New Acyclic Chalcogen Bearing Ligands and their Complexation Reactions

Two (N 3 Se 2) type acyclic Schiff-bases, [{PhSe(CH2)n N=C(CH3)}2C5H3N] (n = 2,3), and their complexes with Cd(II) have been synthesized and characterized. The geometry around central cadmium has been assigned on the basis of physicochemical and spectral studies.Structure of the cadmium complex [PhSe(CH2)3NC(CH3)C5H5N.C(CH3)NH] .CdCl2 has been confirmed by single crystal X-ray diffraction method.

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