Sources, sinks, and seasonal cycles of atmospheric methane

It is shown that a long lifetime of about 8 years is most consistent with the observed latitudinal variation of atmospheric methane, requiring the current global emissions of methane to be around 550 teragrams per year (Tg = 1012 gm). On average there is 25–34 ppbv less methane in the atmosphere of the northern hemisphere during summer when compared with the rest of the year. Methane concentrations rise rapidly to their yearly maximums in fall. Seasonal cycles of CH4 concentration in the southern hemisphere include lowest concentrations during the late Australian summer and fall, being about 14 ppbv less than during the rest of the year. The repeating pattern of a rapid rise of CH4 concentrations during fall in the northern hemisphere suggests a large fall source at latitudes above 30°N. The remaining observed seasonal variations are consistent with the seasonal cycle of OH, which removes methane from the atmosphere. The extensive set of self consistent measurements of methane are reported and analyzed showing that methane has increased during the last 3–4 years at rates of 1–1.9% per year all over the world at sites ranging from inside the arctic circle to the south pole. Observational results are used to estimate the sources, sinks, seasonal cycles of CH4, and the effects of human activities on its atmospheric abundance.

[1]  R. Prinn,et al.  The Atmospheric Lifetime Experiment: 4. Results for CF2Cl2 based on three years data , 1983 .

[2]  J. C. Sheppard,et al.  Inventory of global methane sources and their production rates , 1982 .

[3]  Ralph J. Cicerone,et al.  Possible variations in atmospheric methane , 1977 .

[4]  H. Craig,et al.  Methane: The record in polar ice cores , 1982 .

[5]  D. I. Sebacher,et al.  Methane flux in forested freshwater swamps of the southeastern United States , 1981 .

[6]  M. Mendillo,et al.  Evolution of the atmosphere , 1977 .

[7]  M. Khalil,et al.  Latitudinal distributions of trace gases in and above the boundary layer , 1982 .

[8]  Thomas E. Graedel,et al.  Total organic component data: A study of urban atmospheric patterns and trends , 1982 .

[9]  P. Crutzen,et al.  Latitudinal distributions of CO and CH4 over the Pacific , 1980 .

[10]  C. M. Stevens,et al.  The carbon isotopic composition of atmospheric methane , 1982 .

[11]  J. Hansen,et al.  Greenhouse effect of trace gases, 1970‐1980 , 1981 .

[12]  D. I. Sebacher,et al.  Methane flux in the Great Dismal Swamp , 1982, Nature.

[13]  Ralph J. Cicerone,et al.  Sources of atmospheric methane: Measurements in rice paddies and a discussion , 1981 .

[14]  S. Wofsy,et al.  Tropospheric chemistry: A global perspective , 1981 .

[15]  G. Boer,et al.  An estimate of the interhemispheric transfer of carbon monoxide from tropical general circulation data , 1974 .

[16]  M. Khalil,et al.  Global atmospheric distribution and trend of methylchloroform (CH3CCl3) , 1981 .

[17]  D. Blake,et al.  Methane: Interhemispheric concentration gradient and atmospheric residence time. , 1982, Proceedings of the National Academy of Sciences of the United States of America.

[18]  M. Khalil,et al.  Atmospheric trace gases in antarctica. , 1981, Science.

[19]  D. Ehhalt The atmospheric cycle of methane , 1974 .

[20]  M. Khalil,et al.  Atmospheric methane /CH4/ - Trends and seasonal cycles , 1981 .

[21]  M. Khalil,et al.  Increase in the concentration of atmospheric methane , 1981 .

[22]  J. W. Kidson,et al.  Interhemispheric mass exchange from meteorological and trace substance observations , 1969 .

[23]  H. Singh,et al.  Atmospheric Halocarbons, Hydrocarbons, and Sulfur Hexafluoride: Global Distributions, Sources, and Sinks , 1979, Science.

[24]  M. Khalil,et al.  Global production of methane by termites , 1983, Nature.

[25]  Leonard K. Peters,et al.  Numerical simulation of the transport and chemistry of CH4 and co in the troposphere , 1979 .

[26]  J. Penner,et al.  Analysis of global budgets of halocarbons , 1978 .

[27]  F. S. Rowland,et al.  Global increase in atmospheric methane concentrations between 1978 and 1980 , 1982 .

[28]  G. W. Snedecor Statistical Methods , 1964 .

[29]  M. Molina,et al.  Stratospheric sink for chlorofluoromethanes: chlorine atomc-atalysed destruction of ozone , 1974, Nature.

[30]  M. Khalil,et al.  Secular trends of atmospheric methane (CH4) , 1982 .

[31]  K. H. Mancy,et al.  Methane flux from wetlands areas , 1977 .

[32]  R. E. Larson,et al.  Atmospheric Trace Gases in the Southern Hemisphere , 1973 .

[33]  T. Koyama Gaseous metabolism in lake sediments and paddy soils and the production of atmospheric methane and hydrogen , 1963 .

[34]  J. Louis A two-dimensional transport model of the atmosphere , 1974 .

[35]  L. A. Cavanagh,et al.  Analysis of ancient atmospheres , 1973 .

[36]  P. Crutzen,et al.  The impact of the chlorocarbon industry on the ozone layer , 1978 .

[37]  R. F. Hampson Kinetic and photochemical data for atmospheric chemistry reactions of the nitrogen oxides , 1980 .

[38]  M. Khalil Topics in the behaviour of atmospheric trace gases , 1979 .

[39]  M. Khalil,et al.  Methane and Carbon Monoxide in Snow , 1982 .

[40]  H. Reichle,et al.  Vertical profiles of CO & CH4 in the lower and middle troposphere over the eastern United States January 1978 , 1979 .

[41]  M. Khalil,et al.  Differences in the concentrations of atmospheric trace gases in and above the tropical boundary layer , 1981 .

[42]  P. Fraser,et al.  Trends of atmospheric methane in the southern hemisphere , 1981 .

[43]  P. Crutzen,et al.  Termites: A Potentially Large Source of Atmospheric Methane, Carbon Dioxide, and Molecular Hydrogen , 1982, Science.

[44]  D. Ehhalt,et al.  Sources and sinks of atmospheric methane , 1978 .

[45]  R. F. Hampson Chemical kinetic and photochemical data sheets for atmospheric reactions , 1980 .