Path tracking control of intelligent vehicles has to deal with the difficulties of model uncertainties and nonlinearities. As a class of adaptive optimal control methods, reinforcement learning (RL) has received increasing attention in solving difficult control problems. However, feature representation and online learning ability are two major problems to be solved for learning control of uncertain dynamic systems. In this article, we propose a multi-kernel online RL approach for path tracking control of intelligent vehicles. In the proposed approach, a multiple kernel feature learning framework is designed for online learning control based on dual heuristic programming (DHP) and the new online learning control algorithm is called multi-kernel DHP (MKDHP). In MKDHP, instead of the expert knowledge for selecting and fine-tuning of a suitable kernel function, only a set of basic kernel functions is required to be predefined and the multi-kernel features can be learned for value function approximation in the critic. The simulation studies on path tracking control for intelligent vehicles have been conducted under $S$ -curve and urban road conditions. The results demonstrated that compared with other typical path tracking controllers for intelligent vehicles, such as the linear quadratic regulator (LQR), the pure pursuit controller and the ribbon-based controller, the proposed multi-kernel learning controller can achieve better performance in terms of tracking precision and smoothness.