A Hybrid Sorbent Utilizing Nanoparticles of Hydrous Iron Oxide for Arsenic Removal from Drinking Water

Arsenic in drinking water, present primarily as inorganic As(III) (arsenite) or As(V) (arsenate), has been linked to a number of human ailments. This has prompted the United States Environmental Protection Agency (U.S. EPA) to lower the maximum contaminant level for arsenic in drinking water from 50 to 10 µg/L. ArsenX np was developed to satisfy the need for an efficient, reliable, and reusable material to meet this new arsenic standard. ArsenX np is a hybrid sorbent consisting of nanoparticles of hydrous iron oxide distributed throughout a porous polymeric bead. This combines the excellent handling, flow characteristics and attrition resistance of conventional ion exchange resins with the well-documented arsenic affinity of hydrous iron oxides. In field tests, the resin maintained an effluent arsenic concentration below 10 µg/L for 4 months of continuous operation with no mechanical problems and no pressure buildup across the resin bed. Arsenic is removed from solution due to the interaction with the nan...

[1]  T. Suzuki,et al.  Removal of As(III) and As(V) by a Porous Spherical Resin Loaded with Monoclinic Hydrous Zirconium Oxide , 1997 .

[2]  M. Chanda,et al.  Ligand exchange sorption of arsenate and arsenite anions by chelating resins in ferric ion form I. Weak-base chelating resin dow XFS-4195☆ , 1988 .

[3]  Michael F Hochella,et al.  Aquatic environmental nanoparticles. , 2007, Journal of environmental monitoring : JEM.

[4]  I. Rău,et al.  Arsenic(V) Removal from Aqueous Solutions by Iron(III) Loaded Chelating Resin , 2000 .

[5]  Raymond L D Whitby,et al.  Use of iron-based technologies in contaminated land and groundwater remediation: a review. , 2008, The Science of the total environment.

[6]  R. Eldridge,et al.  Adsorption characteristics of arsenic(III) and arsenic(V) on iron(III)-loaded chelating resin having lysine-Nα,Nα-diacetic acid moiety , 1996 .

[7]  M. Jekel,et al.  Granular ferric hydroxide—a new adsorbent for the removal of arsenic from natural water. , 1998 .

[8]  J. Greenleaf,et al.  Arsenic removal using a polymeric/inorganic hybrid sorbent. , 2003, Water research.

[9]  T. Suzuki,et al.  Adsorption and removal of oxo-anions of arsenic and selenium on the zirconium(IV) loaded polymer resin functionalized with diethylenetriamine-N,N,N',N'-polyacetic acid. , 2000, Journal of environmental monitoring : JEM.

[10]  L. Cumbal,et al.  Arsenic removal using polymer-supported hydrated iron(III) oxide nanoparticles: role of donnan membrane effect. , 2005, Environmental science & technology.

[11]  N. N. Greenwood,et al.  Chemistry of the elements , 1984 .

[12]  T. Suzuki,et al.  Preparation of porous resin loaded with crystalline hydrous zirconium oxide and its application to the removal of arsenic , 2000 .

[13]  Hideyuki Matsunaga,et al.  Adsorption Characteristics of As(III) and As(V) with Titanium Dioxide Loaded Amberlite XAD-7 Resin , 2002, Analytical sciences : the international journal of the Japan Society for Analytical Chemistry.

[14]  Dayang Wang,et al.  Fe2O3/macroporous resin nanocomposites: Some novel highly efficient catalysts for hydroxylation of phenol with H2O2 , 1998 .

[15]  George P. Korfiatis,et al.  Effects of silicate, sulfate, and carbonate on arsenic removal by ferric chloride , 2000 .

[16]  Laurie S. McNeill,et al.  Arsenic Treatability Options and Evaluation of Residuals Management Issues , 2001 .