Highly stretchable integrated system for micro-supercapacitor with AC line filtering and UV detector

Abstract In-plane micro-supercapacitors (MSCs) possess higher volumetric energy density and are thus more compact compared with traditional aluminum electrolytic capacitors (AECs). As a result, developing in-plane MSCs with AC line filtering function is desired to replace the AECs and integrate with other electronic devices. Here, highly stretchable integrated system for in-plane MSCs with AC line filtering and UV detector were fabricated by designing buckled micro-electrodes based on SWCNT film and TiO2 NPs. Although gel electrolyte was used in these MSCs, they still show an ultrafast frequency response with a phase angle of -75.2° because of their unique structure. Such MSCs thus can function as the AC line filtering devices. Furthermore, their AC line filtering behavior remains almost unchanged even stretched up to 200%. Further coating TiO2 NPs on the buckled SWCNT micro-electrodes is able to endow the MSCs with another ability of UV photodetection with the sensitivity of 6.2. Importantly, such integrated device can still show stable photocurrent response and capacitance behaviors at different stretching times and even repeated stretching 100 times. The rational design of such stretchable integrated system for MSCs with AC line filtering and UV photodetector will pave the way for the applications in assembling supercapacitors and other electronics into highly stretchable integrated devices.

[1]  G. Shi,et al.  An ultrahigh-rate electrochemical capacitor based on solution-processed highly conductive PEDOT:PSS films for AC line-filtering , 2016 .

[2]  Changsheng Xie,et al.  A novel planar integration of all-solid-state capacitor and photodetector by an ultra-thin transparent sulfated TiO2 film , 2014 .

[3]  Klaus Müllen,et al.  Ultrathin Printable Graphene Supercapacitors with AC Line‐Filtering Performance , 2015, Advanced materials.

[4]  M. El‐Kady,et al.  Scalable fabrication of high-power graphene micro-supercapacitors for flexible and on-chip energy storage , 2013, Nature Communications.

[5]  Yiqing Sun,et al.  Ultrahigh-rate supercapacitors based on eletrochemically reduced graphene oxide for ac line-filtering , 2012, Scientific Reports.

[6]  Xingbin Yan,et al.  Superior Micro‐Supercapacitors Based on Graphene Quantum Dots , 2013 .

[7]  Xiaodong Zhuang,et al.  Silicon-Compatible Carbon-Based Micro-Supercapacitors. , 2016, Angewandte Chemie.

[8]  Boris Murmann,et al.  Highly stretchable polymer semiconductor films through the nanoconfinement effect , 2017, Science.

[9]  Akira Watanabe,et al.  Laser direct writing of high-performance flexible all-solid-state carbon micro-supercapacitors for an on-chip self-powered photodetection system , 2016 .

[10]  Husam N. Alshareef,et al.  Conducting polymer micro-supercapacitors for flexible energy storage and Ac line-filtering , 2015 .

[11]  Seung Hwan Ko,et al.  A Hyper‐Stretchable Elastic‐Composite Energy Harvester , 2015, Advanced materials.

[12]  Jeong Sook Ha,et al.  Fabrication of high performance flexible micro-supercapacitor arrays with hybrid electrodes of MWNT/V2O5 nanowires integrated with a SnO2 nanowire UV sensor. , 2014, Nanoscale.

[13]  Derrek E. Lobo,et al.  Miniaturized Supercapacitors: Focused Ion Beam Reduced Graphene Oxide Supercapacitors with Enhanced Performance Metrics , 2015 .

[14]  Yongyao Xia,et al.  Electrochemical capacitors: mechanism, materials, systems, characterization and applications. , 2016, Chemical Society reviews.

[15]  Jiho Lee,et al.  Stretchable carbon nanotube/ion-gel supercapacitors with high durability realized through interfacial microroughness. , 2014, ACS applied materials & interfaces.

[16]  Huisheng Peng,et al.  High-performance transparent and stretchable all-solid supercapacitors based on highly aligned carbon nanotube sheets , 2014, Scientific Reports.

[17]  Majid Beidaghi,et al.  Capacitive energy storage in micro-scale devices: recent advances in design and fabrication of micro-supercapacitors , 2014 .

[18]  T. Kallio,et al.  Stretchable and transparent supercapacitors based on aerosol synthesized single-walled carbon nanotube films , 2016 .

[19]  L. Nazar,et al.  Carbon Nanotube-Based Supercapacitors with Excellent ac Line Filtering and Rate Capability via Improved Interfacial Impedance. , 2015, ACS nano.

