Tectono-Magmatic Setting of the Divar Deposit, Eastern Iran: Evidences for VMS Mineralzation

The Divar VMS deposit is located in the Nehbandan ophiolite complex (NOC). It is 10 hosted in the Sistan suture zone (SSZ) marking the boundary between the Lut and Afghan 11 continental blocks. This area is composed mainly of various ophiolitic rock units representing a 12 tectono-sedimentary mélange, which are commonly interpreted as being the remnants of Sistan 13 oceanic lithosphere. The major host rocks cropping out in the Divar deposit are mantle peridotites 14 include clinopyroxene(cpx-) rich harzburgites and depleted harzburgites with gabbronorite, 15 cumulate gabbro, basalt and pelagic sediments. They are interpreted as being related to the rifting 16 and subsequent Late Triassic continental break-up of the southern Neothethys. In this study 17 petrographic observations mineral chemistry with whole rock chemistry, and rare earth element 18 (REE) modeling were carried out on the different rocks associated with Divar deposit. The 19 presented data led to the following conclusions: (1) The depleted harzburgites proved to be related 20 to the residual mantle after 18–22% removal of melts. This is comparable with abyssal peridotites; 21 (2) The cpx-rich harzburgites represent the residual mantle after the removal of 11–13% mid-ocean 22 ridge basalt-type (MORB). Subsequently, the residual mantle was enriched in light REE (LREE) by 23 subduction-derived fluids; (3) The gabbronorite and cumulate gabbro represents a portion of 24 oceanic crust generated in a mid-ocean ridge setting; (4) The basalts belong to the N-MORB-type 25 with no considerable crustal contamination. From the top to bottom, the Divar deposit is 26 characterized a gossan zone, a thick massive ore zone, and a poorly developed stockwork zone. In 27 Divar deposit, host rocks are indicated by serpentinized peridotites and severely altered mafic 28 rocks that include disseminated and stockwork ore under massive lenses. These rocks showed a 29 mineral assemblage of carbonate + quartz-jasper + chlorite + albite + epidote that demonstrate 30 greenschist facies ocean floor metamorphism. Moreover, in the footwall rocks, sericitization and 31 hematitization are also observed. Primary mineralization includes bedded ore, sulphide breccias, 32 stockworks and chimney fragments. Ore mineral abundances decrease from pyrite, magnetite, to 33 chalcopyrite, and sphalerite. Highlightly, there are two distinct mineralization phases' namely 34 massive sulphide (stage-1) and massive magnetite (stage-2). The spatial relationships with the host 35 rocks and textural evidence (e.g., magnetite replacing sulphides) indicate that sulphide minerals 36 and magnetite were generated in different stages. The transition from sulphide to magnetite 37 mineralization is interpreted as being related to the variation of H2S content in the ore fluids. The 38 massive sulphide ore (stage 1) might have formed by primary hydrothermal fluids enriched in H2S 39 and Fe. The second stage (massive magnetite) seem to be related to the later hydrothermal fluids 40 enriched in Fe but poor in H2S, replacing the pre-existing sulphide minerals. The lithological 41 features (stockwork/massive ore and gossan), mineral paragenesis and alteration patterns of the 42 Divar deposit are all consistent with a Cyprus-type VMS system mineralization. However, 43 magnetite formation after the early sulphide mineralization is quite different with typical 44 Cyprus-type VMS deposits where magnetite commonly occurs in lower sections. Consequently, 45 although the general features of Divar deposit is analogous to those of Cyprus-type deposits, but 46 strong magnetite mineralization especially in late stages may indicate that this deposit could be 47 considered as an exceptional Cyprus-type VMS deposit. 48 Preprints (www.preprints.org) | NOT PEER-REVIEWED | Posted: 31 October 2017 doi:10.20944/preprints201710.0193.v1 © 2017 by the author(s). Distributed under a Creative Commons CC BY license.

[1]  M. Bröcker,et al.  Cretaceous high-pressure metamorphism and low pressure overprint in the Sistan Suture Zone, eastern Iran: Additional temperature estimates for eclogites, geological significance of U-Pb zircon ages and Rb-Sr constraints on the timing of exhumation , 2017 .

