1 BOUNDARY ELEMENT METHOD PREDICTIONS OF THE INFLUENCE OF THE ELECTROLYTE ON THE GALVANIC CORROSION OF AZ 91 D COUPLED TO STEEL

This research investigated the galvanic corrosion of the magnesium alloy AZ91D coupled to steel. The galvanic current distribution was measured in 5% NaCl solution, corrosive water and an auto coolant. The experimental measurements were compared with predictions from a Boundary Element Method (BEM) model. The boundary condition, required as an input into the BEM model, needs to be a polarization curve that accurately reflects the corrosion process. Provided that the polarization curve does reflect steady state, the BEM model is expected to be able to reflect steady state galvanic corrosion.

[1]  S. Eisenberg,et al.  Magnesium Alloy in Contact with Coated Components , 2005 .

[2]  D. StJohn,et al.  Corrosion of magnesium alloys in commercial engine coolants , 2005 .

[3]  Andrej Atrens,et al.  Evaluation of the BEASY program using linear and piecewise linear approaches for the boundary conditions , 2004 .

[4]  D. StJohn,et al.  Galvanic corrosion of magnesium alloy AZ91D in contact with an aluminium alloy, steel and zinc , 2004 .

[5]  Akira Tahara,et al.  Potential Distribution Measurerment of Galvanic Corrosion by Kelvin Probe , 1998 .

[6]  F. Varela,et al.  The influence of temperature on the galvanic corrosion of a cast iron-stainless steel couple (prediction by boundary element method) , 1997 .

[7]  Holger Rootzén,et al.  Galvanically Induced Atmospheric Corrosion on Magnesium Alloys: A Designed Experiment Evaluated by Extreme Value Statistics and Conventional Techniques , 1997 .

[8]  K. R. Baldwin,et al.  Corrosion behaviour of some vapour deposited magnesium alloys , 1996 .

[9]  L. Betancourt,et al.  Electrochemical behavior of a magnesium galvanic anode under ASTM test method G 97-89 conditions , 1996 .

[10]  R. M. Degerstedt,et al.  Mathematical Models for Cathodic Protection of an Underground Pipeline with Coating Holidays: Part 1 — Theoretical Development , 1995 .

[11]  David Hawke,et al.  Corrosion Properties of New Magnesium Alloys , 1993 .

[12]  S. Aoki,et al.  Prediction of galvanic corrosion rates by the boundary element method , 1991 .

[13]  S. Aoki,et al.  Boundary Element Analysis of an Inverse Problem in Galvanic Corrosin , 1989 .

[14]  S. Aoki,et al.  Analysis of Potential and Current Density Distributions Using a Boundary Element Method , 1988 .

[15]  J. Scully,et al.  Galvanic Corrosion Prediction Using Long- and Short-Term Polarization Curves , 1986 .

[16]  Roy Johnsen,et al.  Prediction of Galvanic Corrosion Rates and Distribution by Means of Calculation and Experimental Models , 1984 .

[17]  W. Hartt,et al.  Calcareous Deposits on Metal Surfaces in Seawater—A Critical Review , 1984 .

[18]  J. Waber STUDY OF A SIZE EFFECT IN GALVANIC CORROSION , 1957 .

[19]  C. Wagner,et al.  Theoretical Analysis of the Current Density Distribution in Electrolytic Cells , 1951 .

[20]  Zhao Liang Corrosion and protection of magnesium alloys , 2002 .

[21]  J. I. Skar Corrosion and corrosion prevention of magnesium alloys , 1999 .

[22]  T. Itoh,et al.  Atmospheric galvanic corrosion behavior of AZ91D coupled to other metals. , 1999 .

[23]  J. Kruger,et al.  Corrosion of magnesium , 1993 .

[24]  Rs Munn A Review of the Development of Computational Corrosion Analysis for Spatial Corrosion Modeling Through Its Maturity in the Mid-1980s , 1992 .

[25]  S. Aoki,et al.  A boundary element analysis on galvanic corrosion problems—computational accuracy on galvanic fields with screen plates , 1990 .

[26]  J. Scully,et al.  Prediction of Tube-Tubesheet Galvanic Corrosion Using Finite Element and Wagner Number Analyses , 1988 .

[27]  Jw Oldfield,et al.  Electrochemical Theory of Galvanic Corrosion , 1988 .

[28]  H. Teeple Atmospheric Galvanic Corrosion of Magnesium Coupled to Other Metals , 1956 .

[29]  William Edwin Benbow Steels in modern industry , 1951 .