[20]  D. Pech,et al.  Microsupercapacitors as miniaturized energy-storage components for on-chip electronics. , 2017, Nature nanotechnology.

[21]  Peihua Huang,et al.  On-chip and freestanding elastic carbon films for micro-supercapacitors , 2016, Science.

[22]  Kyriakos Komvopoulos,et al.  Highly Stretchable Microsupercapacitor Arrays with Honeycomb Structures for Integrated Wearable Electronic Systems. , 2016, ACS nano.

[23]  Xin Li,et al.  Dynamic and galvanic stability of stretchable supercapacitors. , 2012, Nano letters.

[24]  Jing Xu,et al.  A flexible integrated photodetector system driven by on-chip microsupercapacitors , 2015 .

[25]  Norbert Fabre,et al.  Elaboration of a microstructured inkjet-printed carbon electrochemical capacitor , 2010 .

[26]  M. Bonn,et al.  Coordination Polymer Framework Based On-Chip Micro-Supercapacitors with AC Line-Filtering Performance. , 2017, Angewandte Chemie.

[27]  Jeong Sook Ha,et al.  Fabrication of flexible micro-supercapacitor array with patterned graphene foam/MWNT-COOH/MnOx electrodes and its application , 2015 .

[28]  Bin Liu,et al.  Fiber-based flexible all-solid-state asymmetric supercapacitors for integrated photodetecting system. , 2014, Angewandte Chemie.

[29]  Teng Zhai,et al.  H‐TiO2@MnO2//H‐TiO2@C Core–Shell Nanowires for High Performance and Flexible Asymmetric Supercapacitors , 2013, Advanced materials.

[30]  Ray H. Baughman,et al.  Stretchable, Weavable Coiled Carbon Nanotube/MnO2/Polymer Fiber Solid-State Supercapacitors , 2015, Scientific Reports.

[31]  Andrea Lamberti,et al.  A Highly Stretchable Supercapacitor Using Laser‐Induced Graphene Electrodes onto Elastomeric Substrate , 2016 .

[32]  Zhiqiang Niu,et al.  Unconventional supercapacitors from nanocarbon-based electrode materials to device configurations. , 2016, Chemical Society reviews.

[33]  Jun Chen,et al.  Compact-designed supercapacitors using free-standing single-walled carbon nanotube films , 2011 .

[34]  Hai-Long Jiang,et al.  A Stretchable Electronic Fabric Artificial Skin with Pressure‐, Lateral Strain‐, and Flexion‐Sensitive Properties , 2016, Advanced materials.

[35]  Zhiqiang Niu,et al.  Foldable All‐Solid‐State Supercapacitors Integrated with Photodetectors , 2017 .

[36]  Teng Zhai,et al.  TiO2@C core–shell nanowires for high-performance and flexible solid-state supercapacitors , 2013 .

[37]  Zhiqiang Niu,et al.  Programmable Nanocarbon‐Based Architectures for Flexible Supercapacitors , 2015 .

[38]  Kang Zhang,et al.  Bi-functional electrode for UV detector and supercapacitor , 2015 .

[39]  Yonggang Huang,et al.  Materials and Mechanics for Stretchable Electronics , 2010, Science.

[40]  M. Beidaghi,et al.  Micro‐Supercapacitors Based on Interdigital Electrodes of Reduced Graphene Oxide and Carbon Nanotube Composites with Ultrahigh Power Handling Performance , 2012 .

[41]  Wenwen Liu,et al.  High-performance microsupercapacitors based on two-dimensional graphene/manganese dioxide/silver nanowire ternary hybrid film. , 2015, ACS nano.

[42]  Zheng Yan,et al.  3-Dimensional graphene carbon nanotube carpet-based microsupercapacitors with high electrochemical performance. , 2013, Nano letters.

[43]  Xiaodong Chen,et al.  Highly Stretchable, Integrated Supercapacitors Based on Single‐Walled Carbon Nanotube Films with Continuous Reticulate Architecture , 2013, Advanced materials.

[44]  Shuang Li,et al.  Alternating Stacked Graphene‐Conducting Polymer Compact Films with Ultrahigh Areal and Volumetric Capacitances for High‐Energy Micro‐Supercapacitors , 2015, Advanced materials.

[45]  Gunchul Shin,et al.  Fabrication of a stretchable solid-state micro-supercapacitor array. , 2013, ACS nano.

