Hierarchical Porous Graphene/Polyaniline Composite Film with Superior Rate Performance for Flexible Supercapacitors

A highly flexible graphene free-standing film with hierarchical structure is prepared by a facile template method. With a porous structure, the film can be easily bent and cut, and forms a composite with another material as a scaffold. The 3D graphene film exhibits excellent rate capability and its capacitance is further improved by forming a composite with polyaniline nanowire arrays. The flexible hierarchical composite proves to be an excellent electrode material for flexible supercapacitors.

[1]  Chang Liu,et al.  Advanced Materials for Energy Storage , 2010, Advanced materials.

[2]  G. Shi,et al.  Graphene based new energy materials , 2011 .

[3]  Yong Yan,et al.  Hierarchical crystalline superstructures of conducting polymers with homohelicity. , 2010, Chemistry.

[4]  Meryl D. Stoller,et al.  Review of Best Practice Methods for Determining an Electrode Material's Performance for Ultracapacitors , 2010 .

[5]  G. Lu,et al.  Fabrication of Graphene/Polyaniline Composite Paper via In Situ Anodic Electropolymerization for High-Performance Flexible Electrode. , 2009, ACS nano.

[6]  Hiroyuki Nishide,et al.  Toward Flexible Batteries , 2008, Science.

[7]  M. Wan,et al.  Chiral nanotubes of polyaniline synthesized by a template-free method , 2002 .

[8]  Hui‐Ming Cheng,et al.  Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition. , 2011, Nature materials.

[9]  Jingjing Xu,et al.  Hierarchical nanocomposites of polyaniline nanowire arrays on graphene oxide sheets with synergistic effect for energy storage. , 2010, ACS nano.

[10]  A. Burke Ultracapacitors: why, how, and where is the technology , 2000 .

[11]  G. Shi,et al.  Self-assembled graphene hydrogel via a one-step hydrothermal process. , 2010, ACS nano.

[12]  Hua Zhang,et al.  Preparation of novel 3D graphene networks for supercapacitor applications. , 2011, Small.

[13]  R. Ruoff,et al.  Graphene-based ultracapacitors. , 2008, Nano letters.

[14]  J. Choi,et al.  3D macroporous graphene frameworks for supercapacitors with high energy and power densities. , 2012, ACS nano.

[15]  Stephen Mann,et al.  Higher-order organization by mesoscale self-assembly and transformation of hybrid nanostructures. , 2003, Angewandte Chemie.

[16]  M. Wan,et al.  Nanostructures of polyaniline doped with inorganic acids , 2002 .

[17]  Yonggang Huang,et al.  A curvy, stretchy future for electronics , 2009, Proceedings of the National Academy of Sciences.

[18]  Pooi See Lee,et al.  3D carbon based nanostructures for advanced supercapacitors , 2013 .

[19]  Khalil Amine,et al.  Chemically active reduced graphene oxide with tunable C/O ratios. , 2011, ACS nano.

[20]  R. Ruoff,et al.  Graphene and Graphene Oxide: Synthesis, Properties, and Applications , 2010, Advanced materials.

[21]  Zhongwei Chen,et al.  Ultrathin, transparent, and flexible graphene films for supercapacitor application , 2010 .

[22]  K. Müllen,et al.  Graphene as Transparent Electrode Material for Organic Electronics , 2011, Advanced materials.

[23]  Quan-hong Yang,et al.  Self‐Assembled Free‐Standing Graphite Oxide Membrane , 2009 .

[24]  Wei Lv,et al.  Conductive graphene-based macroscopic membrane self-assembled at a liquid–air interface , 2011 .

[25]  Yan‐Bing He,et al.  A graphene-based nanostructure with expanded ion transport channels for high rate Li-ion batteries. , 2012, Chemical communications.

[26]  H.Q. Li,et al.  Ordered Whiskerlike Polyaniline Grown on the Surface of Mesoporous Carbon and Its Electrochemical Capacitance Performance , 2006 .

[27]  Junwu Zhu,et al.  Bioinspired Effective Prevention of Restacking in Multilayered Graphene Films: Towards the Next Generation of High‐Performance Supercapacitors , 2011, Advanced materials.

[28]  Sook Hee Ku,et al.  Graphene–Biomineral Hybrid Materials , 2011, Advanced materials.

[29]  Yang Yang,et al.  A one-step, solvothermal reduction method for producing reduced graphene oxide dispersions in organic solvents. , 2010, ACS nano.

[30]  L. J. Lee,et al.  Growth and alignment of polyaniline nanofibres with superhydrophobic, superhydrophilic and other properties. , 2007, Nature nanotechnology.

[31]  Fei Liu,et al.  Folded Structured Graphene Paper for High Performance Electrode Materials , 2012, Advanced materials.

[32]  Zhibin Yang,et al.  Hierarchical composites of polyaniline-graphene nanoribbons-carbon nanotubes as electrode materials in all-solid-state supercapacitors. , 2013, Nanoscale.

[33]  G. Shi,et al.  Three-dimensional graphene architectures. , 2012, Nanoscale.

[34]  Yanwu Zhu,et al.  Highly conductive and porous activated reduced graphene oxide films for high-power supercapacitors. , 2012, Nano letters.

[35]  Anran Liu,et al.  Supercapacitors based on flexible graphene/polyaniline nanofiber composite films. , 2010, ACS nano.

[36]  Y. Miao,et al.  High-performance supercapacitors based on hollow polyaniline nanofibers by electrospinning. , 2013, ACS applied materials & interfaces.

[37]  Y. Gogotsi,et al.  Materials for electrochemical capacitors. , 2008, Nature materials.

[38]  Shing‐Jong Huang,et al.  Supplementary Information for , 2013 .

[39]  Zhixiang Wei,et al.  Conducting polymer nanowire arrays with enhanced electrochemical performance , 2010 .

[40]  Lili Zhang,et al.  Carbon-based materials as supercapacitor electrodes. , 2009, Chemical Society reviews.

[41]  Yu Huang,et al.  Flexible solid-state supercapacitors based on three-dimensional graphene hydrogel films. , 2013, ACS nano.

[42]  Tianxi Liu,et al.  Graphene-wrapped polyaniline hollow spheres as novel hybrid electrode materials for supercapacitor applications. , 2013, ACS applied materials & interfaces.

[43]  Siglinda Perathoner,et al.  The Role of Nanostructure in Improving the Performance of Electrodes for Energy Storage and Conversion , 2009 .

[44]  R. Ruoff,et al.  Reduced graphene oxide by chemical graphitization. , 2010, Nature communications.

[45]  Y. Gogotsi,et al.  Capacitance of KOH activated carbide-derived carbons. , 2009, Physical chemistry chemical physics : PCCP.

[46]  Andre K. Geim,et al.  The rise of graphene. , 2007, Nature materials.