Synthesis, structure, and reactivity of mixed-sandwich zirconacarborane methyl complex (η5-C5Me5)[η1:η5-(Me2NCH2CH2)C2B9H10]ZrMe

[1]  Dongmei Liu,et al.  Synthesis, structure, and alkyne insertion of a mixed-sandwich zirconacarborane alkyl , 2015 .

[2]  Jingying Yang,et al.  Synthesis, structure and reactivity of rare-earth metallacarborane alkyls [η(1):η(5)-O(CH2)2C2B9H9]Ln(σ:η(1)-CH2C6H4-o-NMe2)(THF)2. , 2015, Dalton transactions.

[3]  Yangjian Quan,et al.  Transition-metal-mediated three-component cascade cyclization: selective cage B-C(sp2) coupling of carborane with aromatics and synthesis of carborane-fused tricyclics. , 2014, Journal of the American Chemical Society.

[4]  Yong Tang,et al.  Side arm strategy for catalyst design: modifying bisoxazolines for remote control of enantioselection and related. , 2014, Accounts of chemical research.

[5]  Yangjian Quan,et al.  Three-component [2+2+1] cross-cyclotrimerization of carboryne, unactivated alkene, and trimethylsilylalkyne co-mediated by Zr and Ni. , 2013, Journal of the American Chemical Society.

[6]  Li Xiang,et al.  Reaction of [η(1):η(5)-(Me2NCH2CH2)C2B9H10]TaMe3 with aryl isonitriles: tantallacarborane-mediated facile cleavage of C-N multiple bonds. , 2013, Chemical communications.

[7]  Fabian G. Schröder,et al.  Deprotonated P-ylides As Templates for Novel Cyclopentadienyl Phosphonioalkyl, -alkylidene, and -alkylidyne (CpPC) Constrained-Geometry Complexes , 2013 .

[8]  N. Hosmane.  Boron Science : New Technologies and Applications , 2011 .

[9]  Yue-Peng Cai,et al.  Synthesis, structural characterization, and reactivity of Group 4 metallacarboranes bearing the ligand [H2C(C5Me4)(C2B9H10)]3-. , 2011, Chemistry, an Asian journal.

[10]  G. Bellachioma,et al.  Synthesis, Characterization, Interionic Structure, and Self-Aggregation Tendency of Zirconaaziridinium Salts Bearing Long Alkyl Chains , 2011 .

[11]  Zuowei Xie,et al.  Palladium/nickel-cocatalyzed cycloaddition of 1,3-dehydro-o-carborane with alkynes. Facile synthesis of C,B-substituted carboranes. , 2010, Journal of the American Chemical Society.

[12]  M. A. Antunes,et al.  Structure and Reactivity of Neutral and Cationic trans-N,N′-Dibenzylcyclam Zirconium Alkyl Complexes , 2010 .

[13]  Hao Shen,et al.  Atom-economical synthesis of N-heterocycles via cascade inter-/intramolecular C-N bond-forming reactions catalyzed by Ti amides. , 2010, Journal of the American Chemical Society.

[14]  P. V. van Leeuwen,et al.  Bite angle effects of diphosphines in C-C and C-X bond forming cross coupling reactions. , 2009, Chemical Society reviews.

[15]  Zuowei Xie,et al.  Nickel-mediated three-component cycloaddition reaction of carboryne, alkenes, and alkynes. , 2009, Journal of the American Chemical Society.

[16]  T. Roisnel,et al.  Group 4 Metal Complexes of Fluorous (Di)Alkoxide-(Di)Imino Ligands: Synthesis, Structure, Olefin Polymerization Catalysis, and Decomposition Pathways , 2009 .

[17]  Dongmei Liu,et al.  Synthesis, Structure, and Reactivity of Group 4 Metallacarboranes Bearing the Ligand [Me2C(C9H6)(C2B9H10)]3− , 2008 .

