosecond x-ray delay line unit at 8.39 keV. , 2009, Optics letters.

[100]  Little Pb Sliding charge-density waves: A numerical study. , 1986 .

[101]  Y. Chushkin,et al.  Compressed correlation functions and fast aging dynamics in metallic glasses. , 2013, The Journal of chemical physics.

[102]  M. Wulff,et al.  A sub-picosecond accumulating streak camera for x-rays , 2001 .

[103]  S. Glotzer Spatially heterogeneous dynamics in liquids: insights from simulation , 2000 .

[104]  Slow, nondiffusive dynamics in concentrated nanoemulsions. , 2007, Physical review. E, Statistical, nonlinear, and soft matter physics.

[105]  Mark Sutton,et al.  A review of X-ray intensity fluctuation spectroscopy , 2008 .

[106]  A. Mozzanica,et al.  Capturing dynamics with Eiger, a fast-framing X-ray detector , 2012, Journal of synchrotron radiation.

[107]  S K Sinha,et al.  Surface dynamics of polymer films. , 2003, Physical review letters.

[108]  E. Schierle,et al.  Magnetic domain fluctuations in an antiferromagnetic film observed with coherent resonant soft x-ray scattering. , 2007, Physical review letters.

[109]  L. Stadler,et al.  Two-dimensional heterogeneous dynamics at the surface of a colloidal suspension. , 2009, Physical review letters.

[110]  Y Gao,et al.  Direct imaging of dynamical heterogeneities near the colloid-gel transition. , 2007, Physical review letters.

[111]  M. Holt,et al.  Dynamic fluctuations and static speckle in critical X-ray scattering from SrTiO3. , 2007, Physical review letters.

[112]  Ivan K Schuller,et al.  Multiple avalanches across the metal-insulator transition of vanadium oxide nanoscaled junctions. , 2008, Physical review letters.

[113]  Brauer,et al.  X-ray intensity fluctuation spectroscopy observations of critical dynamics in Fe3Al. , 1995, Physical review letters.

[114]  Paul H. Fuoss,et al.  Hard x-ray delay line for x-ray photon correlation spectroscopy and jitter-free pump-probe experiments at LCLS , 2012, Other Conferences.

[115]  David Robin,et al.  The Potential of an Ultimate Storage Ring for Future Light Sources , 2010 .

[116]  Horst Schulte-Schrepping,et al.  Development of a hard X-ray delay line for X-ray photon correlation spectroscopy and jitter-free pump–probe experiments at X-ray free-electron laser sources , 2011, Journal of synchrotron radiation.

[117]  L Cipelletti,et al.  Atomic-scale relaxation dynamics and aging in a metallic glass probed by x-ray photon correlation spectroscopy. , 2012, Physical review letters.

[118]  Frédéric Livet,et al.  Diffraction with a coherent X-ray beam: dynamics and imaging , 2007, Acta Crystallographica Section A: Foundations of Crystallography.