Capillary Pressure Saturation Relations for PEM Fuel Cell Gas Diffusion Layers

Capillary pressure saturation relations (CPSRs) are presented for Toray TGP-H-060 and Mitsubishi rayon carbon fiber paper which can both be used as gas diffusion layers (GDLs) in proton-exchange membrane fuel cells (PEMFCs). The saturation is measured using water over a range of capillary pressures. Boundary and scanning curves for imbibition and drainage are measured to further understand the hysteresis observed during PEMFC operation. The primary source of hysteresis in CPSRs is attributed to the difference in advancing and receding contact angles. The measured hysteresis is predicted to have a significant effect on mass transport in the GDL and thus performance in PEMFCs.

[1]  Ioannis Chatzis,et al.  Network modelling of pore structure and transport properties of porous media , 1993 .

[2]  Shouxiang Ma,et al.  Effect of contact angle on drainage and imbibition in regular polygonal tubes , 1996 .

[3]  Chao-Yang Wang,et al.  Fundamental models for fuel cell engineering. , 2004, Chemical reviews.

[4]  V. S. Bagotzky,et al.  The standard contact porosimetry , 2001 .

[5]  Jiujun Zhang,et al.  A review of water flooding issues in the proton exchange membrane fuel cell , 2008 .

[6]  Chao-Yang Wang,et al.  Pore-network modeling of liquid water transport in gas diffusion layer of a polymer electrolyte fuel cell , 2007 .

[7]  A. Weber,et al.  Modeling transport in polymer-electrolyte fuel cells. , 2004, Chemical reviews.

[8]  Hubert A. Gasteiger,et al.  Handbook of fuel cells : fundamentals technology and applications , 2003 .

[9]  T. Nguyen,et al.  Measurement of Capillary Pressure Property of Gas Diffusion Media Used in Proton Exchange Membrane Fuel Cells , 2008 .

[10]  Mark Pritzker,et al.  Capillary pressure and hydrophilic porosity in gas diffusion layers for polymer electrolyte fuel cells , 2006 .

[11]  B. Miller,et al.  A study of the primary cause of contact angle hysteresis on some polymeric solids , 1980 .

[12]  M. Fowler,et al.  In-plane and through-plane gas permeability of carbon fiber electrode backing layers , 2006 .

[13]  S. M. Hassanizadeh,et al.  A Theoretical Model of Hysteresis and Dynamic Effects in the Capillary Relation for Two-phase Flow in Porous Media , 2001 .

[14]  R. Good,et al.  Contact angle, wetting, and adhesion: a critical review , 1992 .

[15]  K. Sharp,et al.  Validated Leverett Approach for Multiphase Flow in PEFC Diffusion Media II. Compression Effect , 2007 .

[16]  Jin Hyun Nam,et al.  Effective diffusivity and water-saturation distribution in single- and two-layer PEMFC diffusion medium , 2003 .

[17]  K. Sharp,et al.  Validated Leverett Approach for Multiphase Flow in PEFC Diffusion Media I. Hydrophobicity Effect , 2007 .

[18]  A. Bismarck,et al.  Influence of fluorination on the properties of carbon fibres , 1997 .

[19]  A. Weber,et al.  Understanding porous water-transport plates in polymer-electrolyte fuel cells , 2007 .

[20]  J. Bear Dynamics of Fluids in Porous Media , 1975 .

[21]  T. Fuller,et al.  Water and Thermal Management in Solid‐Polymer‐Electrolyte Fuel Cells , 1993 .

[22]  J. Newman,et al.  Modeling Two-Phase Behavior in PEFCs , 2004 .

[23]  Extrand,et al.  An Experimental Study of Contact Angle Hysteresis , 1997, Journal of colloid and interface science.

[24]  A. Cassie,et al.  Wettability of porous surfaces , 1944 .

[25]  Jung S. Yi,et al.  Water management along the flow channels of PEM fuel cells , 2004 .

[26]  Kendra V. Sharp,et al.  Validated Leverett Approach for Multiphase Flow in PEFC Diffusion Media III. Temperature Effect and Unified Approach , 2007 .

[27]  Mark Pritzker,et al.  Pore network modeling of fibrous gas diffusion layers for polymer electrolyte membrane fuel cells , 2007 .

[28]  J. St-Pierre,et al.  A microfluidic approach for measuring capillary pressure in PEMFC gas diffusion layers , 2007 .