Hamiltonian view on process systems

The thermodynamic approach of analyzing structural stability of process plants was extended to construct the simple Hamiltonian model of lumped process systems. This type of model enables to design a nonlinear PD feedback controller for passivation and loop shaping. This approach is applicable for lumped process systems where Kirchhoff convective transport takes place together with the transfer and sources of various types, and the manipulable input variables are the flow rates. Systems with constant mass holdup and uniform pressure in every balance volume satisfy these conditions. General results are shown by simple examples of practical importance: on a bilinear heat exchanger cell and on an isotherm CSTR with nonlinear reaction.