Characterization of interfacial and mechanical properties of “green” composites with soy protein isolate and ramie fiber

Environment-friendly fiber-reinforced composites were fabricated using ramie fibers and soy protein isolate (SPI) and were characterized for their interfacial and mechanical properties. Ramie fibers were characterized for their tensile properties and the parameters for the Weibull distribution were estimated. Effect of glycerol content on the tensile properties of SPI was studied. Interfacial shear strength (IFSS) was determined using the microbond technique. Based on the IFSS results and fiber strength distribution, three different fiber lengths and fiber weight contents (FWC) were chosen to fabricate short fiber-reinforced composites. The results indicate that the fracture stress increases with increase in fiber length and fiber weight content. Glycerol was found to increase the fracture strain and reduce the resin fracture stress and modulus as a result of plasticization. For 10% (w/w) of 5 mm long fibers, no significant reinforcement effect was observed. In fact the short fibers acted as flaws and led to reduction in the tensile properties. On further increasing the fiber length and FWC, a significant increase in the Young's modulus and fracture stress and decrease in fracture strain was observed as the fibers started to control the tensile properties of the composites. The experimental data were compared to the theoretical predictions made using Zweben's model. The experimental results are lower than the predicted values for a variety of reasons. However, the two values get closer with increasing fiber length and FWC.

[1]  A. Netravali,et al.  Characterization of henequen fibers and the henequen fiber/poly(hydroxybutyrate-co-hydroxyvalerate) interface , 2001 .

[2]  X. S. Sun,et al.  Curing Process and Mechanical Properties of Protein-Based Polymers , 1999 .

[3]  T. Creighton Proteins: Structures and Molecular Properties , 1986 .

[4]  J. Jane,et al.  Processability and Properties of Biodegradable Plastics Made from Agricultural Biopolymers , 1999 .

[5]  Bernard Miller,et al.  A microbond method for determination of the shear strength of a fiber/resin interface , 1987 .

[6]  G. Hinrichsen,et al.  Flax and cotton fiber reinforced biodegradable polyester amide composites, 1. Manufacture of composites and characterization of their mechanical properties , 1999 .

[7]  K. Satyanarayana,et al.  Structure and properties of some vegetable fibres , 1986 .

[8]  W. Sachse,et al.  Some remarks on acoustic emission measurements and the single-fiber-composite test , 1991 .

[9]  J. Jane,et al.  Biodegradable Plastic Made from Soybean Products. 1. Effect of Preparation and Processing on Mechanical Properties and Water Absorption , 1994 .

[10]  D. Fontanelli,et al.  Ramie (Boehmeria nivea (L.) Gaud.) and Spanish Broom (Spartium junceum L.) fibres for composite materials: agronomical aspects, morphology and mechanical properties , 2000 .

[11]  W. Sachse,et al.  An acoustic emission technique for measuring fiber fragment length distributions in the single-fiber- composite test , 1989 .

[12]  Anil N. Netravali,et al.  Interfacial and mechanical properties of environment-friendly “green” composites made from pineapple fibers and poly(hydroxybutyrate-co-valerate) resin , 1999 .

[13]  B. Miller,et al.  Effects of external loading of fiber on fiber/matrix interfacial shear strength , 1995 .

[14]  Anil N. Netravali,et al.  Mechanical and thermal properties of environment-friendly green composites made from pineapple leaf fibers and poly(hydroxybutyrate-co-valerate) resin , 1999 .

[15]  Keshun Liu,et al.  Soybeans: Chemistry, Technology and Utilization , 1997 .

[16]  P. Herrera-Franco,et al.  Effect of fiber treatment on the mechanical properties of LDPE-henequen cellulosic fiber composites , 1997 .

[17]  Sabu Thomas,et al.  Effect of chemical treatment on the tensile properties of short sisal fibre-reinforced polyethylene composites , 1996 .

[18]  A. Mohanty,et al.  Influence of chemical surface modification on the properties of biodegradable jute fabrics—polyester amide composites , 2000 .