Effect of thin SiO2 layers deposited by means of atomic layer deposition method on the mechanical and physical properties of stainless steel

The aim of this study was to assess the suitability of the atomic layer deposition method in terms of using it for 316 LVM (low carbon vacuum melt) steel surface modification that is used for blood‐contacting implants in determined technological conditions. As part of a suitability assessment of thin layer deposition technology, the performance of mechanical and physical properties testing was proposed. The investigation influences the evaluation of the analysed material in the cardiovascular system's behavior used for blood. 316 LVM stainless steel was the initial material to be tested. The 316 LVM steel was subjected to the following surface modifications: electrolytic polishing, chemical passivation and deposition of a silicon dioxide (SiO2) layer using the atomic layer deposition method. The layer was applied at a variable thickness depending on the atomic layer deposition process, at constant temperature. In terms of mechanical properties, the analyzing adhesion of applied layers to the metallic base and its hardness were examined. What is more, during the evaluation of physical properties, testing of surface wettability was performed, which has a fundamental significance in case of implants used in the cardiovascular system. The obtained results have direct impact on optimization process of SiO2 layers deposition with atomic layer deposition method on blood‐contacting implants, which surface was made of steel 316 LVM, there by resulting in their have a direct impact functional properties improvement.

[1]  I. Jovin,et al.  In-stent restenosis nine years after initial placement of a drug-eluting stent. , 2017, Cardiovascular revascularization medicine : including molecular interventions.

[2]  Jin-seong Park,et al.  Low temperature atomic layer deposition of SiO2 thin films using di-isopropylaminosilane and ozone , 2017 .

[3]  T. Pustelny,et al.  Influence of surface modification on physico-chemical properties of Ti6Al7Nb alloy , 2016 .

[4]  R. Aune,et al.  Tribocorrosion studies of metallic biomaterials: The effect of plasma nitriding and DLC surface modifications. , 2016, Journal of the mechanical behavior of biomedical materials.

[5]  K. Gołombek,et al.  Corrosion Resistance, EIS and Wettability of the Implants Made of 316 LVM Steel Used in Chest Deformation Treatment , 2016 .

[6]  Z. Opilski,et al.  Mechanical properties of atomic layer deposition (ALD) TiO2 layers on stainless steel substrates , 2016 .

[7]  R. Jendruś,et al.  Influence of Surface Modification on Properties of Stainless Steel Used for Implants / Wpływ Modyfikacji Powierzchni Na Właściwości Stali Nierdzewnej Stosowanej Na Implanty , 2015 .

[8]  Anil Mahapatro,et al.  Bio-functional nano-coatings on metallic biomaterials. , 2015, Materials science & engineering. C, Materials for biological applications.

[9]  A. Fave,et al.  Characterization of Al2O3 Thin Films Prepared by Thermal ALD , 2015 .

[10]  Mehrdad Yousefi,et al.  Parametrical optimization of stent design; a numerical-based approach , 2014 .

[11]  A. Lanzutti,et al.  Multilayer Al2O3/TiO2 Atomic Layer Deposition coatings for the corrosion protection of stainless steel , 2012 .

[12]  M. Gelfi,et al.  Young modulus and Poisson ratio measurements of TiO2 thin films deposited with Atomic Layer Deposition , 2012 .

[13]  Antonio Colombo,et al.  Selection of coronary stents. , 2002, Journal of the American College of Cardiology.

[14]  M. Basiaga,et al.  Influence of ALD process parameters on the physical and chemical properties of the surface of vascular stents , 2017 .

[15]  P. Chu,et al.  Thin Film Coatings for Biomaterials and Biomedical Applications , 2016 .

[16]  C. Wen,et al.  Introduction to surface coating and modification for metallic biomaterials , 2015 .

[17]  S. Bruyère,et al.  TiO2 anatase films obtained by direct liquid injection atomic layer deposition at low temperature , 2014 .

[18]  Hongkai Liu,et al.  Study on preparation and characters of one multi-function SiO2 film , 2011 .