Towards sustainable energy. Generation of hydrogen fuel using nuclear energy

Abstract The increasing demand for sustainable energy results in the development of new technologies of energy generation. The key objective of hydrogen economy is the introduction of hydrogen as main energy carrier, along with electricity, on a global scale. The key goal is the development of hydrogen-related technologies needed for hydrogen generation, hydrogen storage, hydrogen transportation and hydrogen distribution as well as hydrogen safety systems. It is commonly believed that hydrogen is environmentally clean since its combustion results in the formation of water. However, the technology currently employed for the generation of hydrogen from natural gas, does in fact lead to the emission of greenhouse gases and climate change. Therefore, the key issues in the introduction of hydrogen economy involve the development of environmentally clean hydrogen production technology as well as storage and transport. The clean options available for hydrogen generation using nuclear energy; such as advanced nuclear fission and, ultimately, nuclear fusion, are discussed. The latter, which is environmentally clean, is expected to be the primary approach in the production of hydrogen fuel at the global scale. The present work considers the effect of hydrogen on properties of TiO2 and its solid solutions in the contexts of photocatalytic energy conversion and the effect of tritium on advanced tritium breeders.

[1]  S. A. Sherif,et al.  Handbook of Hydrogen Energy , 2014 .

[2]  L. Vlček,et al.  Dynamics and structure of hydration water on rutile and cassiterite nanopowders studied by quasielastic neutron scattering and molecular dynamics simulations. , 2007 .

[3]  C. Johnson,et al.  Properties and performance of tritium breeding ceramics , 1992 .

[4]  F. Moura,et al.  Self-trapping of interacting electrons in crystalline nonlinear chains , 2012 .

[5]  L. Padilla-Campos A theoretical investigation of occupation sites for tritium atoms in lithium titanate , 2003 .

[6]  K. Okuno,et al.  Tritium release behavior of ceramic breeder candidates for fusion reactors , 1988 .

[7]  H. Friedli,et al.  Ice core record of the 13C/12C ratio of atmospheric CO2 in the past two centuries , 1986, Nature.

[8]  J. R. Powell,et al.  Studies of fusion reactor blankets with minimum radioactive inventory and with tritium breeding in solid lithium compounds: a preliminary report , 1973 .

[9]  Y. Oya,et al.  Migration of hydrogen isotopes in lithium metatitanate , 2013 .

[10]  E. Wachsman,et al.  Photosensitive oxide semiconductors for solar hydrogen fuel and water disinfection , 2014 .

[11]  N. Hine,et al.  Point Defects and Non-stoichiometry in Li2TiO3 , 2014 .

[12]  Z. Wen,et al.  Effect of Ta-doping on the ionic conductivity of lithium titanate , 2010 .

[13]  Yoshinori Kawamura,et al.  Evaluation of Tritium Release Properties of AdvancedTritium Breeders , 2015 .

[14]  P. Bonoli,et al.  ARC: A compact, high-field, fusion nuclear science facility and demonstration power plant with demountable magnets , 2014, 1409.3540.

[15]  T. Nejat Veziroglu,et al.  21st Century's Energy: Hydrogen Energy System , 2008 .

[16]  T. Veziroglu,et al.  Remediation of greenhouse problem through replacement of fossil fuels by hydrogen , 1989 .

[17]  K. Schoots,et al.  Learning curves for hydrogen production technology: An assessment of observed cost reductions , 2008 .

[18]  H. Oeschger,et al.  Evidence from polar ice cores for the increase in atmospheric CO2 in the past two centuries , 1985, Nature.

[19]  H. F. Zhang,et al.  First-principles study of electronic, dynamical and thermodynamic properties of Li2TiO3 , 2012 .

[20]  T. Veziroglu,et al.  Sustainable practices: Solar hydrogen fuel and education program on sustainable energy systems , 2014 .

[21]  T. Nejat Veziroglu,et al.  IMPACT OF HYDROGEN ON THE ENVIRONMENT , 2011, Alternative Energy and Ecology (ISJAEE).

[22]  J. Lawson SOME CRITERIA FOR A POWER PRODUCING THERMONUCLEAR REACTOR , 1957 .

[23]  Craig M. Brown,et al.  Hydrogen adsorption in HKUST-1: a combined inelastic neutron scattering and first-principles study , 2009, Nanotechnology.

[24]  A. Lusis,et al.  Electrical conductivity studies in the system Li2TiO3-Li1.33Ti1.67O4 , 2002 .

[25]  P. Gierszewski Review of properties of lithium metatitanate , 1998 .

[26]  Eileen Claussen,et al.  Climate change : science, strategies, & solutions , 2001 .

[27]  Shinzaburo Matsuda,et al.  The EU/JA broader approach activities , 2007 .

[28]  Tsuyoshi Hoshino,et al.  Development of fabrication technologies for advanced breeding functional materials For DEMO reactors , 2012 .

[29]  J. V. Cathcart,et al.  Tritium diffusion in rutile (TiO2) , 1979 .

[30]  G. J. Hill,et al.  The effect of hydrogen on the electrical properties of rutile , 1968 .

[31]  S. Murphy Tritium Solubility in Li2TiO3 from First-Principles Simulations , 2014 .

[32]  H. Kleykamp,et al.  Phase equilibria in the Li–Ti–O system and physical properties of Li2TiO3 , 2002 .

[33]  Alan M. Baxter,et al.  Deep-Burn: making nuclear waste transmutation practical , 2003 .

[34]  T. Norby Proton Conduction in Solids: Bulk and Interfaces , 2009 .

[35]  P. Chester,et al.  Electrolytically Induced Conductivity in Rutile , 1963, Nature.

[36]  T. Nejat Veziroglu,et al.  Solar hydrogen energy : the power to save the earth , 1991 .

[37]  Y. Oya,et al.  Dependency of irradiation damage density on tritium migration behaviors in Li2TiO3 , 2014 .

[38]  Z. Wen,et al.  Synthesis and ionic conductivity of Mg-doped Li2TIO3 , 2008 .

[39]  N. Roux,et al.  Low-temperature tritium releasing ceramics as potential materials for the ITER breeding blanket , 1996 .

[40]  Yoichi Takahashi,et al.  Non-stoichiometry and its effect on thermal properties of Li2TiO3 , 2002 .

[41]  Per Kofstad,et al.  Nonstoichiometry, diffusion, and electrical conductivity in binary metal oxides. , 1972 .

[42]  E. Wachsman,et al.  Effect of Crystal Imperfections on Reactivity and Photoreactivity of TiO2 (Rutile) with Oxygen, Water, and Bacteria , 2011 .

[43]  D. J. Suiter Lithium-based oxide ceramics for tritium-breeding applications , 1983 .

[44]  P. Knauth,et al.  Electrical and Point Defect Properties of TiO2 Nanotubes Fabricated by Electrochemical Anodization , 2011 .

[45]  C. D. Keeling,et al.  A three‐dimensional model of atmospheric CO2 transport based on observed winds: 1. Analysis of observational data , 2013 .

[46]  L. V. Brutzel,et al.  Atomistic Simulation of the Structural, Thermodynamic, and Elastic Properties of Li2TiO3 , 2011 .

[47]  K. Tsuchiya,et al.  Preliminary test for reprocessing technology development of tritium breeders , 2009 .

[48]  Agence pour l'Energie Nucléaire Nuclear Production of Hydrogen , 2004 .