A Review on Microcellular Injection Moulding

Microcellular injection moulding (MuCell®) is a polymer processing technology that uses a supercritical fluid inert gas, CO2 or N2, to produce light-weight products. Due to environmental pressures and the requirement of light-weight parts with good mechanical properties, this technology recently gained significant attention. However, poor surface appearance and limited mechanical properties still prevent the wide applications of this technique. This paper reviews the microcellular injection moulding process, main characteristics of the process, bubble nucleation and growth, and major recent developments in the field. Strategies to improve both the surface quality and mechanical properties are discussed in detail as well as the relationships between processing parameters, morphology, and surface and mechanical properties. Modelling approaches to simulate microcellular injection moulding and the mathematical models behind Moldex 3D and Moldflow, the two most commonly used software tools by industry and academia, are reviewed, and the main limitations are highlighted. Finally, future research perspectives to further develop this technology are also discussed.

[1]  S. Chen,et al.  Using P(Pressure)-T(Temperature) Path to Control the Foaming Cell Sizes in Microcellular Injection Molding Process , 2021, Polymers.

[2]  D. Sykutera,et al.  The Microcellular Structure of Injection Molded Thick-Walled Parts as Observed by In-Line Monitoring , 2020, Materials.

[3]  P. Bártolo,et al.  A Study of Physico-Mechanical Properties of Hollow Glass Bubble, Jute Fibre and Rubber Powder Reinforced Polypropylene Compounds with and without MuCell® Technology for Lightweight Applications , 2020, Polymers.

[4]  S. Ray,et al.  Foamability and Special Applications of Microcellular Thermoplastic Polymers: A Review on Recent Advances and Future Direction , 2020, Macromolecular Materials and Engineering.

[5]  Mohammad Reza Khosravani,et al.  Injection molding manufacturing process: review of case-based reasoning applications , 2020, J. Intell. Manuf..

[6]  Hua-jie Mao,et al.  Investigation on Foamed PP/Nano-CaCO3 Composites in a Combined in-Mold Decoration and Microcellular Injection Molding Process , 2020, Polymers.

[7]  C. Griffiths,et al.  A Novel Hybrid Foaming Method for Low-Pressure Microcellular Foam Production of Unfilled and Talc-Filled Copolymer Polypropylenes , 2019, Polymers.

[8]  Jianzhong Fu,et al.  In-situ ultrasonic characterization of microcellular injection molding , 2019, Journal of Materials Processing Technology.

[9]  M. Sánchez-Soto,et al.  Microcellular injection moulding: A comparison between MuCell process and the novel micro-foaming technology IQ Foam , 2019, Journal of Materials Processing Technology.

[10]  R. Pantani,et al.  Lightweight High-Performance Polymer Composite for Automotive Applications , 2019, Polymers.

[11]  Youngjae Ryu,et al.  Warpage Reduction of Glass Fiber Reinforced Plastic Using Microcellular Foaming Process Applied Injection Molding , 2019, Polymers.

[12]  Jianzhong Fu,et al.  On‐line measurement of clamping force for injection molding machine using ultrasonic technology , 2019, Ultrasonics.

[13]  G. Steinbichler,et al.  Influence of process parameters on mechanical properties of physically foamed, fiber reinforced polypropylene parts , 2018, Journal of Applied Polymer Science.

[14]  Chul B. Park,et al.  Lightweight and strong microcellular injection molded PP/talc nanocomposite , 2018, Composites Science and Technology.

[15]  F. Henning,et al.  Process comparison on the microstructure and mechanical properties of fiber-reinforced polyphenylene sulfide using MuCell technology , 2018 .

[16]  António Gaspar-Cunha,et al.  Modeling and optimization of the injection-molding process: a review , 2018 .

[17]  M. Sánchez‐Soto,et al.  Influence of injection molding parameters on the morphology, mechanical and surface properties of ABS foams , 2018 .

[18]  Guoqun Zhao,et al.  Morphology Evolution and Elimination Mechanism of Bubble Marks on Surface of Microcellular Injection-Molded Parts with Dynamic Mold Temperature Control , 2018 .

[19]  Guoqun Zhao,et al.  A novel gas-assisted microcellular injection molding method for preparing lightweight foams with superior surface appearance and enhanced mechanical performance , 2017 .

[20]  Chul B. Park,et al.  Effect of the melt compressibility and the pressure drop rate on the cell-nucleation behavior in foam injection molding with mold opening , 2017 .

[21]  R. Geyer,et al.  Production, use, and fate of all plastics ever made , 2017, Science Advances.

[22]  A. Sato,et al.  Effects of hydrophobic-modified cellulose nanofibers (CNFs) on cell morphology and mechanical properties of high void fraction polypropylene nanocomposite foams , 2017 .

[23]  Chul B. Park,et al.  Visualization of polypropylene crystallites formed from a stressed melt in extrusion , 2016 .

[24]  Guoqun Zhao,et al.  Formation mechanism and structural characteristics of unfoamed skin layer in microcellular injection-molded parts , 2016 .