[46]  X. Bao,et al.  Bottom-Up Fabrication of Sulfur-Doped Graphene Films Derived from Sulfur-Annulated Nanographene for Ultrahigh Volumetric Capacitance Micro-Supercapacitors. , 2017, Journal of the American Chemical Society.

[47]  Nae-Eung Lee,et al.  Recent Progress on Stretchable Electronic Devices with Intrinsically Stretchable Components , 2017, Advanced materials.

[48]  P. Irazoqui,et al.  Ultrasmall Integrated 3D Micro‐Supercapacitors Solve Energy Storage for Miniature Devices , 2014 .

[49]  John R. Miller,et al.  Electric double layer capacitors for ac filtering made from vertically oriented graphene nanosheets on aluminum , 2017 .

[50]  R. Outlaw,et al.  Fast Response, vertically oriented graphene nanosheet electric double layer capacitors synthesized from C(2)H(2). , 2014, ACS nano.

[51]  G. Gary Wang,et al.  Flexible solid-state supercapacitors: design, fabrication and applications , 2014 .

[52]  Gordon G Wallace,et al.  Intrinsically stretchable supercapacitors composed of polypyrrole electrodes and highly stretchable gel electrolyte. , 2013, ACS applied materials & interfaces.

[53]  Yongyao Xia,et al.  Recent Progress in Supercapacitors: From Materials Design to System Construction , 2013, Advanced materials.

[54]  Cunjiang Yu,et al.  Stretchable Supercapacitors Based on Buckled Single‐Walled Carbon‐Nanotube Macrofilms , 2009, Advanced materials.

[55]  B. Jang,et al.  Graphene-based supercapacitor with an ultrahigh energy density. , 2010, Nano letters.

[56]  Jeong Woo Han,et al.  Omnidirectionally stretchable, high performance supercapacitors based on a graphene–carbon-nanotube layered structure , 2015 .

[57]  Qiu Jiang,et al.  Micro-Pseudocapacitors with Electroactive Polymer Electrodes: Toward AC-Line Filtering Applications. , 2016, ACS applied materials & interfaces.

[58]  Haibo Zeng,et al.  Self-powered fiber-shaped wearable omnidirectional photodetectors , 2016 .

[59]  Yang Li,et al.  Breathable and Wearable Energy Storage Based on Highly Flexible Paper Electrodes , 2016, Advanced materials.

[60]  Bin Wang,et al.  Fiber-shaped solid-state supercapacitors based on molybdenum disulfide nanosheets for a self-powered photodetecting system , 2016 .

[61]  Xiaodong Chen,et al.  A “skeleton/skin” strategy for preparing ultrathin free-standing single-walled carbon nanotube/polyaniline films for high performance supercapacitor electrodes , 2012 .

[62]  Klaus Müllen,et al.  Graphene-based in-plane micro-supercapacitors with high power and energy densities , 2013, Nature Communications.

[63]  Tricia Breen Carmichael,et al.  Stretchable Light‐Emitting Electrochemical Cells Using an Elastomeric Emissive Material , 2012, Advanced materials.

[64]  Yongan Huang,et al.  Energy Harvesters for Wearable and Stretchable Electronics: From Flexibility to Stretchability , 2016, Advanced materials.

[65]  John R. Miller,et al.  Graphene Double-Layer Capacitor with ac Line-Filtering Performance , 2010, Science.

[66]  Peihua Huang,et al.  Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon. , 2010, Nature nanotechnology.

[67]  Goangseup Zi,et al.  Stretchable patterned graphene gas sensor driven by integrated micro-supercapacitor array , 2016 .

[68]  Oliver G. Schmidt,et al.  Stimulus‐Responsive Micro‐Supercapacitors with Ultrahigh Energy Density and Reversible Electrochromic Window , 2017, Advanced materials.

[69]  Sanggeun Jeon,et al.  Body‐Attachable and Stretchable Multisensors Integrated with Wirelessly Rechargeable Energy Storage Devices , 2016, Advanced materials.

[70]  Hui-Ming Cheng,et al.  Recent advances in graphene-based planar micro-supercapacitors for on-chip energy storage , 2014 .

[71]  P. Ajayan,et al.  Ultrathin planar graphene supercapacitors. , 2011, Nano letters.

[72]  S. W. Kim,et al.  2.5 V compact supercapacitors based on ultrathin carbon nanotube films for AC line filtering , 2015 .