Fouling control of a membrane coupled photocatalytic process treating greywater.

Fouling in membrane coupled photocatalytic reactors was investigated in the case of greywater treatment by establishing the link between product type, dose, irradiation time and fouling rates in a cross flow membrane cell fitted with a 0.4 microm pore sized polyethylene membrane. Rapid fouling occurred only with shower gels and conditioners and was linked to changes in the organo-TiO(2) aggregate size postulated to be caused by polymers within the products. Fouling was reduced to a negligible level when sufficient irradiation was applied demonstrating that the membrane component of the process is not the issue and that scale up and implementation of the process relates to effective design of the UV reactor.

[1]  P Jeffrey,et al.  Membrane chemical reactor (MCR) combining photocatalysis and microfiltration for grey water treatment. , 2006, Water science and technology : a journal of the International Association on Water Pollution Research.

[2]  C. Dong,et al.  Advanced chemical oxidation: Its present role and potential future in hazardous waste treatment , 1993 .

[3]  B Jefferson,et al.  A review of floc strength and breakage. , 2005, Water research.

[4]  D. Wolbert,et al.  Photocatalytic degradation of pesticides in pure water and a commercial agricultural solution on TiO2 coated media. , 2008, Chemosphere.

[5]  I. Moon,et al.  A total solution for simultaneous organic degradation and particle separation using photocatalytic oxidation and submerged microfiltration membrane hybrid process , 2005 .

[6]  K. Rajeshwar,et al.  An integrated flow reactor-membrane filtration system for heterogeneous photocatalysis. Part II: Experiments on the ultrafiltration unit and combined operation , 1999 .

[7]  Sylwia Mozia,et al.  Photocatalytic membrane reactor (PMR) coupling photocatalysis and membrane distillation—Effectiveness of removal of three azo dyes from water , 2007 .

[8]  Enrico Drioli,et al.  Hybrid processes coupling photocatalysis and membranes for degradation of organic pollutants in water , 2002 .

[9]  Simon Judd,et al.  Sub-critical flux fouling in membrane bioreactors : a review of recent literature , 2005 .

[10]  LIGHT INTENSITY DISTRIBUTION IN PHOTOCATALYTIC REACTORS USING A FINITE VOLUME METHOD , 2003 .

[11]  Z. Wang,et al.  A new submerged membrane photocatalysis reactor (SMPR) for fulvic acid removal using a nano-structured photocatalyst. , 2006, Journal of hazardous materials.

[12]  K. Choo,et al.  Use of an integrated photocatalysis/hollow fiber microfiltration system for the removal of trichloroethylene in water. , 2008, Journal of hazardous materials.

[13]  B. Jefferson,et al.  A comparison of submerged and sidestream tubular membrane bioreactor configurations , 2005 .

[14]  K. Wintermantel PROCESS AND PRODUCT ENGINEERING ACHIEVEMENTS, PRESENT AND FUTURE CHALLENGES , 1999 .

[15]  Simon Judd,et al.  Technologies for domestic wastewater recycling , 2000 .

[16]  Bruce Jefferson,et al.  Reuse Of Urban Water: Impact Of Product Choice , 2008 .

[17]  K. Wintermantel,et al.  Process and Product Engineering: Achievements, Present and Future Challenges , 1999 .

[18]  Bruce Jefferson,et al.  How the natural organic matter to coagulant ratio impacts on floc structural properties. , 2005, Environmental science & technology.

[19]  Bruce Jefferson,et al.  Greywater recycling: treatment options and applications , 2007 .

[20]  Bruce Jefferson,et al.  Technologies for urban water recycling , 2008 .

[21]  J. Tay,et al.  Removal of humic acid foulant from ultrafiltration membrane surface using photocatalytic oxidation process. , 2005, Water science and technology : a journal of the International Association on Water Pollution Research.

[22]  P. Hlavínek,et al.  Dangerous Pollutants (Xenobiotics) in Urban Water Cycle , 2008 .

[23]  Anita Rachel,et al.  Comparison of photocatalytic efficiencies of TiO2 in suspended and immobilised form for the photocatalytic degradation of nitrobenzenesulfonic acids , 2002 .

[24]  Xiangyang Shi,et al.  Tunable synthesis and immobilization of zero-valent iron nanoparticles for environmental applications. , 2008, Environmental science & technology.

[25]  W. Gernjak,et al.  Solar photocatalytic degradation of some hazardous water-soluble pesticides at pilot-plant scale. , 2006, Journal of hazardous materials.

[26]  Simon Judd,et al.  Critical flux determination by the flux-step method in a submerged membrane bioreactor , 2003 .

[27]  D. Ollis Integrating Photocatalysis and Membrane Technologies for Water Treatment , 2003, Annals of the New York Academy of Sciences.

[28]  S. Vigneswaran,et al.  A combined photocatalytic slurry reactor–immersed membrane module system for advanced wastewater treatment , 2008 .

[29]  Ho-In Lee,et al.  Use of Ultrafiltration Membranes for the Separation of TiO2 Photocatalysts in Drinking Water Treatment , 2001 .

[30]  A. Fane,et al.  Factors affecting the performance of a low-pressure submerged membrane photocatalytic reactor , 2007 .

[31]  B. Jefferson,et al.  Polymers as bubble surface modifiers in the flotation of algae , 2010, Environmental technology.

[32]  B Jefferson,et al.  Methods for understanding organic fouling in MBRs. , 2004, Water science and technology : a journal of the International Association on Water Pollution Research.