[18]  Hao Shen,et al.  Synthesis and Structural Characterization of Group 4 Metal Complexes Bearing Pentavalent Phosphorus-Bridged Ligands [(C13H8)(iPr2N)P(−O)(C2B10H10)]2− and [(C13H9)(iPr2N)P(═O)(C2B9H10)]2− , 2008 .

[19]  Dongmei Liu,et al.  Synthesis, Structural Characterization, and Reactivity of Group 4 Metallacarboranes Containing the Ligand [Me2C(C5H4)(C2B9H10)]3− , 2008 .

[20]  A. Hoveyda,et al.  Chiral Titanocenes and Zirconocenes in Synthesis , 2008 .

[21]  Minserk Cheong,et al.  New Types of Constrained Geometry Group 4 Metal Complexes Derived from the Aminomethyldicarbollyl Ligand System: Synthesis and Structural Characterization of Mono-dicarbollylamino and Bis-dicarbollylamino Group 4 Metal Complexes , 2007 .

[22]  Hao Shen,et al.  Synthesis, Structure, and Reactivity of [σ:η1:η5-(OCH2)(Me2NCH2)C2B9H9]Ti(NR2) (R = Me, Et) , 2007 .

[23]  S. Coles,et al.  Half-sandwich group 4 salicyloxazoline catalysts , 2006 .

[24]  Hao Shen,et al.  Guanylation of Amines Catalyzed by a Half-Sandwich Titanacarborane Amide Complex , 2006 .

[25]  S. Grimme,et al.  Stereo-electronic interaction in complex molecules: cyclopropyl conjugation with Lewis acidic centres across connecting carbon-carbon triple bonds. , 2006, Chemical communications.

[26]  L. Deng,et al.  Nickel-mediated regioselective [2 + 2 + 2] cycloaddition of carboryne with alkynes. , 2006, Journal of the American Chemical Society.

[27]  C. Qian,et al.  Synthesis, Structure, and Olefin Polymerization Behavior of Constrained-Geometry Group 4 Metallacarboranes Incorporating Imido-Dicarbollyl Ligands , 2006 .

[28]  Zuowei Xie.  Group 4 metallocenes incorporating constrained-geometry carboranyl ligands , 2006 .

[29]  Baiquan Wang.  Ansa-metallocene polymerization catalysts: Effects of the bridges on the catalytic activities , 2006 .

[30]  Hoi-Shan Chan,et al.  Highly Electrophilic Half-Sandwich Group 4 Metallacarborane Alkyls. C-H/C-O Activation and Alkyne Insertion Reactions at Neutral Metal Complexes , 2005 .

[31]  Hoi-Shan Chan,et al.  Synthesis, Structural Characterization, and Reactivity of Rare Earth Complexes Incorporating Lewis Base Appended nido-Carborane Anions of the C2B9 and C2B10 Systems , 2005 .

[32]  Hoi-Shan Chan,et al.  Synthesis and structural characterization of mono- and bisfunctional o-carboranes. , 2005, Dalton transactions.

[33]  Zuowei Xie,et al.  Synthesis, Characterization, and Reactivity of Terminal Titanium Imido Complexes Incorporating Constrained-Geometry Carboranyl Ligands , 2005 .

[34]  Hoi-Shan Chan,et al.  A new synthetic route to high-valent half-sandwich group 4 metallacarborane alkyls. synthesis and structural characterization of [η1:η6-(Me2NCH2CH2)C2B10H11]Hf(CH2SiMe3)2 , 2005 .

[35]  Minserk Cheong,et al.  Sterically protected titanium (aminoethyl)dicarbollides : Synthesis of novel constrained-geometry complexes showing an unusual cage B,N-cyclization , 2005 .

[36]  J. Ko,et al.  Novel titanium complexes of a multidentate dicarbollide ligand. Synthesis and structural characterization of a constrained geometry complex. , 2003, Chemical communications.

[37]  M. H. Lee,et al.  Group 4 complexes derived from o-carborane: synthesis, structures and ethylene polymerization properties , 2003 .

