Diffraction properties of two-dimensional photonic crystals

We show that the envelope of the diffraction efficiency of a two-dimensional photonic crystal can exhibit spectral regions of very small diffraction efficiency (<5×10−3), while in other regions, the diffraction efficiency is near unity. The experimental results on higher bands of hexagonal, silicon-based photonic crystals agree well with corresponding numerical calculations and highlight the prominent role of the surface termination, an aspect which cannot be described by the photonic band structure alone. We speculate about possible applications of such additional spectral filters in Raman and photoluminescence spectroscopy.