[2]  D. Teagle,et al.  Hydrothermal mobilisation of Au and other metals in supra-subduction oceanic crust: Insights from the Troodos ophiolite , 2017 .

[3]  H. Moeinzadeh,et al.  Comparison of support vector machine and neutral network classification method in hyperspectral mapping of ophiolite mélanges–A case study of east of Iran , 2017 .

[4]  A. Abedini,et al.  Geology and geochemistry of the sediment-hosted Cheshmeh-Konan redbed-type copper deposit, NW Iran , 2017 .

[5]  L. Beccaluva,et al.  The Betic Ophiolites and the Mesozoic Evolution of the Western Tethys , 2017 .

[6]  J. Cloutier,et al.  Lithostratigraphic and structural reconstruction of the Zn-Pb-Cu-Ag-Au Lemarchant volcanogenic massive sulphide (VMS) deposit, Tally Pond group, central Newfoundland, Canada , 2017 .

[7]  K. Keil,et al.  The origin of aubrites: Evidence from lithophile trace element abundances and oxygen isotope compositions , 2016 .

[8]  D. Lentz,et al.  Analysis of Au-Ag Mineralization in the Caribou Base-Metal VMS Deposit, New Brunswick; Examination of Micro-Scale Inter- and Intra-Sulphide Distribution and Its Relation to Geometallurgy , 2016 .

[9]  A. Hezarkhani,et al.  Delineation of Geochemical Anomalies Based on Cu by the Boxplot as an Exploratory Data Analysis (EDA) Method and Concentration-Volume (C-V) Fractal Modeling in Mesgaran Mining Area, Eastern Iran , 2016 .

[10]  K. Zaw,et al.  Geology, ore facies and sulfur isotopes geochemistry of the Nudeh Besshi-type volcanogenic massive sulfide deposit, southwest Sabzevar basin, Iran , 2016 .

[11]  A. Surour,et al.  Fluid-related modifications of Cr-spinel and olivine from ophiolitic peridotites by contact metamorphism of granitic intrusions in the Ablah area, Saudi Arabia , 2016 .

[12]  P. Monaco,et al.  Depositional environments and ichnology of Upper Cretaceous deep-marine deposits in the Sistan Suture Zone, Birjand, Eastern Iran , 2016 .

[13]  J. Burg,et al.  U-Pb geochronology and geochemistry of Zahedan and Shah Kuh plutons, southeast Iran: Implication for closure of the South Sistan suture zone , 2016 .

[14]  K. Haase,et al.  Systematic variations of trace element and sulfur isotope compositions in pyrite with stratigraphic depth in the Skouriotissa volcanic-hosted massive sulfide deposit, Troodos ophiolite, Cyprus , 2016 .

[15]  E. Schetselaar,et al.  Seismic properties and effects of hydrothermal alteration on Volcanogenic Massive Sulfide (VMS) deposits at the Lalor Lake in Manitoba, Canada , 2015 .

[16]  B. Malvoisin Mass transfer in the oceanic lithosphere: Serpentinization is not isochemical , 2015 .

[17]  Xiao-dong Liu,et al.  Mid-ocean ridge (MOR) and suprasubduction zone (SSZ) geological events in the Yarlung Zangbo suture zone: Evidence from the mineral record of mantle peridotites , 2015 .

[18]  E. Saccani A new method of discriminating different types of post-Archean ophiolitic basalts and their tectonic significance using Th-Nb and Ce-Dy-Yb systematics , 2015 .

[19]  Maanijou Mohammad,et al.  FLUID INCLUSION AND SULFUR STABLE ISOTOPE EVIDENCE FOR THE ORIGIN OF THE AHANGRAN PB-AG DEPOSIT , 2015 .

[20]  M. Hamada,et al.  Water content in arc basaltic magma in the Northeast Japan and Izu arcs: an estimate from Ca/Na partitioning between plagioclase and melt , 2014, Earth, Planets and Space.

[21]  R. Stern,et al.  Ophiolites of Iran: Keys to understanding the tectonic evolution of SW Asia: (I) Paleozoic ophiolites , 2014 .

[22]  N. Cook,et al.  Trace and minor elements in sphalerite from metamorphosed sulphide deposits , 2014, Mineralogy and Petrology.