[25]  V. Altstädt,et al.  Microcellular to nanocellular polymer foams : Progress(2004–2015) and future directions ; A review , 2015 .

[26]  S. Iannace,et al.  Biofoams : Science and Applications of Bio-Based Cellular and Porous Materials , 2015 .

[27]  Imre Kiss,et al.  About the numerous cost and processing advantages of the microcellular foam injection molding process for thermoplastics materials in the automobile industry , 2015 .

[28]  Guoqun Zhao,et al.  Research on formation mechanisms and control of external and inner bubble morphology in microcellular injection molding , 2015 .

[29]  H. Heim,et al.  General aspects of foam injection molding using local precision mold opening technology , 2015 .

[30]  Carlos Javierre,et al.  Analysis of the Influence of Microcellular Injection Molding on the Environmental Impact of an Industrial Component , 2014 .

[31]  Guoqun Zhao,et al.  The cell forming process of microcellular injection‐molded parts , 2014 .

[32]  L. Turng,et al.  Fabrication of super ductile polymeric blends using microcellular injection molding , 2014 .

[33]  Shikai Luo,et al.  Cell morphology and mechanical properties of microcellular mucell® injection molded polyetherimide and polyetherimide/fillers composite foams , 2013 .

[34]  Xiangfang Peng,et al.  Influence and prediction of processing parameters on the properties of microcellular injection molded thermoplastic polyurethane based on an orthogonal array test , 2013 .

[35]  S. Chen,et al.  The effects of gas counter pressure and mold temperature variation on the surface quality and morphology of the microcellular polystyrene foams , 2013 .

[36]  Shikai Luo,et al.  Microstructure and Properties of Microcellular Poly (phenylene sulfide) Foams by Mucell Injection Molding , 2013 .

[37]  E. Vivaldo‐Lima,et al.  Handbook of Polymer Synthesis, Characterization, and Processing , 2013 .

[38]  Fujiao Song,et al.  Effect of nano-Calcium Carbonate on microcellular foaming of polypropylene , 2013, Journal of Materials Science.

[39]  Rean-Der Chien,et al.  Structure and mechanical properties of polystyrene foams made through microcellular injection molding via control mechanisms of gas counter pressure and mold temperature , 2012 .

[40]  Guoqun Zhao,et al.  Thermal response of an electric heating rapid heat cycle molding mold and its effect on surface appearance and tensile strength of the molded part , 2012 .

[41]  Martin Rohleder,et al.  Correlation between injection moulding processing parameters and mechanical properties of microcellular polycarbonate , 2012 .

[42]  T. Ishikawa,et al.  Visual observation and numerical studies of polymer foaming behavior of polypropylene/carbon dioxide system in a core-back injection molding process , 2011 .

[43]  Guang-hong Hu,et al.  Research Progress of Improving Surface Quality of Microcellular Foam Injection Parts , 2011 .

[44]  Jungjoo Lee,et al.  A novel method for improving the surface quality of microcellular injection molded parts , 2011 .

[45]  E. Wintermantel,et al.  The Effects of Mold Design on the Pore Morphology of Polymers Produced with MuCell ®Technology , 2010 .

[46]  L. Turng,et al.  The Microcellular Injection Molding of Low-Density Polyethylene (LDPE) Composites , 2010 .

[47]  M. P. Queirós,et al.  Experimental assessment of hybrid mould performance , 2010 .

[48]  A. S. Pouzada,et al.  Hybrid moulds: effect of the moulding blocks on the morphology and dimensional properties , 2009 .

[49]  T. Kuboki,et al.  Injection Molding of Wood–Fiber/Plastic Composite Foams , 2009 .

[50]  Rean-Der Chien,et al.  Variable mold temperature to improve surface quality of microcellular injection molded parts using induction heating technology , 2008 .

[51]  S. Chen,et al.  Using thermally insulated polymer film for mold temperature control to improve surface quality of microcellular injection molded parts , 2008 .

[52]  K. Taki Experimental and numerical studies on the effects of pressure release rate on number density of bubbles and bubble growth in a polymeric foaming process , 2008 .

[53]  Shyh-Shin Hwang,et al.  Shrinkage study of textile roller molded by conventional/microcellular injection-molding process☆ , 2008 .

[54]  J. Seo,et al.  Bubble Nucleation and Growth in Microcellular Injection Molding Processes , 2008 .

[55]  A. Błędzki,et al.  Microcellular foamed wood-plastic composites by different processes : A review , 2007 .

[56]  Jung Joo Lee,et al.  Characteristics of the Skin Layers of Microcellular Injection Molded Parts , 2006 .

[57]  A. Behravesh,et al.  Experimental Study on Filling Stage of Microcellular Injection Molding Process , 2006 .

[58]  Zhongbao Chen,et al.  Quantitative Study of Shrinkage and Warpage Behavior for Microcellular and Conventional Injection Molding , 2005 .

[59]  Sung Woon Cha,et al.  Influence of Mould Temperature on the Thickness of a Skin Layer and Impact Strength in the Microcellular Injection Moulding Process , 2005 .