[38]  P. Chirik,et al.  Alkyl substituent effects on reductive elimination reactions in zirconocene alkyl hydride complexes. Manipulation of the alkyl steric environment allows the synthesis of a zirconocene dinitrogen complex , 2003 .

[39]  P. Sharp,et al.  Cp 2 Zr(η 2 -benzocyclobutadiene)(PMe 3 ), a Rare η 2 -Cyclobutadiene Complex , 2002 .

[40]  Zuowei Xie.  Advances in the chemistry of metallacarboranes of f-block elements , 2002 .

[41]  K. Henderson,et al.  Synthesis of zirconocene amides and ketimides and an investigation into their ethylene polymerization activity , 2002 .

[42]  R. Waymouth,et al.  2-Arylindene metallocenes: conformationally dynamic catalysts to control the structure and properties of polypropylenes. , 2002, Accounts of chemical research.

[43]  Zuowei Xie,et al.  Synthesis, Structural Characterization, and Olefin Polymerization Behavior of Group 4 Metal Complexes with Constrained-Geometry Carborane Ligands , 2001 .

[44]  S. Macgregor,et al.  Insertions of unsymmetric alkynes into the metal-carbon bonds of nickelacycles: What determines the regiochemistry? , 2001 .

[45]  J. Won,et al.  Dicarbollide Analogues of the Constrained-Geometry Polymerization Catalyst , 2001 .

[46]  G. Erker,et al.  Homogeneous single-component betaine Ziegler-Natta catalysts derived from (butadiene)zirconocene precursors. , 2001, Accounts of chemical research.

[47]  V. Young,et al.  Titanium Dicarbollide Complexes. Molecular Structures of (η5-C2B9H11)(C5Me5)TiMe and (η5-C2B9H11)(η5,η1-C5Me4CH2)Ti , 2001 .

[48]  D. Armstrong,et al.  Zirconocene ketimides: Synthesis, structural characterization, ethylene polymerization activity, and ab initio computational studies , 2000 .

[49]  G. Erker,et al.  Addition and Coupling Reactions of Zirconocene Cation Complexes that Contain a Pendant η2-Formaldiminium Side Chain , 2000 .

[50]  J. Reek,et al.  Ligand Bite Angle Effects in Metal-catalyzed C-C Bond Formation. , 2000, Chemical reviews.

[51]  L. Cavallo,et al.  Selectivity in propene polymerization with metallocene catalysts. , 2000, Chemical reviews.

[52]  V. R. Jensen,et al.  Toward Quantitative Prediction of Stereospecificity of Metallocene-Based Catalysts for alpha-Olefin Polymerization. , 2000, Chemical reviews.

[53]  H. Alt,et al.  Effect of the Nature of Metallocene Complexes of Group IV Metals on Their Performance in Catalytic Ethylene and Propylene Polymerization. , 2000, Chemical reviews.

[54]  V. Burlakov,et al.  What do titano- and zirconocenes do with diynes and polyynes? , 2000, Accounts of chemical research.

[55]  G. Erker,et al.  Evidence for α-Nitrogen Participation in the Internal C−H Activation Reaction at ((Dimethylamino)methyl)cyclopentadienyl-Derived Methylzirconocene Cations , 1999 .

[56]  U. Thewalt,et al.  Synthesis and crystal structure of a zirconium(III) diacetylide tweezer complex: [(η5-C5HMe4)2Zr(η1-CCSiMe3)2]-K+ , 1998 .

[57]  V. Young,et al.  Formation of novel ansa-carborane-alkoxide complexes by carbonylation of (C5Me5)(η5-C2B9H 11)TiMe , 1998 .

[58]  R. F. Jordan,et al.  CATALYTIC DIMERIZATION OF TERMINAL ALKYNES BY A HAFNIUM CARBORANYL COMPLEX. A SELF-CORRECTING CATALYST , 1997 .