[23]  M. Bröcker,et al.  New age constraints for the geodynamic evolution of the Sistan Suture Zone, eastern Iran , 2013 .

[24]  Y. Dilek,et al.  Geochronology and petrology of the Early Carboniferous Misho Mafic Complex (NW Iran), and implications for the melt evolution of Paleo-Tethyan rifting in Western Cimmeria , 2013 .

[25]  M. Khatib,et al.  Zircon U–Pb age and geochemical constraints on the origin of the Birjand ophiolite, Sistan suture zone, eastern Iran , 2012 .

[26]  L. Beccaluva,et al.  PETROLOGY OF MANTLE PERIDOTITES AND INTRUSIVE MAFIC ROCKS FROM THE KERMANSHAH OPHIOLITIC COMPLEX (ZAGROS BELT, IRAN): IMPLICATIONS FOR THE GEODYNAMIC EVOLUTION OF THE NEO-TETHYAN OCEANIC BRANCH BETWEEN ARABIA AND IRAN , 2010 .

[27]  H. Furnes,et al.  Structure and geochemistry of Tethyan ophiolites and their petrogenesis in subduction rollback systems , 2009 .

[28]  O. Parlak,et al.  Tectonic significance of the geochemistry and petrology of ophiolites in southeast Anatolia, Turkey , 2009 .

[29]  F. Fürsich,et al.  The Cimmerian Orogeny in northern Iran: tectono‐stratigraphic evidence from the foreland , 2009 .

[30]  Ömer Akıncı,et al.  Ophiolite-Hosted Copper and Gold Deposits of Southeastern Turkey: Formation and Relationship with Seafloor Hydrothermal Processes , 2009, Turkish Journal of Earth Sciences.

[31]  J. Molina,et al.  The Eocene bimodal Piranshahr massif of the Sanandaj–Sirjan Zone, NW Iran: a marker of the end of the collision in the Zagros orogen , 2009, Journal of the Geological Society.

[32]  A. Zanchi,et al.  The Eo-Cimmerian (Late? Triassic) orogeny in North Iran , 2009 .

[33]  R. Metcalf,et al.  Suprasubduction-zone ophiolites: Is there really an ophiolite conundrum? , 2008 .

[34]  E. Rastad,et al.  The Bavanat Cu-Zn-Ag orebody: First recognition of a Besshi-type VMS deposit in Iran , 2007 .

[35]  M. Salisbury APPLICATION OF SEISMIC METHODS TO MINERAL EXPLORATION , 2007 .

[36]  A. Aftabi,et al.  Metamorphic textures and geochemistry of the Cyprus-type massive sulfide lenses at Zurabad, Khoy, Iran , 2006 .

[37]  T. Juteau,et al.  Petrological and geochemical study of the Late Cretaceous ophiolite of Khoy (NW Iran), and related geological formations , 2006 .

[38]  C. J. Talbot,et al.  A new tectonic scenario for the Sanandaj–Sirjan Zone (Iran) , 2006 .

[39]  M. Karimpour,et al.  Taknar Polymetal (Cu-Zn-Au-Ag-Pb) Deposit: A New Type Magnetite-Rich VMS Deposit, Northeast of Iran , 2005 .

[40]  S. Hart,et al.  Major and trace element composition of the depleted MORB mantle (DMM) , 2005 .

[41]  P. D. Wever,et al.  Early Cretaceous radiolarian assemblages from radiolarites in the Sistan Suture (eastern Iran) , 2004 .

[42]  M. Doyle,et al.  Subsea-floor replacement in volcanic-hosted massive sulfide deposits , 2003 .

[43]  C. Fergusson,et al.  Cretaceous–Tertiary convergence and continental collision, Sanandaj–Sirjan Zone, western Iran , 2003 .

[44]  Seyed Ahmad Babazadeh Biostratigraphie et contrôles paléogéographiques de la zone de suture de l'Iran oriental : implications sur la fermeture Téthysienne , 2003 .

[45]  J. Gemmell,et al.  The Archean Cu-Zn Magnetite-Rich Gossan Hill Volcanic-Hosted Massive Sulfide Deposit, Western Australia: Genesis of a Multistage Hydrothermal System , 2002 .

[46]  E. Rastad,et al.  SHEIKH-ALI COPPER DEPOSIT, A CYPRUS-TYPE VMS DEPOSIT IN SOUTHEAST IRAN , 2002 .