[60]  S. Cha,et al.  The Relationship of Mold Temperatures and Swirl Marks on the Surface of Microcellular Plastics , 2005 .

[61]  G. Steinbichler,et al.  Polycarbonate Microfoams with a Smooth Surface and Higher Notched Impact Strength , 2004 .

[62]  L. Turng,et al.  Study of injection molded microcellular polyamide-6 nanocomposites , 2004 .

[63]  S. Cha,et al.  A Mold Surface Treatment for Improving Surface Finish of Injection Molded Microcellular Parts , 2004 .

[64]  L. Turng,et al.  Effects of nano-fillers and process conditions on the microstructure and mechanical properties of microcellular injection molded polyamide nanocomposites , 2003 .

[65]  N. Suh Impact of Microcellular plastics on industrial practice and academic research , 2003 .

[66]  T. Chong,et al.  Effect of dissolved gas on the viscosity of HIPS in the manufacture of microcellular plastics , 2003 .

[67]  J. R. Royer,et al.  Generation of microcellular foams of PVDF and its blends using supercritical carbon dioxide in a continuous process , 2002 .

[68]  Wen-Hsien Yang,et al.  Numerical simulation of mold filling in injection molding using a three‐dimensional finite volume approach , 2001 .

[69]  H. Yokoi,et al.  Visual analysis of cavity filling and packing process in injection molding of thermoset phenolic resin by the gate‐magnetization method , 2001 .

[70]  Chul B. Park,et al.  Processing and characterization of microcellular foamed high-density polythylene/isotactic polypropylene blends , 1998 .

[71]  E. Beckman,et al.  Generation of microcellular polymeric foams using supercritical carbon dioxide. I: Effect of pressure and temperature on nucleation , 1994 .

[72]  Jonathan S. Colton,et al.  The nucleation of microcellular thermoplastic foam with additives: Part II: Experimental results and discussion , 1987 .

[73]  Jonathan S. Colton,et al.  The nucleation of microcellular thermoplastic foam with additives: Part I: Theoretical considerations , 1987 .

[74]  Jonathan S. Colton,et al.  Nucleation of microcellular foam: Theory and practice , 1987 .

[75]  R. Frutiger The effect of flow on cavity surface temperatures in thermoset and thermoplastic injection molding , 1986 .

[76]  Donald V. Rosato,et al.  Injection Molding Handbook , 1985 .

[77]  C. Han,et al.  Studies on structural foam processing. IV. Bubble growth during mold filling , 1981 .

[78]  Z. Tadmor,et al.  Principles of Polymer Processing , 1979 .

[79]  M. Kamal,et al.  The fluid mechanics and heat transfer of injection mold filling of thermoplastic materials , 1976 .

[80]  C. Han,et al.  A study of foam extrusion using a chemical blowing agent , 1976 .

[81]  M. Maspoch,et al.  Microcellular PP/GF composites: Morphological, mechanical and fracture characterization , 2018 .

[82]  M. Berry Microcellular Injection Molding , 2017 .

[83]  Guoqun Zhao,et al.  Investigation on bubble morphological evolution and plastic part surface quality of microcellular injection molding process based on a multiphase-solid coupled heat transfer model , 2017 .

[84]  Shota Ishihara,et al.  A new microcellular foam injection-molding technology using non-supercritical fluid physical blowing agents , 2017 .

[85]  Julia Kastner,et al.  Handbook Of Fluid Dynamics , 2016 .

[86]  D. Arencón,et al.  Morphology and Mechanical Characterization of ABS Foamed by Microcellular Injection Molding , 2015 .

[87]  D. Hsu,et al.  DYNAMIC BEHAVIOR AND EXPERIMENTAL VALIDATION OF CELL NUCLEATION AND GROWING MECHANISM IN MICROCELLULAR INJECTION MOLDING PROCESS , 2012 .

[88]  S. Chen,et al.  Effects of Process Conditions on the Mechanical Properties of Microcellular Injection Molded Polycarbonate Parts , 2008 .

[89]  Mladen Šercer,et al.  Comparison of Moldex3D and Moldflow Injection Moulding Simulation , 2006 .

[90]  Jingyi Xu,et al.  Microcellular foam processing in reciprocating-screw injection molding machines , 2001 .

[91]  J. Colton THE NUCLEATION OF MICROCELLULAR FOAMS IN SEMI CRYSTALLINE THERMOPLASTICS , 1989 .

[92]  N. Suh,et al.  THE NUCLEATION OF MICROCELLULAR THERMOPLASTIC FOAM: PROCESS MODEL AND EXPERIMENTAL RESULTS , 1986 .

[93]  J. Pearson,et al.  Mechanics of polymer processing , 1985 .

[94]  J. Colton The nucleation of microcellular thermoplastic foam , 1985 .

[95]  H. Daoust,et al.  Chemical and Physical Blowing Agents , 1983 .

[96]  Francis Abbott Waldman,et al.  The processing of microcellular foam , 1982 .

[97]  Jane Ellen Martini,et al.  The production and analysis of microcellular foam , 1981 .