Detailed numerical modeling of pyrolysis in a heterogeneous packed bed using XDEM

Abstract The aim of this investigation is to predict pyrolysis of biomass in a packed bed. The eXtended Discrete Element Method (XDEM) as a simulation framework is proposed to predict the heat transfer, drying and pyrolysis of biomass in a packed bed. This allows determination of the detailed information about each single particle and the whole bed as well, which is very important to understand the complex process in the packed bed. XDEM is considered as an Euler–Lagrange model, where the fluid phase is a continuous phase and each particle is tracked with a Lagrangian approach. The particle model itself is based on one-dimensional and transient differential conservation equations for mass, momentum, species and energy. However gas phase is modeled in three-dimensional and behaves more like an external flow through the void space, formed by particles in the reactor. The model has been compared to experimental data for a wide range of temperatures. Good agreement between simulation and measurement proves the ability of the model to predict pyrolysis of packed bed; therefore it can be used as a reliable tool for designing gasification devices.

[1]  F. Thurner,et al.  Kinetic investigation of wood pyrolysis , 1981 .

[2]  C. Branca,et al.  Kinetics of primary product formation from wood pyrolysis , 2001 .

[3]  Colomba Di Blasi,et al.  Modeling chemical and physical processes of wood and biomass pyrolysis , 2008 .

[4]  Jacob Bear,et al.  Transport Phenomena in Porous Media , 1998 .

[5]  M. Ha,et al.  A numerical study on the combustion of a single carbon particle entrained in a steady flow , 1994 .

[6]  C. Mandl,et al.  Modelling of an updraft fixed-bed gasifier operated with softwood pellets , 2010 .

[7]  Bernhard Peters,et al.  Thermal Conversion of Solid Fuels , 2002 .

[8]  Shaohua Wu,et al.  Experimental study on effects of moisture content on combustion characteristics of simulated municipal solid wastes in a fixed bed. , 2008, Bioresource technology.

[9]  A. Bridgwater,et al.  The influence of feedstock drying on the performance and economics of a biomass gasifier–engine CHP system , 2002 .

[10]  Thomas Nussbaumer,et al.  Measurements and particle resolved modelling of heat-up and drying of a packed bed , 2002 .

[11]  B Peters,et al.  A flexible and stable numerical method for simulating the thermal decomposition of wood particles. , 2001, Chemosphere.

[12]  Kunio Yoshikawa,et al.  Analysis of an updraft biomass gasifier with high temperature steam using a numerical model , 2012 .

[13]  B. B. Krieger,et al.  Modelling and experimental verification of physical and chemical processes during pyrolysis of a large biomass particle , 1985 .

[14]  Y. Haseli,et al.  Numerical study of the conversion time of single pyrolyzing biomass particles at high heating conditions , 2011 .

[15]  C. Simonson,et al.  Modeling of the packed bed drying of paddy rice using the local volume averaging (LVA) approach , 2006 .

[16]  Henrik Thunman,et al.  CFD simulations of biofuel bed conversion: A submodel for the drying and devolatilization of thermally thick wood particles , 2013 .

[17]  T. Zhao,et al.  An extension of Darcy's law to non-Stokes flow in porous media , 2000 .

[18]  J. Banavar,et al.  Computer Simulation of Liquids , 1988 .

[19]  Morten Grønli,et al.  Mathematical Model for Wood PyrolysisComparison of Experimental Measurements with Model Predictions , 2000 .

[20]  Colomba Di Blasi,et al.  Modeling wood gasification in a countercurrent fixed‐bed reactor , 2004 .

[21]  C. Di Blasi,et al.  Modeling a stratified downdraft wood gasifier with primary and secondary air entry , 2013 .

[22]  N. Papayannakos,et al.  Modelling of the pyrolysis of biomass particles. Studies on kinetics, thermal and heat transfer effects , 1991 .

[23]  J. Saastamoinen Comparison of Moving Bed Dryers of Solids Operating in Parallel and Counterflow Modes , 2005 .

[24]  Tiziano Faravelli,et al.  Chemical Kinetics of Biomass Pyrolysis , 2008 .

[25]  H. Yücel,et al.  Pyrolysis kinetics of lignocellulosic materials , 1993 .

[26]  P. Cundall,et al.  A discrete numerical model for granular assemblies , 1979 .

[27]  Johann C. Wurzenberger,et al.  Thermal conversion of biomass: Comprehensive reactor and particle modeling , 2002 .

[28]  B. Peters Validation of a numerical approach to model pyrolysis of biomass and assessment of kinetic data , 2011 .

[29]  C. Di Blasi,et al.  Kinetic and Heat Transfer Control in the Slow and Flash Pyrolysis of Solids , 1996 .

[30]  Larry L. Baxter,et al.  Effects of particle shape and size on devolatilization of biomass particle , 2010 .

[31]  B. Peters,et al.  A discrete approach to thermal conversion of solid fuel by the discrete particle method (dpm) , 2010 .

[33]  J. Collazo,et al.  Numerical modeling of the combustion of densified wood under fixed-bed conditions , 2012 .

[34]  Hugo A. Jakobsen,et al.  Multi-scale modeling of fixed-bed thermo-chemical processes of biomass with the representative particle model: Application to pyrolysis , 2013 .

[35]  B. Peters,et al.  Application of XDEM as a novel approach to predict drying of a packed bed , 2014 .

[36]  Y. Haseli,et al.  Modeling biomass particle pyrolysis with temperature-dependent heat of reactions , 2011 .

[37]  M. Assari,et al.  Numerical simulation of fluid bed drying based on two-fluid model and experimental validation , 2007 .

[38]  V. Cozzani,et al.  Heat of wood pyrolysis , 2003 .