[47]  S. Edwards,et al.  Geochemistry and tectonic significance of peridotites from the South Sandwich arc–basin system, South Atlantic , 2000 .

[48]  C. Fergusson,et al.  Dextral transpression in Late Cretaceous continental collision, Sanandaj–Sirjan Zone, western Iran , 2000 .

[49]  M. Hannington,et al.  Setting and characteristics of ophiolite-hosted volcanogenic massive sulfide deposits , 1999 .

[50]  J. Craig,et al.  Pyrite: physical and chemical textures , 1998 .

[51]  A. Hofmann,et al.  Isotopic contrasts within the Internal Liguride ophiolite (N. Italy): the lack of a genetic mantle-crust link , 1998 .

[52]  A. Hofmann,et al.  Petrology, Mineral and Isotope Geochemistry of the External Liguride Peridotites (Northern Apennines, Italy) , 1995 .

[53]  D. Peate,et al.  Tectonic Implications of the Composition of Volcanic Arc Magmas , 1995 .

[54]  A. Sobolev,et al.  Petrology and Geochemistry of Boninites from the North Termination of the Tonga Trench: Constraints on the Generation Conditions of Primary High-Ca Boninite Magmas , 1994 .

[55]  S. Arai Characterization of spinel peridotites by olivine-spinel compositional relationships: Review and interpretation , 1994 .

[56]  M. Alavi TECTONICS OF THE ZAGROS OROGENIC BELT OF IRAN - NEW DATA AND INTERPRETATIONS , 1994 .

[57]  T. Ishii,et al.  Petrological studies of peridotites from Diapiric Serpentinite seamounts in the Izu-Ogasawara-Mariana forearc, Leg125 , 1992 .

[58]  M. Alavi,et al.  Sedimentary and structural characteristics of the Paleo-Tethys remnants in northeastern Iran , 1991 .

[59]  J. Franklin,et al.  Lithogeochemical and Mineralogical Methods For Base Metal and Gold Exploration , 1991 .

[60]  P. Rickwood Boundary lines within petrologic diagrams which use oxides of major and minor elements , 1989 .

[61]  W. McDonough,et al.  Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes , 1989, Geological Society, London, Special Publications.

[62]  Nobuo Morimoto,et al.  Nomenclature of Pyroxenes , 1988, Mineralogical Magazine.

[63]  H. Dick,et al.  Chromian spinel as a petrogenetic indicator in abyssal and alpine-type peridotites and spatially associated lavas , 1984 .

[64]  W. Boynton Geochemistry of the rare earth elements : meteorite studies , 1984 .

[65]  R. A. Howie Mineral Deposits of Europe. Volume 2: Southeast Europe , 1983, Mineralogical Magazine.

[66]  Victor E. Camp,et al.  The Sistan suture zone of eastern Iran , 1983 .

[67]  Victor E. Camp,et al.  Character, genesis and tectonic setting of igneous rocks in the Sistan suture zone, eastern Iran , 1982 .

[68]  Julian A. Pearce,et al.  Trace element characteristics of lavas from destructive plate boundaries , 1982 .

[69]  M. Berberian,et al.  Towards a paleogeography and tectonic evolution of Iran: Reply , 1981 .

[70]  G. Serri The petrochemistry of ophiolite gabbroic complexes. A key for the classification of ophiolites into low-Ti and high-Ti types , 1981 .

[71]  D. Mallick,et al.  The volcanic stratigraphy and location of massive sulphide deposits in the Oman ophiolite , 1980 .

[72]  P. Thornley,et al.  Some geothermal aspects of polymetallic massive sulfide formation , 1979 .

[73]  A. Şengör,et al.  Post-collisional tectonics of the Turkish-Iranian plateau and a comparison with Tibet , 1979 .

[74]  J. Pearce,et al.  Petrogenetic implications of Ti, Zr, Y, and Nb variations in volcanic rocks , 1979 .

[75]  J. Haas The effect of salinity on the maximum thermal gradient of a hydrothermal system at hydrostatic pressure , 1971 .

[76]  T. Irvine,et al.  A Guide to the Chemical Classification of the Common Volcanic Rocks , 1971 .