[59]  D. J. Crowther,et al.  Synthesis, Structure, and Reactivity of a Novel Hafnium Carboranyl Hydride Complex , 1997 .

[60]  R. Grubbs,et al.  α-Agostic Interactions and Olefin Insertion in Metallocene Polymerization Catalysts , 1996 .

[61]  George M. Sheldrick,et al.  SADABS, Program for Empirical Absorption Correction of Area Detector Data , 1996 .

[62]  D. J. Crowther,et al.  EARLY METAL DICARBOLLIDE CHEMISTRY. CHARACTERIZATION OF AN UNUSUAL BRIDGING C2B9H112- BONDING MODE IN (C5ME5)2(C2B9H11)2HF2ME2 , 1995 .

[63]  R. F. Jordan,et al.  EARLY METAL CARBORANE CHEMISTRY. GENERATION AND REACTIVITY OF (C5ME5)(ETA 5-C2B9H11)TIME , 1995 .

[64]  D. J. Crowther,et al.  Coordination of CB11H12- to cationic zirconium(IV) complexes. Synthesis and structures of (C5H5)2Zr(.eta.2-CH2Ph)(CB11H12), (C5H4Me)2Zr(CH3)(CB11H12), and (C5Me5)Zr(CH3)2(CB11H12) , 1993 .

[65]  D. J. Crowther,et al.  Group 4 metal dicarbollide chemistry. Synthesis, structures, and reactivity of electrophilic alkyl complexes (Cp*)(C2B9H11)M(R), M = Hf, Zr , 1991 .

[66]  R. F. Jordan,et al.  Insertion chemistry of Cp2Zr(.eta.2-C,N-CH2{6-Me-pyrid-2-yl})+: facile zirconium-mediated functionalization of methyl carbon-hydrogen bonds of 2,6-lutidine , 1991 .

[67]  R. F. Jordan,et al.  Electronic control of regioselectivity in coupling reactions of SiMe3-substituted alkenes with Cp2Zr(*2(N,C2)-6-phenylpyridyl)(THF)+ , 1990 .

[68]  S. Buchwald,et al.  Zirconocene complexes of imines. General synthesis, structure, reactivity, and in situ generation to prepare geometrically pure allylic amines , 1989 .

[69]  W. L. Jorgensen,et al.  Ab initio investigations of the .beta.-silicon effect on alkyl and cyclopropyl carbenium ions and radicals , 1989 .

[70]  G. Erker,et al.  Cp2Zr(N=CPh2)2, an organometallic heteroallene-type Schiff base derivative relevant to describing sp2-hybridized nitrogen inversion , 1988 .

[71]  F. Palacios,et al.  (C5Me5)SiMe3 as a mild and effective reagent for transfer of the C5Me5 ring: an improved route to monopentamethylcyclopentadienyl trihalides of the group 4 elements , 1988 .

[72]  K. Morokuma,et al.  SiC agostic interaction with Ti: origin of alkenyl group distortion in Ti(C(SiH2CH3)=CH2)X2+. An ab initio MO study , 1988 .

[73]  J. B. Lambert,et al.  Stabilization of positive charge by .beta.-silicon , 1987 .

[74]  Scott G. Wierschke,et al.  Magnitude and origin of the .beta.-silicon effect on carbenium ions , 1985 .

[75]  C. Eaborn.  Silicon Reagents in Organic Synthesis , 1983 .

[76]  J. Bercaw,et al.  Alkyl and hydride derivatives of (pentamethylcyclopentadienyl)zirconium(IV) , 1982 .

[77]  N. A. Clinton,et al.  Vertical stabilization of cations by neighboring .sigma. bonds. General considerations , 1971 .

[78]  M. Hawthorne.  Chemistry of the polyhedral species derived from transition metals and carboranes , 1968 .

[79]  M. Hawthorne,et al.  Carbametallic Boron Hydride Derivatives. I. Apparent Analogs of Ferrocene and Ferricinium Ion , 1965 .