Effect of SiO2 Sol/Silane Emulsion in Reducing Water and Chloride Ion Penetration in Concrete

Here, a new concrete hydrophobic treatment method is developed using SiO2 sol and silane emulsion. The effectiveness of the modification for concrete protection is evaluated through testing water absorption and chloride diffusion. Two types of concrete with different strength grades (C40, C50) are used as the research object. The results show that the water capillary absorption coefficient and chloride ion diffusion coefficient of concrete decrease greatly under the protection of SiO2 sol and silane emulsion. Additionally, the protection effect is better with the increase of SiO2 consumption. Contact angle test results reveal that when the coating amount of SiO2 sol and silane emulsion is 300 g/m2, respectively, the contact angle reaches 150.2°, indicating the concrete (C40) surface reaches the superhydrophobic state. Through scanning electron microscope (SEM) observation, it is found that the hydrophobic effect of the SiO2 sol/silane emulsion is mainly due to the change in the surface morphology of concrete (C40).

[1]  Ting Zhang,et al.  Effects of colloidal nano-SiO2 on the immobilization of chloride ions in cement-fly ash system , 2020 .

[2]  Sivaranjani,et al.  Characterization, properties and microstructure studies of cement mortar incorporating nano-SiO2 , 2020 .

[3]  Zhao Tiejun,et al.  Capillary suction induced water absorption and chloride transport in non-saturated concrete: The influence of humidity, mineral admixtures and sulfate ions , 2020 .

[4]  T. Ngo,et al.  Investigation of long-term corrosion resistance of reinforced concrete structures constructed with various types of concretes in marine and various climate environments , 2020, Construction and Building Materials.

[5]  T. Nijland,et al.  The influence of defects at the steel/concrete interface for chloride-induced pitting corrosion of naturally-deteriorated 20-years-old specimens studied through X-ray Computed Tomography , 2020, Construction and Building Materials.

[6]  C. Balestra,et al.  Reinforcement corrosion risk of marine concrete structures evaluated through electrical resistivity: Proposal of parameters based on field structures , 2019, Ocean Engineering.

[7]  P. Chindaprasirt,et al.  Exponentially aging functions coupled with time-dependent chloride transport model for predicting service life of surface-treated concrete in tidal zone , 2019, Cement and Concrete Research.

[8]  X. Weng,et al.  Evaluation of the freeze-thaw durability of surface-treated airport pavement concrete under adverse conditions , 2019, Construction and Building Materials.

[9]  T. Zhao,et al.  Preparation and mechanism of graphene oxide/isobutyltriethoxysilane composite emulsion and its effects on waterproof performance of concrete , 2019, Construction and Building Materials.

[10]  Hui Zhang,et al.  Performance of silane -based surface treatments for protecting degraded historic concrete , 2019, Progress in Organic Coatings.

[11]  Min Liu,et al.  Effects of nano-SiO2 on early strength and microstructure of steam-cured high volume fly ash cement system , 2019, Construction and Building Materials.

[12]  V. Saraswathy,et al.  Development of water-repellent cement mortar using silane enriched with nanomaterials , 2018, Progress in Organic Coatings.

[13]  Jinxiang Hong,et al.  The inhibition behavior of a water-soluble silane for reinforcing steel in 3.5% NaCl saturated Ca(OH)2 solution , 2018, Construction and Building Materials.

[14]  Chuang Wang,et al.  Influences of VTMS/SiO2 ratios on the contact angle and morphology of modified super-hydrophobic silicon dioxide material by vinyl trimethoxy silane , 2018, Results in Physics.

[15]  Alireza Joshaghani,et al.  Nano-SiO2 contribution to mechanical, durability, fresh and microstructural characteristics of concrete: A review , 2018, Construction and Building Materials.

[16]  Y. Lai,et al.  Exploring the influence of SiO2 and TiO2 nanoparticles on the mechanical properties of concrete , 2018, Construction and Building Materials.

[17]  Yongsheng Ji,et al.  Influences of modified nanoparticles on hydrophobicity of concrete with organic film coating , 2018 .

[18]  Qin Wang,et al.  Synthesis and properties of a silane and copolymer-modified graphene oxide for use as a water-reducing agent in cement pastes , 2018 .

[19]  Jiaping Liu,et al.  Application of organic- and nanoparticle-modified foams in foamed concrete: Reinforcement and stabilization mechanisms , 2018 .

[20]  L. Xin,et al.  Effect of sodium sulfate and nano-SiO2 on hydration and microstructure of cementitious materials containing high volume fly ash under steam curing , 2018 .

[21]  Mohammad Dareyni,et al.  Effect of cationic asphalt emulsion as an admixture on transport properties of roller-compacted concrete , 2018 .

[22]  J. Dai,et al.  A systematic investigation of the waterproofing performance and chloride resistance of a self-developed waterborne silane-based hydrophobic agent for mortar and concrete , 2017 .

[23]  A. Joshaghani,et al.  Enhancing the permeability and abrasion resistance of concrete using colloidal nano-SiO2 oxide and spraying nanosilicon practices , 2017 .

[24]  M. Martínez,et al.  Influence of the type of solvent on the development of superhydrophobicity from silane-based solution containing nanoparticles , 2017 .

[25]  Tung-Chai Ling,et al.  A review on surface treatment for concrete – Part 2: Performance , 2017 .

[26]  Tung-Chai Ling,et al.  A review on concrete surface treatment Part I: Types and mechanisms , 2017 .

[27]  Jeffrey M. Davis,et al.  Imaging the presence of silane coatings in concrete with micro X-ray fluorescence , 2017 .

[28]  Xin Cheng,et al.  The use of tetraethyl orthosilicate silane (TEOS) for surface-treatment of hardened cement-based materials: A comparison study with normal treatment agents , 2016 .

[29]  M. Tyler Ley,et al.  Determining the effective service life of silane treatments in concrete bridge decks , 2016 .

[30]  C. Cansoy,et al.  Applicability of Cassie–Baxter equation for superhydrophobic fluoropolymer–silica composite films , 2015 .

[31]  G. Brenner-Weiss,et al.  Characterization of silane-based hydrophobic admixtures in concrete using TOF-MS , 2015 .

[32]  J. Aguiar,et al.  Carbonation of surface protected concrete , 2013 .

[33]  Chris I. Goodier,et al.  Long-term performance of surface impregnation of reinforced concrete structures with silane , 2013 .

[34]  Deyu Kong,et al.  Modification effects of colloidal nanoSiO2 on cement hydration and its gel property , 2013 .

[35]  A. Nazari,et al.  Microstructural, thermal, physical and mechanical behavior of the self compacting concrete containing SiO2 nanoparticles , 2010 .

[36]  G. Moriconi,et al.  The effect of silane-based hydrophobic admixture on corrosion of reinforcing steel in concrete , 2008 .

[37]  Surendra P. Shah,et al.  Effects of colloidal nanosilica on rheological and mechanical properties of fly ash–cement mortar , 2013 .

[38]  Chi Sun Poon,et al.  Influence of silane-based water repellent on the durability properties of recycled aggregate concrete , 2013 .

[39]  R. C. Joshi,et al.  Reexamination of ASTM C 1202 : Standard test method for electrical indication of concrete's ability to resist chloride ion penetration , 2000 .